352 resultados para (2R)-taxiphyllin


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In this thesis we study Galois representations corresponding to abelian varieties with certain reduction conditions. We show that these conditions force the image of the representations to be "big," so that the Mumford-Tate conjecture (:= MT) holds. We also prove that the set of abelian varieties satisfying these conditions is dense in a corresponding moduli space.

The main results of the thesis are the following two theorems.

Theorem A: Let A be an absolutely simple abelian variety, End° (A) = k : imaginary quadratic field, g = dim(A). Assume either dim(A) ≤ 4, or A has bad reduction at some prime ϕ, with the dimension of the toric part of the reduction equal to 2r, and gcd(r,g) = 1, and (r,g) ≠ (15,56) or (m -1, m(m+1)/2). Then MT holds.

Theorem B: Let M be the moduli space of abelian varieties with fixed polarization, level structure and a k-action. It is defined over a number field F. The subset of M(Q) corresponding to absolutely simple abelian varieties with a prescribed stable reduction at a large enough prime ϕ of F is dense in M(C) in the complex topology. In particular, the set of simple abelian varieties having bad reductions with fixed dimension of the toric parts is dense.

Besides this we also established the following results:

(1) MT holds for some other classes of abelian varieties with similar reduction conditions. For example, if A is an abelian variety with End° (A) = Q and the dimension of the toric part of its reduction is prime to dim( A), then MT holds.

(2) MT holds for Ribet-type abelian varieties.

(3) The Hodge and the Tate conjectures are equivalent for abelian 4-folds.

(4) MT holds for abelian 4-folds of type II, III, IV (Theorem 5.0(2)) and some 4-folds of type I.

(5) For some abelian varieties either MT or the Hodge conjecture holds.

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In the quest to develop viable designs for third-generation optical interferometric gravitational-wave detectors, one strategy is to monitor the relative momentum or speed of the test-mass mirrors, rather than monitoring their relative position. The most straightforward design for a speed-meter interferometer that accomplishes this is described and analyzed in Chapter 2. This design (due to Braginsky, Gorodetsky, Khalili, and Thorne) is analogous to a microwave-cavity speed meter conceived by Braginsky and Khalili. A mathematical mapping between the microwave speed meter and the optical interferometric speed meter is developed and used to show (in accord with the speed being a quantum nondemolition observable) that in principle the interferometric speed meter can beat the gravitational-wave standard quantum limit (SQL) by an arbitrarily large amount, over an arbitrarily wide range of frequencies . However, in practice, to reach or beat the SQL, this specific speed meter requires exorbitantly high input light power. The physical reason for this is explored, along with other issues such as constraints on performance due to optical dissipation.

Chapter 3 proposes a more sophisticated version of a speed meter. This new design requires only a modest input power and appears to be a fully practical candidate for third-generation LIGO. It can beat the SQL (the approximate sensitivity of second-generation LIGO interferometers) over a broad range of frequencies (~ 10 to 100 Hz in practice) by a factor h/hSQL ~ √W^(SQL)_(circ)/Wcirc. Here Wcirc is the light power circulating in the interferometer arms and WSQL ≃ 800 kW is the circulating power required to beat the SQL at 100 Hz (the LIGO-II power). If squeezed vacuum (with a power-squeeze factor e-2R) is injected into the interferometer's output port, the SQL can be beat with a much reduced laser power: h/hSQL ~ √W^(SQL)_(circ)/Wcirce-2R. For realistic parameters (e-2R ≃ 10 and Wcirc ≃ 800 to 2000 kW), the SQL can be beat by a factor ~ 3 to 4 from 10 to 100 Hz. [However, as the power increases in these expressions, the speed meter becomes more narrow band; additional power and re-optimization of some parameters are required to maintain the wide band.] By performing frequency-dependent homodyne detection on the output (with the aid of two kilometer-scale filter cavities), one can markedly improve the interferometer's sensitivity at frequencies above 100 Hz.

Chapters 2 and 3 are part of an ongoing effort to develop a practical variant of an interferometric speed meter and to combine the speed meter concept with other ideas to yield a promising third- generation interferometric gravitational-wave detector that entails low laser power.

Chapter 4 is a contribution to the foundations for analyzing sources of gravitational waves for LIGO. Specifically, it presents an analysis of the tidal work done on a self-gravitating body (e.g., a neutron star or black hole) in an external tidal field (e.g., that of a binary companion). The change in the mass-energy of the body as a result of the tidal work, or "tidal heating," is analyzed using the Landau-Lifshitz pseudotensor and the local asymptotic rest frame of the body. It is shown that the work done on the body is gauge invariant, while the body-tidal-field interaction energy contained within the body's local asymptotic rest frame is gauge dependent. This is analogous to Newtonian theory, where the interaction energy is shown to depend on how one localizes gravitational energy, but the work done on the body is independent of that localization. These conclusions play a role in analyses, by others, of the dynamics and stability of the inspiraling neutron-star binaries whose gravitational waves are likely to be seen and studied by LIGO.

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The problem of global optimization of M phase-incoherent signals in N complex dimensions is formulated. Then, by using the geometric approach of Landau and Slepian, conditions for optimality are established for N = 2 and the optimal signal sets are determined for M = 2, 3, 4, 6, and 12.

The method is the following: The signals are assumed to be equally probable and to have equal energy, and thus are represented by points ṡi, i = 1, 2, …, M, on the unit sphere S1 in CN. If Wik is the halfspace determined by ṡi and ṡk and containing ṡi, i.e. Wik = {ṙϵCN:| ≥ | ˂ṙ, ṡk˃|}, then the Ʀi = ∩/k≠i Wik, i = 1, 2, …, M, the maximum likelihood decision regions, partition S1. For additive complex Gaussian noise ṅ and a received signal ṙ = ṡie + ṅ, where ϴ is uniformly distributed over [0, 2π], the probability of correct decoding is PC = 1/πN ∞/ʃ/0 r2N-1e-(r2+1)U(r)dr, where U(r) = 1/M M/Ʃ/i=1 Ʀi ʃ/∩ S1 I0(2r | ˂ṡ, ṡi˃|)dσ(ṡ), and r = ǁṙǁ.

For N = 2, it is proved that U(r) ≤ ʃ/Cα I0(2r|˂ṡ, ṡi˃|)dσ(ṡ) – 2K/M. h(1/2K [Mσ(Cα)-σ(S1)]), where Cα = {ṡϵS1:|˂ṡ, ṡi˃| ≥ α}, K is the total number of boundaries of the net on S1 determined by the decision regions, and h is the strictly increasing strictly convex function of σ(Cα∩W), (where W is a halfspace not containing ṡi), given by h = ʃ/Cα∩W I0 (2r|˂ṡ, ṡi˃|)dσ(ṡ). Conditions for equality are established and these give rise to the globally optimal signal sets for M = 2, 3, 4, 6, and 12.

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鹿角蕨(Platycerium wallichii Hook.)是鹿角蕨科鹿角蕨属植物,为国家二级保护植物。该植物主要分布在云南西南部盈江县那邦坝,在当地用作跌打药。有关鹿角蕨属的系统关系存在一些假设,关于鹿角蕨属植物化学成分及生物活性的研究未见报道。从鹿角蕨(Platycerium wallichii Hook.)叶95%乙醇提取物中,我们分离得到了七个已知化合物。根据理化常数及波谱数据 (IR、UV、MS及NMR),其结构分别鉴定为:(I)β一谷甾醇、(II)胡萝卜甙、 (III)2-propenoic acid,3一[(2R, 3S)-2,3-dihydro-2- (4-hydroxy-3-methoxyphenyl) -3- (hydroxymethyl) -7-mnethoxy-5-benzofuranyll -、(Ⅳ)松脂素-4’-0-β -D-葡萄糖甙、(v)松腊素、(Ⅵ)2,5_二羟基苯甲酸甲酯、(Ⅶ)槲皮素3-0-β -半乳糖甙。七个成分均为首次从该种植物中获得。 我们对鹿角蕨(Platvcerium wallichii Hook.)能育叶部分以及基生叶部分的乙醇提取物进行了镇痛试验和抗炎试验,试验表明鹿角蕨(Platvcerium wallichii Hook.)的叶有弱镇痛作用。

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A wavelength conversion device was demonstrated at the bit rate of 2.488 Gb/s with 2R (reamplification and reshaping) regenerative properties. A low frequency pilot tone was removed during the conversion process and a new one added. The wavelength converter is shown to operate well at 10 Gb/s, and tone identification/replacement should also be possible at this data rate.

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An integrated semiconductor optical amplifier/distributed feedback (SOA/DFB) laser that show promise as a simple all-optical wavelength conversion device together with useful simultaneous functions such as 2R regeneration and the ability to remove a wavelength identifying tone is presented. Wavelength conversion performance at 20Gb/s and 40Gb/s can be obtained with this laser.

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壳聚糖是一种天然的聚阳离子氨基多糖,由甲壳素经脱乙酰反应得到。作为天然可再生资源,壳聚糖以其特有的安全无毒、可生物降解、生物相容等特性,在农业、生物工程、制药、环保等领域引起广泛关注。随着对壳聚糖研究的不断深入,壳聚糖的抑菌活性及机理成为研究热点之一,但是,大多集中于壳聚糖分子量和脱乙酰度对其抑菌活性的影响,而对壳聚糖衍生物的抑菌性能及机理研究较少。本文合成了N–季铵盐,N,O–季铵盐,羧甲基壳聚糖希夫碱及其铜配合物,壳聚糖有机酸盐,并对它们的抑菌活性进行了研究,同时探讨了引入基团与抑菌活性之间的关系。 测定了壳聚糖及其季铵盐对黄瓜枯萎病菌、黄瓜炭疽病菌和桃褐腐病菌的抑制活性,结果表明壳聚糖季铵盐的抑制活性高于壳聚糖,其中,抑制活性最强的是N–异丁基–N,N–二甲基壳聚糖,当样品浓度为500μg/mL时,对三种病原菌的抑制率分别为:67.52%、70.42%和76.25%。壳聚糖分子带正电荷的氨基可以与菌体表面带负电的物质作用,导致菌体死亡,而壳聚糖季铵盐分子中的正电性可以加强这种作用,从而增强抑菌活性,而且随着正电性的增强,抑菌活性增强。 为了进一步研究壳聚糖季铵盐的正电性与其抑菌活性的关系,合成了含有氟、溴、氯吸电子基团苯环取代的壳聚糖季铵盐,通过计算分别得到取代基团的电负性以及氨基正电性。结果表明,随着取代基团电负性的增强,季铵盐氨基正电性增强,抑菌活性增强。其中,抑菌活性最强的是N–(2–氟)苄基–N,N–二甲基壳聚糖,当样品浓度为500μg/mL时,对三种病原菌的抑制率分别为:80.85%、100%和100%。 将壳聚糖的–NH2与有机酸的–H通过离子键结合制备得到了系列的固态壳聚糖有机酸盐:壳聚糖甲酸盐、壳聚糖乙酸盐、壳聚糖丙酸盐、壳聚糖丁酸盐和壳聚糖戊酸盐,抑菌活性结果表明,随着衍生物链长的增加,抑菌活性增强,而且衍生物抑菌活性与取代基团的电负性成正相关。 以羧甲基壳聚糖为原料,合成了羧甲基壳聚糖希夫碱及其铜配合物,各类衍生物的抑菌活性强弱顺序如下:羧甲基壳聚糖希夫碱铜配合物>羧甲基壳聚糖希夫碱>羧甲基壳聚糖,从而说明了基团的相互增效作用能增强衍生物的抑菌活性。 以N–季铵盐为原料,以环氧丙基三甲基氯化铵为改性剂合成了具有–N+(CH3)2R和–N+(CH3)3两种基团的N,O–季铵盐,抑菌活性结果表明,N,O–季铵盐的抑菌活性

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观察了新近发现于我国云南的果蝇属暗果蝇种组( Drosophila obscura species group ) 种类 D1luguensis 、D1 dianensis 和D1limingi 的有丝分裂中期核型, 并将3 个种的核型与各自的近缘种类进行了比较。 D1luguensis 具2n = 12 条染色体, 包括3 对中央着丝粒(V 形) 染色体、2 对近端着丝粒(棒状) 染色体以及1 对微小(点状) 染色体。其中X 和Y染色体均为中央着丝粒染色体。D1 dianensis 和D1limingi 具2n = 10 条染 色体, 包括1 对大的V 形常染色体, 1 对小的V 形常染色体, 2 对J 形(亚中着丝粒型) 常染色体和1 对点状染 色体。其中X 染色体为J 形, Y染色体为短棒状。基于核型比较的结果以及D1sinobscura 亚组地理分布的资料, 结合种间系统发育关系研究结果, 认为D1 luguensis 可能保留了该亚组祖先种类的核型。D1sinobscura 的核型(2n = 12 : 2V , 1J , 2R , 1D) 可能由一个pre2“sinobscura2hubeiensis”谱系的一个分支通过臂间倒位演化而来, 而D1 hubeiensis 的核型(2n = 10 : 4V , 1D) 可能由该谱系的另一分支通过着丝粒融合(2 对近端着丝粒常染色 体的融合) 而形成。推测在D1 dianensis 和近缘欧洲种D1subsilvestris (2n = 12 : 3V , 2R , 1D) 间、D1limingi 和 东亚近缘种D1tsukubaensis (2n = 12 : 3V , 2R , 1D) 间的物种分化过程中, 可能有相似的染色体变异类型发生。

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Five models for human interleukin-7 (HIL-7), HIL-9, HIL-13, HIL-15 and HIL-17 have been generated by SYBYL software package. The primary models were optimized using molecular dynamics and molecular mechanics methods. The final models were optimized using a steepest descent algorithm and a subsequent conjugate gradient method. The complexes with these interleukins and the common gamma chain of interleukin-2 receptor (IL-2R) were constructed and subjected to energy minimization. We found residues, such as Gln127 and Tyr103, of the common gamma chain of IL-2R are very important. Other residues, e.g. Lys70, Asn128 and Glu162, are also significant. Four hydrophobic grooves and two hydrophilic sites converge at the active site triad of the gamma chain. The binding sites of these interleukins interaction with the common gamma chain exist in the first helical and/or the fourth helical domains. Therefore, we conclude that these interleukins binds to the common gamma chain of IL-2R by the first and the fourth helix domain. Especially at the binding sites of some residues (lysine, arginine, asparagine, glutamic acid and aspartic acid), with a discontinuous region of the common gamma chain of IL-2R, termed the interleukins binding sites (103-210). The study of these sites can be important for the development of new drugs. (C) 2000 Elsevier Science B.V. All rights reserved.

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Kolmogorov's two-thirds, ((Δv) 2) ∼ e 2/ 3r 2/ 3, and five-thirds, E ∼ e 2/ 3k -5/ 3, laws are formally equivalent in the limit of vanishing viscosity, v → 0. However, for most Reynolds numbers encountered in laboratory scale experiments, or numerical simulations, it is invariably easier to observe the five-thirds law. By creating artificial fields of isotropic turbulence composed of a random sea of Gaussian eddies whose size and energy distribution can be controlled, we show why this is the case. The energy of eddies of scale, s, is shown to vary as s 2/ 3, in accordance with Kolmogorov's 1941 law, and we vary the range of scales, γ = s max/s min, in any one realisation from γ = 25 to γ = 800. This is equivalent to varying the Reynolds number in an experiment from R λ = 60 to R λ = 600. While there is some evidence of a five-thirds law for g > 50 (R λ > 100), the two-thirds law only starts to become apparent when g approaches 200 (R λ ∼ 240). The reason for this discrepancy is that the second-order structure function is a poor filter, mixing information about energy and enstrophy, and from scales larger and smaller than r. In particular, in the inertial range, ((Δv) 2) takes the form of a mixed power-law, a 1+a 2r 2+a 3r 2/ 3, where a 2r 2 tracks the variation in enstrophy and a 3r 2/ 3 the variation in energy. These findings are shown to be consistent with experimental data where the polution of the r 2/ 3 law by the enstrophy contribution, a 2r 2, is clearly evident. We show that higherorder structure functions (of even order) suffer from a similar deficiency.

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This study investigates the structural behavior of precracked reinforced concrete (RC) T-beams strengthened in shear with externally bonded carbon fiber-reinforced polymer (CFRP) sheets. It reports on seven tests on unstrengthened and strengthened RC T-beams, identifying the influence of load history, beam depth, and percentage of longitudinal steel reinforcement on the structural behavior. The experimental results indicate that the contributions of the external CFRP sheets to the shear force capacity can be significant and depend on most of the investigated variables. This study also investigates the accuracy of the prediction of the fiber-reinforced polymer (FRP) contribution in ACI 440.2R-08, UK Concrete Society TR55, and fib Bulletin 14 design guidelines for shear strengthening. A comparison of predicted values with experimental results indicates that the guidelines can overestimate the shear contribution of the externally bonded FRP system. © 2012, American Concrete Institute.

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The Hamiltonian in the framework of eight-band effective-mass approximation of the zinc-blende nanowires and nanorods in the presence of external homogeneous magnetic field is given in the cylindrical coordinate. The electronic structure, optical properties, magnetic energy levels, and g factors of the nanowires and nanorods are calculated. It is found that the electron states consist of many hole-state components, due to the coupling of the conduction band and valence band. For the normal bands which are monotone functions of |k(z)|, long nanorods can be modeled by the nanowires, the energy levels of the nanorods approximately equal the values of the energy band E(k(z)) of the nanowires with the same radius at a special k(z), where k(z) is the wave vector in the wire direction. Due to the coupling of the states, some of the hole energy bands of the nanowires have their highest points at k(z)=0. Especially, the highest hole state of the InSb nanowires is not at the k(z)=0 point. It is an indirect band gap. For these abnormal bands, nanorods can not be modeled by the nanowires. The energy levels of the nanorods show an interesting plait-like pattern. The linear polarization factor is zero, when the aspect ratio L/2R is smaller than 1, and increases as the length increases. The g(z) and g(x) factors as functions of the k(z), radius R and length L are calculated for the wires and rods, respectively. For the wires, the g(z) of the electron ground state increases, and the g(z) of the hole ground state decreases first, then increases with the k(z) increasing. For the rods, the g(z) and g(x) of the electron ground state decrease as the R or the L increases. The g(x) of the hole ground state decreases, the g(z) of the hole ground state increases with the L increasing. The variation of the g(z) of the wires with the k(z) is in agreement with the variation of the g(z) of the rods with the L.

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本工作对环形聚苯乙烯的溶液性质作了系统研究。工作中运用了各种溶液性质的研究方法如激光光散射、凝胶色谱和溶液粘度。对不同分子量(1 * 10~4 ~ 2.3 * 10~5)的窄分布环形聚苯乙烯样品在良溶剂甲苯,不良溶剂丁酮以及不同温度的环已烷中第二维利系数的测定发现,在良溶剂中环形聚苯乙烯的第二维利系数小于线形聚苯乙烯,在不良溶剂中两者第二维利系数相近,而环形聚苯乙烯在环已烷中的θ温度为30 ℃,比线形聚苯乙烯的θ温度低4.5 ℃。这些结果表明环形聚苯乙烯分子间排斥体积效应小于线形分子,而分子内排斥体积效应略大于线形分子。环形聚苯乙烯在甲苯(25 ℃)和丁酮(25 ℃)中的第二维利系数与分子量的关系分别为甲苯 A_(2r) = 1.28 * 10~(-2) (M-bar)_w~(-0.283)丁酮 A_Z(2r) = 5.06 * 10~(-3) (M-bar)_w~(-0.273)通过测定环形聚苯乙烯系列样品在θ溶剂,良溶剂和不良溶剂中的特性粘数,确定了环形聚苯乙烯在多种溶剂中的Mark-Houwink方程,在θ溶剂中的Mark-Houwink方程为[η]_r = 5.102 * 10~(-2) (M-bar)_w~(0.508) 环已烷30 ℃应用粘度结果讨论了环形聚苯乙烯的粘度扩展因子、等效球半径,均方回转半径以及穿流效应,并与线形聚苯乙烯作了比较。

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本论文由三章组成。第一章阐述了藏药水菖蒲的化学成分研究,共分离鉴定了39个化学成分,其中6个为新化合物。第二章报道了几种忍冬属植物的HPLC、HPLC-MS、GC分析以及抑菌活性、重金属含量测定结果。第三章概述了菖蒲属植物的研究进展。 第一章报道了水菖蒲(Acorus calamus L.)化学成分的分离纯化与结构鉴定。采用正、反相硅胶柱层析等分离方法,从水菖蒲的根中共分离出41个化合物,通过红外、质谱、核磁共振及X-ray单晶衍射等波谱方法和模拟计算方法鉴定了其中39个化合物的结构,主要为倍半萜、苯丙素、甾体类化合物。其中含有5个新的倍半萜类化合物和1系列新的甾体皂苷衍生物。经波谱分析将它们的结构鉴定为 1b, 7a(H)-cadinane-4a, 6a, 10a-triol (1), (2R,6R,7S,9S)-1(10), 4-cadinadiene-2, 9-diol (2), 1a, 5b-guaiane-10a-O-ethyl-4b, 6b-diol (7), 6b, 7b(H)-cadinane-1a, 4a, 10a-triol (13),(1R,4R,6S,10R)-1-hydroxy-7(11)-cadinen-5, 8-dione (14), 4′-O-正n碳酰基-3-O- β-D-葡萄糖基谷甾醇(n=14, 16, 18, 22) (15)。 第二章包括四个部分。第一部分报道了忍冬属三种植物40个样品的HPLC测定和对主要活性成分绿原酸的定量分析结果,以及运用HPLC-MS技术对色谱图中8个峰进行指认。在此基础上,考察了种植和采收多个因素对绿原酸含量的影响。第二部分报道了忍冬属三种植物27个样品的GC分析,根据样品的挥发性成分的保留时间对不同样品进行了定性比较,并考察了花期及海拔高度对植物挥发性成分的影响。第三、四部分分别阐述了灰毡毛忍冬和红腺忍冬的体外抑菌活性研究和重金属含量测定结果。 第三章全面系统地概述了菖蒲属植物的化学成分和药理活性研究进展。 This dissertation is composed by three chapters. The first chapter elaborates the phytochemical investigation of Acorus calamus L. Thirty-nine compounds including six new compounds were isolated and identified. The second chapter reports the research on genus Lonicera by HPLC, HPLC-MS and GC. Antifungal activity and heavy metals measurement of genus Lonicera were reported. The third chapter is a review about the research progress on the plant family of Acorus. The first chapter focuses on the isolation and identification of chemical constituents from Acorus calamus L.. Forty-one compounds were isolated from the root of Acorus calamus L. by repeat column chromatography over normal and reversed phase silica gel, the structure of thirty-nine compounds was identified by spectroscopic methods and computational methods, including IR, MS, NMR and X-ray. Those compounds mainly belonged to sesquiterpene, phenylpropanoid and steroid. Among them, five are new sesquiterpenes and one series are new steroid glycoside derivatives. Their structure were suggested as 1b, 7a(H)-cadinane-4a, 6a, 10a-triol (1), (2R,6R,7S,9S)-1(10), 4-cadinadiene-2, 9-diol (2), 1a, 5b-guaiane-10a-O-ethyl-4b, 6b- diol (7), 6b, 7b(H)-cadinane-1a, 4a, 10a-triol (13), (1R,4R,6S,10R)-1-hydroxy-7(11)- cadinen-5, 8-dione (14), 4′-O-carbonyl-3-O-β-D-glucosyl-sitosterol (carbonyl = tetradecanoyl, hexadecanoyl, octadecyl, docosanoyl) (15). The second chapter consists of four parts. The first part reports the HPLC analysis of forty samples of the genus Lonicera, and the quantitative investigation of chlorogenic acid in these samples by HPLC analysis. Relationship between the content of chlorogenic acid in different samples and their planting conditions and harvesting time were discussed. Furthermore, eight compounds were identified or tentatively characterized based on their mass spectra and UV spectra profiles. The second part is about qualitative analysis of the volatile constituent in twenty-seven samples of genus Lonicera by GC. The effect of planting altitude and harvesting time on the volatile constituent was also investigated. The third and fourth parts describe the antifungal activity and content of some kinds of heavy metals of L. macranthoides Hand.-Mazz. and L. hypoglauca Miq.. The third chaspter is a review about the research progress of the plant family of Acorus.

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本文对禄春安息香(Styrax macranthus)种子和攀援孔药花(Porandra scandens)全草的化学成分进行了研究,共获得30个化合物,其中2个为新化合物。 从禄春安息香种子95%乙醇提取物中分离并鉴定了12个化合物,其中2个新化合物鉴定为3-[7-methoxy-2-(3,4-methylenedioxy phenyl) benzofuran-5-yl] propyl 3-[7-methoxy-2-(3,4-methylenedioxyphenyl)benzofuran-5-yl] propanoate (1) 和去甲氧基-egonol-龙胆双糖甙 (2);已知化合物分别为2-(3,4-二氧亚甲基苯基)-5-甲酰基-7-甲氧基-苯并呋喃 (3)、egonol (4)、去甲氧基-egonol (5)、去甲基-egonol (6)、egonol-葡萄糖甙 (7)、egonol-龙胆双糖甙 (8)、egonol-龙胆三糖甙 (9)、豆甾醇 (10)、二十四烷酸 1-甘油酯 (11) 和胡萝卜甙 (12)。生物活性测试发现,化合物2具有促进雌激素E2合成的作用。 从攀援孔药花全草95%乙醇提取物中分离并鉴定了19个化合物:(2S,3S,4R)-2-[(2R)-2-羟基-二十一烷酰基氨基]-二十一烷-1,3,4-三醇 (13)、(2S,3S,4R)–2–二十四烷酰基氨基-十八烷-1,3,4-三醇 (14)、胡萝卜甙 (12)、β-谷甾醇 (15)、(20S,22E,24R)-5α,8α-表二氧-麦角甾-6,22-二烯-3β-醇 (16)、6β-羟基-豆甾-4-烯-3-酮 (17)、十六烷酸 1-甘油酯 (18)、桦木酸 (19)、大黄素 (20)、二十二烷酸 1-甘油酯 (21)、对羟基苯甲醛 (22)、十七烷酸 1-甘油酯 (23)、金色酰胺醇乙酸酯(24)、十九烷酸 1-甘油酯 (25)、棕榈酸 (26)、(E)-p-香豆酸 (27)、(22E,24S)-24-麦角甾醇-7,22-二烯-3β,5α,6β-三醇 (28)、2-去氧-β-蜕皮激素 (29)和auranamide (30)。 综述了近十年来发现的2-芳基苯并呋喃类新木脂素的结构特征、来源、生物活性和化学全合成。 Phytochemical investigation on the seeds of Styrax macranthus and the whole plants of Porandra scandens led to the isolation of thirty compounds, two of which were new ones. Two new 2-aryl benzofuran derivatives, 3-[7-methoxy-2-(3,4-methylenedioxy phenyl) benzofuran-5-yl]propyl 3-[7-methoxy-2-(3,4-methylenedioxyphenyl)benzo furan-5-yl]propanoate (1) and demethoxy egonol gentiobioside (2), were isolated from the 95% aqueous ethanolic extract of the seeds of Styrax macranthus, together with 7-methoxy-2-(3,4-methylenedioxyphenyl) benzofuran-5-carbaldehyde (3), egonol (4), demethoxy egonol (5), demethyl egonol (6), egonol glucoside (7), egonol gentiobioside (8), egonol gentiotrioside (9), stigmasterol (10), 2,3-dihydroxypropyl tetracosoate (11), and daucosterol (12). In vitro test, compound 2 promote the synthesis of estrogen E2. Nineteen compounds were isolated from the 95% aqueous ethanolic extract of the whole plant of Porandra scandens for the first time. Their structures were identified as (2S,3S,4R)-2-[(2R)-2-hydroxy-heneicosanoylamino]-1,3,4- heneicosanetriol (13), (2S,3S,4R)-2-tetracosanoylamino-1,3,4-octadecanetriol (14), daucosterol (15), β-sitosterol (12), (20S,22E,24R)-5α,8α-epidioxy-ergosta-6,22-diene- 3β-ol (16), 6β-hydroxylstigmast-4-en-3-one (17), 1-glycerol-1-hexadecoate (18), betulinic acid (19), emodin (20), 1-glycerol-1-docosoate (21), p-hydroxybenzaldehyde (22), 1-glycerol-1-heptadecoate (23), aurantiamide acetate (24), 1-glycerol-1- nonadecoate (25), palmatic acid (26), (E)-p-coumaric acid (27), (22E,24S)- 24-metbylcbolesta-7,22-diene-3β,5α,6β-triol (28), 2-deoxycrustecdysone (29), and auranamide (30). The characteristic, natural resource, bioactivity, and the total synthesis of 2-aryl benzofurans were reviewed.