Petrophysical measurement of ODP Leg 122 and 123 samples (Tables 1, 2)

The capillary-pressure characteristics of 22 samples of lithified post-Paleozoic Indian-Ocean carbonates were compared to published data from older carbonate rocks (lower Paleozoic Hunton Group of Texas and Oklahoma). The Indian-Ocean samples are considerably more porous than are the Paleozoic samples, yet all of the Indian-Ocean samples fit readily into a descriptive petrofacies scheme previously established for the Hunton Group. The Indian-Ocean samples may be assigned to four petrophysical facies (petrofacies) based on the shapes of their capillary-pressure curves, their pore-throat-size distributions, their estimated recovery efficiency values (for nonwetting fluids), and the visual characteristics of their pore systems, as observed with a scanning-electron microscope. Petrofacies assignments for the Indian-Ocean samples are as follows. Petrofacies I includes six samples collected from the coarse basal portions of event deposits (primarily turbidites). These samples have large throats, leptokurtic throat-size distributions, low- to moderate recovery efficiency values, concave cumulative-intrusion capillary-pressure curves, and high porosity values. Petrofacies II includes two sedimentologically dissimilar samples that have medium-size throats, platykurtic throat-size distributions, moderate- to-high recovery efficiency values, gently sloping cumulative-intrusion capillary-pressure curves, and high porosity values. Petrofacies III includes two polymictic sandstones and a skeletal packstone that have small throats, polymodal throat-size distributions, moderate recovery efficiency values, gently sloping cumulative-intrusion capillary-pressure curves, and high porosity values. Petrofacies IV includes 11 samples, mostly recrystallized neritic carbonates, that have small throats, leptokurtic throat-size distributions, high recovery efficiency values, convex cumulative-intrusion capillary-pressure curves, and low porosity values. Comparison of petrofacies assignment to core-, thin-section-, and smear-slide data, and to inferred depositional setting, suggests that pore systems in most samples from Holes 765C and 766A result from primary depositional features, whereas pore systems in samples from Hole 761C and one sample from Hole 765C have been strongly influenced by diagenetic processes. For Hole 761C, prediction of petrophysical parameters should be most successful if based on diagenetic facies patterns. By contrast, the distribution of favorable reservoir facies and of permeability barriers in less highly altered rocks collected from Holes 765C and 766A is related to depositional patterns. Recovery efficiency is inversely related to both porosity and median throat size for the present data set. This relationship is similar to that observed for carbonates of the lower Paleozoic Hunton Group and the Ordovician Ellenburger dolomite, but opposite of that observed for some other ancient carbonates. The coarse deposits of the massive basal units of turbidites are petrophysically distinct and form a coherent petrophysical group (Petrofacies I) with substantial reservoir potential. Two samples assigned to Petrofacies I have extremely large throats (median throat size at least 4 ?m, and at least six times that of any other sample) and therefore high permeability values. These two samples come from thin, coarse turbidites that lack or have poorly developed fine divisions and are interpreted to have been deposited on channeled suprafan lobes in a proximal mid-fan setting. The restriction of extremely high permeability values to a single depositional facies suggests that careful facies mapping of deep-sea fans in a deliberate search for such coarse turbidites could dramatically enhance the success of exploration for aquifers or hydrocarbon reservoirs. Such reservoirs should have substantial vertical heterogeneity. They should have high lateral permeability values but low vertical permeability values, and reservoir sections should include numerous thin units having widely differing petrophysical characteristics.

Lower Cretaceous nannofossils of the northwestern Australian margin

Moderately to sparsely nannofossiliferous Neocomian siliciclastics and rich Aptian-Albian nannofossil chalks were cored at two Leg 123 sites on the abyssal plains off northwestern Australia. At Site 765, the basal 70 m of cored section yields questionable Tithonian and Berriasian to early Hauterivian assemblages of moderate diversity containing Cruelellipsis cuvillieri, Tegumentum striatum, Speetonia colligata, and Crucibiscutum salebrosum. The overlying Hauterivianlower Aptian is represented by 140 m of sediments barren of nannofossils. Above this, the remaining 80 m of the Lower Cretaceous section has been assigned to the Rhagodiscus angustus Zone (late Aptian-early Albian in age) and the Prediscosphaera columnata Zone (middle-late Albian in age). Common species include Rhagodiscus angustus, Prediscosphaera columnata, Eprolithus floralis, Eprolithus sp., Chiastozygus litterarius, Rucinolithus irregularis, and Flabellites biforaminis. At Site 766, the Neocomian, represented by 200 m of sediment, yields C. cuvillieri, T. striatum, S. colligata, and C. salebrosum. Within the overlying Aptian-Albian sequence of 80 m, the Rhagodiscus angustus, and P. columnata zones were recognized. The paleobiogeographic patterns and implications are discussed, with special emphasis paid to the bipolar high-latitude distribution pattern of C. salebrosum in the Valanginian-Hauterivian. Biostratigraphically important species are discussed and their occurrence in the Indian Ocean is compared with one from the Tethys and Boreal realms. Two new species, Serbiscutum gaultensis and Eprolithus bettenstaedtii, are described.

Petrography and geochemistry of organic matter in Triassic and Cretaceous sediments from the Wombat and Exmouth Plateau

Triassic (Carnian-Rhaetian) continental margin sediments from the Wombat Plateau off northwest Australia (Sites 759, 760, 761, and 764) contain mainly detrital organic matter of terrestrial higher plant origin. Although deposited in a nearshore deltaic environment, little liptinitic material was preserved. The dominant vitrinites and inertinites are hydrogen-lean, and the small quantities of extractable bitumen contain w-alkanes and bacterial hopanoid hydrocarbons as the most dominant single gas-chromatography-amenable compounds. Lower Cretaceous sediments on the central Exmouth Plateau (Sites 762 and 763) farther south in general have an organic matter composition similar to that in the Wombat Plateau sediments with the exception of a smaller particle size of vitrinites and inertinites, indicating more distal transport and probably deposition in deeper water. Nevertheless, organic matter preservation is slightly better than in the Triassic sediments. Long-chain fatty acids, as well as aliphatic ketones and alcohols, are common constituents in the Lower Cretaceous sediments in addition to n-alkanes and hopanoid hydrocarbons. Thin, black shale layers at the Cenomanian/Turonian boundary, although present at several sites (Sites 762 and 763 on the Exmouth Plateau, Site 765 in the Argo Abyssal Plain, and Site 766 on the continental margin of the Gascoyne Abyssal Plain), are particularly enriched in organic matter only at Site 763 (up to 26%). These organic-matter-rich layers contain mainly bituminite of probable fecal-pellet origin. Considering the high organic carbon content, the moderate hydrogen indices of 350-450 milligrams of hydrocarbon-type material per gram of Corg, the maceral composition, and the low sedimentation rates in the middle Cretaceous, we suggest that these black shales were accumulated in an area of oxygen-depleted bottom-water mass (oceanwide reduced circulation?) underlying an oxygen-rich water column (in which most of the primary biomass other than fecal pellets is destroyed) and a zone of relatively high bioproductivity. Differences in organic matter accumulation at the Cenomanian/Turonian boundary at different sites off northwest Australia are ascribed to regional variations in primary bioproductivity.

Lower Cretaceous radiolarians from the northwestern Australian margin

During Leg 123, abundant and well-preserved Neocomian radiolarians were recovered at Site 765 (Argo Abyssal Plain) and Site 766 (lower Exmouth Plateau). The assemblages are characterized by a scarcity or absence of Tethyan taxa. The Berriasian-early Aptian radiolarian record recovered at Site 765 is unique in its density of well-preserved samples and in its faunal contents. Remarkable contrasts exist between radiolarian assemblages extracted from claystones of Site 765 and reexamined DSDP Site 261, and faunas recovered from radiolarian sand layers of Site 765. Clay faunas are unusual in their low diversity of apparently ecologically tolerant species, whereas sand faunas are dominated by non-Tethyan species that have never been reported before. Comparisons with Sites 766 and 261, as well as sedimentological observations, lead to the conclusion that this faunal contrast results from a difference in provenance, rather than from hydraulic sorting. Biostratigraphic dating proved difficult principally because of the paucity or even absence of (Tethyan) species used in published zonations. In addition, published zonations are contradictory and do not reflect total ranges of species. Radiolarian assemblages recovered from claystones at Sites 765 and 261 in the Argo Basin reflect restricted oceanic conditions for the latest Jurassic to Barremian time period. Neither the sedimentary facies nor the faunal associations bear any resemblance to sediment and radiolarian facies observed in typical Tethyan sequences. I conclude that the Argo Basin was paleoceanographically separated from Tethys during the Late Jurassic and part of the Early Cretaceous by its position at a higher paleolatitude and by enclosing landmasses, i.e., northeastern India and the Shillong Block, which were adjacent to the northwestern Australian margin before the opening. Assemblages recovered from radiolarian sand layers are dominated by non-Tethyan species that are interpreted as circumantarctic. Their sudden appearance in the late Berriasian/early Valanginian pre-dates the oceanization of the Indo-Australian break-up (Ml 1, late Valanginian) by about 5 m.y., but coincides with a sharp increase in margin-derived pelagic turbidites. The Indo-Australian rift zone and its adjacent margins probably were submerged deeply enough to allow an intermittent "spillover" of circumantarctic cold water into the Argo Basin, creating increased bottom current activity. Circumantarctic cold-water radiolarians transported into the Argo Basin upwelled along the margin and died en masse. Concomitant winnowing by bottom currents led to their accumulation in distinct radiolarite layers. High rates of faunal change and the sharp increase of bottom current activity are thought to be synchronous with the two pronounced late Berriasian-early Valanginian lowstands in sea level. Hypothetically, both phenomena might have been caused by a glaciation on the Antarctic-Australian continent, which was for the first time isolated from the rest of Gondwana by oceanic seaways as a result of Jurassic and Early Cretaceous seafloor spreading. The absence of typical Tethyan radiolarian species during the late Valanginian to late Hauterivian period is interpreted as reflecting a time of strong influx of circumantarctic cold water following oceanization (Mil) and rapid spreading between southeast India and western Australia. The reappearance and gradual increase in abundance and diversity of Tethyan forms along with the still dominant circumantarctic species are thought to result from overall more equitable climatic conditions during the Barremian and early Aptian and may have resulted from the establishment of an oceanic connection with the Tethys Ocean during the early Aptian.

Geochemistry of basalts of the Indian Ocean

Indian Ocean crust formed at Sites 765 and 766 is geochemically comparable to that presently forming in the Red Sea. In both cases, we interpret the crust as reflecting high degrees of mantle melting that are associated with an enhanced thermal gradient below recently rifted continental lithosphere. Asthenospheric melts formed in this environment are rich in CaO and FeO, poor in Na2O and Al2O3, and characterized by depleted rare earth element (REE) profiles ([La/Sm]n approximately 0.5-0.6). Both the Red Sea basalts and the basalts at Sites 765 and 766 are distinct from those erupted at the present Mid-Indian Ocean Ridge. The isotope characteristics of the Site 765 basalts define a geochemical signature similar to that of the present-day Mid-Indian Ocean Ridge basalts (MIORB). The Indian Ocean mantle domain is distinct from that of the Atlantic and Pacific oceans, and this distinction has persisted since Jurassic time, when the Site 765 oceanic crust was formed.

Jurassic to Cretaceous calcareous nannofossils from the Argo Abyssal Plain

A summary of calcareous nannofossil biostratigraphy performed for Late Jurassic (Kimmeridgian) to Early Cretaceous (Hauterivian) cores of Site 765 (Cores 123-765C-58R to -55R) and Site 261 (Cores 27-261-33 to -27), Argo Abyssal Plain, off northwestern Australia is presented. Precise age determinations were limited by variable preservation and the exclusion of a number of marker species due to provincialism. However, the presence of species, such as, Stephanolithion bigotii bigotii, Watznaueria manivitae, Tubodiscus verenae, and Cruciellipsis cuvillieri results in a reasonably good degree of biostratigraphic control. Biogeographic interpretation of the nannofossil data suggests that the Argo Basin occupied a position transitional between the Tethyan and Austral nannofloral realms. A cooler water regime is suggested by the absence of thermophyllic Tethyan forms, such as Nannoconus, and the presence of taxa that display bipolar distribution, such as Crucibiscutum salebrosum. Two new species, Zeugrhabdotus cooperi and Cyclagelosphaera argoensis, and one new combination, Haqius ellipticus are described.

Paleomagnetic of lower Cretaceous sediments from the Argo and Gascoyne Abyssal Plain

Lower Cretaceous sediments were sampled for magnetostratigraphy at three sites. ODP Site 765 and DSDP Site 261, in the Argo Abyssal Plain, consist primarily of brownish-red to gray claystone having hematite and magnetite carriers of characteristic magnetization. ODP Site 766, in the Gascoyne Abyssal Plain, consists mainly of dark greenish-gray volcaniclastic turbidites with magnetite as the carrier of characteristic magnetization. Progressive thermal demagnetization (Sites 765 and 261) or alternating field demagnetization (Site 766) yielded well-defined polarity zones and a set of reliable paleolatitudes. Magnetic polarity chrons were assigned to polarity zones using biostratigraphic correlations. Late Aptian chron M"-1"r, a brief reversed-polarity chron younger than MOr, is a narrow, 40-cm feature delimited in Hole 765C. Early Aptian reversed-polarity chron MOr is also present in Hole 765C. Polarity chrons Mir through M3r were observed in the Barremian of all three sites. Valanginian and Hauterivian polarity chrons can be tentatively assigned to polarity zones only in Hole 766A. The paleolatitude of this region remained at 35° to 37°S from the Berriasian through the Aptian. During this interval, there was approximately 16° of clockwise rotation, with the oriented sample suites of Site 765 displaying a Berriasian declination of 307° to an Aptian declination of 323°. These results are consistent with the interpolated Early Cretaceous apparent polar wander for Australia, but indicate that this region was approximately 5? farther north than predicted.

Geochemistry of Cretaceous sediments from Argo and Gascoyne Abyssal Plains

The accumulation of organic matter, ferrous and pyrite iron, and the ratios of organic carbon/total sulfur and organic carbon/total phosphorus in the Lower Cretaceous sediments from the Argo and Gascoyne abyssal plains have been used as indicators of both the source and reactivity of organic matter in the sediments and the depositional environment. Total sulfur, used as an indicator of pyrite sulfur, is more abundant in sediments from the Gascoyne Abyssal Plain than in those from the Argo Abyssal Plain. Sulfur positively correlates with TOC at both sites (although poorly at the Argo Abyssal Plain site, R = 0.48), with an extension of the line of best-fit through the origin, indicating that pyrite (TOC <2 wt%) is diagenetic and deposited from normal marine conditions. The average ratio of C/S for samples of TOC <2 wt% is 5.4 at Argo Abyssal Plain (compared to the modern normal marine value of 2.8) indicating deposition of organic matter probably of mixed terrestrial and oxidized marine sources that is unreactive to the sulfate-reducing bacteria. One sample from the Aptian sediments is rich in TOC (5.1 wt%) and has a C/S ratio of 0.5. The average C/S ratio in Gascoyne Abyssal Plain sediments is 0.8 (R = 0.97), which indicates the formation of abundant pyrite in addition to burial and preservation of relatively fresh organic matter that is reactive to the sulfate-reducing bacteria. Organic carbon to phosphorus ratios (C/P) in the sediments indicate preferential remobilization of organic carbon over phosphorus with increasing water depth. Estimates of the degree of pyritization (DOP) increase with increasing TOC at both sites, indicating iron is not limiting and pyrite is formed diagenetically. The one sample with a TOC content of 5.1 wt%, from the Argo Abyssal Plain near the Barremian-Aptian boundary, is composed mostly of framboidal pyrite, finely laminated and not bioturbated, and hence may have been deposited during a brief period of anoxia in the overlying waters.

Chemistry of earliest Cretaceous bentonites

Bentonites (i.e., smectite-dominated, altered volcanic ash layers) were discovered in Berriasian to Valanginian hemipelagic (shelfal) to eupelagic (deep-sea) sediments of the Wombat Plateau (Site 761), Argo Abyssal Plain (Sites 261, 765), southern Exmouth Plateau (Site 763), and Gascoyne Abyssal Plain (Site 766). A volcaniclastic origin with trachyandesitic to rhyolitic ash as parent material is proved by the abundance of well-ordered montmorillonite, fresh to altered silicic glass shards, volcanogenic minerals (euhedral sanidine, apatite, slender zircon), and rock fragments, and by a vitroclastic ultra-fabric (smectitized glass shards). For the Argo Abyssal Plain, we can distinguish four types of bentonitic claystones of characteristic waxy appearance: (1) pure smectite bentonites, white to light gray, sharp basal contacts, and a homogeneous cryptocrystalline smectite matrix, (2) thin, greenish-gray bentonitic claystones having sharp upper and lower contacts, (3) gray-green bentonitic claystones mottled with background sedimentation and a distinct amount of terrigenous and pelagic detrital material, and (4) brick-red smectitic claystones having diffuse sedimentary contacts and a doubtful volcanic origin. For the other drill sites, we can distinguish between (1) pure bentonitic claystones similar in appearance and chemical composition to Type 1 of the Argo Abyssal Plain (except for gradual basal contacts) and (2) impure bentonitic claystones containing textures of volcanogenic smectite and pyroclastic grains with terrigenous and pelagic components resulting from resedimentation or bioturbation. The ash layers were progressively altered (smectitized) during diagenesis. Silicic glass was first hydrated, then slightly altered (etched with incipient smectite authigenesis), then moderately smectitized (with shard shape still intact), and finally, completely homogenized to a pure smectite matrix without obvious relict structures. Volcanic activity was associated with continental breakup and rapid subsidence during the "juvenile ocean phase." Potential source areas for a Neocomian post-breakup volcanism include Wombat Plateau, Joey and Roo rises, Scott Plateau, and Wallaby Plateau/Cape Range Fracture Zone. Westward-directed trade winds transported silicic ash from these volcanic source areas to the Exmouth Plateau and, via turbidity currents, into the adjacent abyssal plains. The Wombat and Argo abyssal plain bentonites are interpreted, at least in parts, as proximal or distal ash turbidites, respectively.