MoO3 nanoparticles dispersed uniformly in carbon matrix : a high capacity composite anode for Li-ion batteries

A MoO₃-carbon nanocomposite was synthesized from a mixture of MoO₃ and graphite by a controlled ball milling procedure. The as-prepared product consists of nanosized MoO₃ particles (2-180 nm) homogeneously distributed in carbon matrix. The nanocomposite acts as a high capacity anode material for lithium-ion batteries and exhibits good cyclic behavior. Its initial capacity exceeds the theoretical capacity of 745 mA h g^-1 in a mixture of MoO₃ and graphite (1:1 by weight), and the stable capacity of 700 mA h g^-1 (94% of the theoretical capacity) is still retained after 120 cycles. The electrode performance is linked with the unique nanoarchitecture of the composite and is compared with the performance of MoO₃-based anode materials reported in the literature previously (nanoparticles, ball milled powders, and carbon-coated nanobelts). The high value of capacity and good cyclic stability of MoO₃-carbon nanocomposite are attractive in respect to those of the reported MoO₃ electrodes.<br />

A discussion on the process of defining 2-D separation selectivity

In this manuscript, we investigate the importance that must be placed on the selection of standard compounds when undertaking studies to optimize the performance of 2-D-HPLC separations. A geometric approach to factor analysis and a measure of peak density across the separation space were applied to assess localized measures of component distributions within the 2-D separation plane. The results of this analysis of data showed that the measure of separation quality varied markedly, depending on the elution zone for which the test was undertaken. The study concluded that if standards cannot be obtained that adequately describe the entire sample matrix, the sample itself should be used, and also, the separation should be optimized for regions of interest, not necessarily the separation as a whole.<br />

Nonnegative Matrix Factorization Applied to Nonlinear Speech and Image Cryptosystems

Nonnegative matrix factorization (NMF) is widely used in signal separation and image compression. Motivated by its successful applications, we propose a new cryptosystem based on NMF, where the nonlinear mixing (NLM) model with a strong noise is introduced for encryption and NMF is used for decryption. The security of the cryptosystem relies on following two facts: 1) the constructed multivariable nonlinear function is not invertible; 2) the process of NMF is unilateral, if the inverse matrix of the constructed linear mixing matrix is not nonnegative. Comparing with Lin's method (2006) that is a theoretical scheme using one-time padding in the cryptosystem, our cipher can be used repeatedly for the practical request, i.e., multitme padding is used in our cryptosystem. Also, there is no restriction on statistical characteristics of the ciphers and the plaintexts. Thus, more signals can be processed (successfully encrypted and decrypted), no matter they are correlative, sparse, or Gaussian. Furthermore, instead of the number of zero-crossing-based method that is often unstable in encryption and decryption, an improved method based on the kurtosis of the signals is introduced to solve permutation ambiguities in waveform reconstruction. Simulations are given to illustrate security and availability of our cryptosystem.

Versican processing by a disintegrin-like and metalloproteinase domain with thrombospondin-1 repeats proteinases-5 and -15 facilitates myoblast fusion

Skeletal muscle development and regeneration requires the fusion of myoblasts into multinucleated myotubes. Because the enzymatic proteolysis of a hyaluronan and versican-rich matrix by ADAMTS versicanases is required for developmental morphogenesis, we hypothesized that the clearance of versican may facilitate the fusion of myoblasts during myogenesis. Here, we used transgenic mice and an in vitro model of myoblast fusion, C2C12 cells, to determine a potential role for ADAMTS versicanases. Versican processing was observed during in vivo myogenesis at the time when myoblasts were fusing to form multinucleated myotubes. Relevant ADAMTS genes, chief among them Adamts5 and Adamts15, were expressed both in developing embryonic muscle and differentiating C2C12 cells. Reducing the levels of Adamts5 mRNA in vitro impaired myoblast fusion, which could be rescued with catalytically active but not the inactive forms of ADAMTS5 or ADAMTS15. The addition of inactive ADAMTS5, ADAMTS15, or full-length V1 versican effectively impaired myoblast fusion. Finally, the expansion of a hyaluronan and versican-rich matrix was observed upon reducing the levels of Adamts5 mRNA in myoblasts. These data indicate that these ADAMTS proteinases contribute to the formation of multinucleated myotubes such as is necessary for both skeletal muscle development and during regeneration, by remodeling a versican-rich pericellular matrix of myoblasts. Our study identifies a possible pathway to target for the improvement of myogenesis in a plethora of diseases including cancer cachexia, sarcopenia, and muscular dystrophy.

Matrix-based pairwise key establishment in wireless mesh networks using deployment knowledge

Due to the nature of wireless transmission, communication in wireless mesh networks (WMNs) is vulnerable to many adversarial activities including eavesdropping. Pairwise key establishment is one of the fundamental issues in securing WMNs. This paper presents a new matrix-based pairwise key establishment scheme for mesh clients. Our design is motivated by the fact that in WMNs, mesh routers are more powerful than mesh clients, both in computation and communication. By exploiting this heterogeneity, expensive operations can be delegated to mesh routers, which help alleviate the overhead of mesh clients during key establishment. The new scheme possesses two desirable features: (1) Neighbor mesh clients can directly establish pairwise keys; and (2) Communication and storage costs at mesh clients are significantly reduced.

Potassium channel modulation by a toxin domain in matrix metalloprotease

Peptide toxins found in a wide array of venoms block K+ channels, causing profound physiological and pathological effects. Here we describe the first functional K+ channel-blocking toxin domain in a mammalian protein. MMP23 (matrix metalloprotease 23) contains a domain (MMP23TxD) that is evolutionarily related to peptide toxins from sea anemones. MMP23TxD shows close structural similarity to the sea anemone toxins BgK and ShK. Moreover, this domain blocks K+ channels in the nanomolar to low micromolar range (Kv1.6 &gt; Kv1.3 &gt; Kv1.1 = Kv3.2 &gt; Kv1.4, in decreasing order of potency) while sparing other K+ channels (Kv1.2, Kv1.5, Kv1.7, and KCa3.1). Full-length MMP23 suppresses K+ channels by co-localizing with and trapping MMP23TxD-sensitive channels in the ER. Our results provide clues to the structure and function of the vast family of proteins that contain domains related to sea anemone toxins. Evolutionary pressure to maintain a channel-modulatory function may contribute to the conservation of this domain throughout the plant and animal kingdoms.

Development and characterization of the 2,4,6-trichlorophenol (2,4,6-TCP) aerobic degrading granules in sequencing batch airlift reactor

2,4,6-trichlorophenol (2,4,6-TCP) aerobic degrading granules were successfully developed in the sequencing batch airlift reactor. The key strategy used in cultivation of the granules was dosing glucose and acetate as co-substrates. After granulation, average concentrations of 2,4,6-TCP and COD in the effluent were less than 8mgL-1 and 59mgL-1, respectively. The removal efficiencies of 2,4,6-TCP and COD were above 93% and 90%, respectively. The specific degradation rate of 2,4,6-TCP peaked at 61mg 2,4,6-TCP gVSS-1h-1 when inoculated at the concentration of 400mgL-1. The extracellular polymeric substance (EPS) contents of the 2,4,6-TCP aerobic degrading granules were decreased compared with the contents in seed sludge. Two peaks attributed to the protein-like fluorophores were identified by three-dimensional excitation emission matrix (EEM) fluorescence spectra. The decrease of fluorescence parameters, e.g., peak locations, intensities, indicated quenching effect of 2,4,6-TCP on the EPS fluorescence. Meanwhile, the shift of peak position indicated chemical changes of the EPS.

Molecular dynamics modelling of diffusional formation of titanium carbide clusters in iron matrix

Molecular dynamics simulation was employed to study the atomic interactions in titanium carbides and iron matrix containing carbon and titanium, which are significant for understanding the formation of titanium carbide cluster during precipitate process. The atoms trajectory and diffusion coefficients of carbon in titanium carbide were analyzed to provide a vacancy-exchanging mechanism and clarify the carbon concentration dependence of carbon diffusion in titanium carbide. The dependence of the formation of titanium carbide cluster in iron matrix on carbon was determined from the study of atoms diffusivity, cluster formation and formation energy of titanium carbide cluster. The simulation results provided insight into the carbon diffusion process and improved the understanding of the formation of titanium carbide cluster.

The competition between metastable and equilibrium S (Al<inf>2</inf>CuMg) phase during the decomposition of AlCuMg alloys

Abstract The decomposition sequence of the supersaturated solid solution leading to the formation of the equilibrium S (Al<inf>2</inf>CuMg) phase in AlCuMg alloys has long been the subject of ambiguity and debate. Recent high-resolution synchrotron powder diffraction experiments have shown that the decomposition sequence does involve a metastable variant of the S phase (denoted S1), which has lattice parameters that are distinctly different to those of the equilibrium S phase (denoted S2). In this paper, the difference between these two phases is resolved using high-resolution synchrotron and neutron powder diffraction and atom probe tomography, and the transformation from S1 to S2 is characterised in detail by in situ synchrotron powder diffraction. The results of these experiments confirm that there are no significant differences between the crystal structures of S1 and S2, however, the powder diffraction and atom probe measurements both indicate that the S1 phase forms with a slight deficiency in Cu. The in situ isothermal aging experiments show that S1 forms rapidly, reaching its maximum concentration in only a few minutes at high temperatures, while complete conversion to the S2 phase can take thousands of hours at low temperature. The kinetics of S phase precipitation have been quantitatively analysed for the first time and it is shown that S1 phase forms with an average activation energy of 75 kJ/mol, which is much lower than the activation energy for Cu and Mg diffusion in an Al matrix (136 kJ/mol and 131 kJ/mol, respectively). The mechanism of the replacement of S1 with the equilibrium S2 phase is discussed.

Pesquisa orientada a resultado : proposta de um m��todo estruturado para disponibilizar uma nova tecnologia para o mercado : um caso aplicado ao projeto etanol de 2�� gera����o

Esta disserta����o de mestrado teve como objetivo principal propor um m��todo estruturado suportado for ferramentas gerenciais que permitisse orientar e sistematizar o desenvolvimento de um projeto de pesquisa na disponibiliza����o de uma nova tecnologia para o mercado. O ���Projeto Etanol de 2�� Gera����o���, etanol produzido a partir de biomassas lignocelul��sicas, aqui selecionado para estudo de caso, foi extra��do da carteira de projetos do Centro de Tecnologia Canavieira (CTC). O m��todo estruturado sugerido �� constitu��do, fundamentalmente, por oito requisitos arranjados de forma cronol��gica ao longo do desenvolvimento do projeto, que visam auxiliar na prospec����o, entendimento, avalia����o, valora����o, prioriza����o, planejamento e implanta����o de, por exemplo, uma tecnologia inovadora, otimizando tempo, capital e recursos humanos aplicados. Um dos principais pontos do m��todo proposto refere-se �� escolha adequada das ferramentas gerenciais a serem utilizadas em cada requisito (brainstorm, an��lise de patentes, painel de especialistas, an��lise SWOT, dentre outras). O ��xito na aplica����o do m��todo requer o entendimento de todos os (potenciais) efeitos, inclusive os colaterais, no processo como um todo. Ou seja, uma vez que toda ferramenta gerencial apresenta pontos fortes e fracos, o importante �� adapt��-las ao sistema de neg��cio e n��o vice-versa. A partir do gerenciamento do projeto por um gestor com dom��nio das ferramentas gerenciais, a escolha destas ocorre de forma din��mica, onde a cada passo de avalia����o novas ferramentas (simples e/ou complexas) podem ser inclu��das ou exclu��das da matriz do m��todo. Neste trabalho ficou demonstrada a import��ncia de se trabalhar com m��todos estruturados e flex��veis, que permitem retroalimenta����o de informa����es geradas internamente durante o desenvolvimento da pesquisa ou advindas de fontes externas. O projeto Etanol de 2�� Gera����o do CTC vem aplicando o m��todo proposto em seu desenvolvimento e obtendo grande ��xito em seus resultados, uma vez que a equipe envolvida permanece focada no objetivo principal, obedecendo prazos e recursos inicialmente definidos, com const��ncia do prop��sito do projeto, sem retrocesso ou recome��o.

Ascorbate electro-oxidation by modified electrodes: Polypyrrole and polypyrrole/Ni(OH)(2) composite thin films

Conselho Nacional de Desenvolvimento Cient��fico e Tecnol��gico (CNPq)

Proteoliposomes Harboring Alkaline Phosphatase and Nucleotide Pyrophosphatase as Matrix Vesicle Biomimetics

Funda����o de Amparo �� Pesquisa do Estado de S��o Paulo (FAPESP)

Evaluation of an average numerator relationship matrix model and a Bayesian hierarchical model for growth traits in Nellore cattle with uncertain paternity

Funda����o de Amparo �� Pesquisa do Estado de S��o Paulo (FAPESP)

A low-cost 3D reconstruction system using a single-shot projection of a pattern matrix

Funda����o de Amparo �� Pesquisa do Estado de S��o Paulo (FAPESP)