Polymer collapse in supercritical solvents

We show analytically that in dilute solutions of high molecular weight polymers, a collapse transition of the chain can be induced by proximity to the critical point of the solvent. The transition is driven by the fluctuations in the medium, which lead to an effective attractive interaction of long range between different parts of the polymer. At the critical point itself, however, the chain adopts the same average conformations that characterize its size in the off-critical limit. In other words, on approach to the critical point, the polymer is found first to contract and collapse, and then subsequently to return to its original dimensions. This behavior has recently been observed in simulations of polymer-solvent mixtures near the lower critical solution temperature of the system, and it is also known to be characteristic of solutions of polymers in bicomponent solvent mixtures near the critical consolute point of the two solvents. (C) 1999 American Institute of Physics. [S0021-9606(99)50431-5].

Nonneutral network and the role of bargaining power in side payments

Representatives of several Internet access providers have expressed their wish to see a substantial change in the pricing policies of the Internet. In particular, they would like to see content providers pay for use of the network, given the large amount of resources they use. This would be in clear violation of the �network neutrality� principle that had characterized the development of the wireline Internet. Our first goal in this paper is to propose and study possible ways of implementing such payments and of regulating their amount. We introduce a model that includes the internaut�s behavior, the utilities of the ISP and of the content providers, and the monetary flow that involves the internauts, the ISP and content provider, and in particular, the content provider�s revenues from advertisements. We consider various game models and study the resulting equilibrium; they are all combinations of a noncooperative game (in which the service and content providers determine how much they will charge the internauts) with a cooperative one - the content provider and the service provider bargain with each other over payments to one another. We include in our model a possible asymmetric bargaining power which is represented by a parameter (that varies between zero to one). We then extend our model to study the case of several content providers. We also provide a very brief study of the equilibria that arise when one of the content providers enters into an exclusive contract with the ISP.

Defect-Free Hyperbranched Polydithioacetal via Melt Polymerization

Degree of branching (DB) describes the level of structural perfection of a hyperbranched polymer when compared to its defect-free analogue, namely the dendrimer. The strategy most commonly used to achieve high DB values, specifically while using AB(2) type self-condensations, is to design an AB2 monomer wherein the reaction of the first B-group leads to an enhancement of the reactivity of the second one. In the present study, we show that an AB2 monomer carrying a dimethylacetal unit and a thiol group undergoes a rapid self-condensation in the melt under acid-catalysis to yield a hyperbranched polydithioacetal with no linear defects. NMR studies using model systems reveal that the intermediate monothioacetal is relatively unstable under the polymerization conditions and transforms rapidly to the dithioacetal; because this second step occurs irreversibly during polymer formation, it leads to a defect-free hyperbranched polydithioacetal. TGA studies of the polymerization process provided some valuable insights into the kinetics of polymerization. An additional virtue of this approach is that the numerous terminal dimethylacetal groups are very labile and can be quantitatively transformed by treatment with a variety of functional thiols; the terminal dimethylacetals were, thus, reacted with various thiols, such as dodecanethiol, benzyl mercaptan, ethylmercaptopropionate, and so on, to demonstrate the versatility of these systems as sulfur-rich hyperscaffolds to anchor different kinds of functionality on their periphery.

Game theoretic analysis of collusions in nonneutral networks

This paper studies the impact of exclusive contracts between a content provider (CP) and an internet service provider (ISP) in a nonneutral network. We consider a simple linear demand function for the CPs. We studywhen an exclusive contract is benefcial to the colluding pair and evaluate its impact on the noncolluding players at equilibrium. For the case of two CPs and one ISP we show that collusion may not always be benefcial. We derive an explicit condition in terms of the advertisement revenues of the CPs that tells when a collusion is proftable to the colluding entities.

Local stability of a gravitating filament: a dispersion relation

Filamentary structures are ubiquitous in astrophysics and are observed at various scales. On a cosmological scale, matter is usually distributed along filaments, and filaments are also typical features of the interstellar medium. Within a cosmic filament, matter can contract and form galaxies, whereas an interstellar gas filament can clump into a series of bead-like structures that can then turn into stars. To investigate the growth of such instabilities, we derive a local dispersion relation for an idealized self-gravitating filament and study some of its properties. Our idealized picture consists of an infinite self-gravitating and rotating cylinder with pressure and density related by a polytropic equation of state. We assume no specific density distribution, treat matter as a fluid, and use hydrodynamics to derive the linearized equations that govern the local perturbations. We obtain a dispersion relation for axisymmetric perturbations and study its properties in the (kR, kz) phase space, where kR and kz are the radial and longitudinal wavenumbers, respectively. While the boundary between the stable and unstable regimes is symmetrical in kR and kz and analogous to the Jeans criterion, the most unstable mode displays an asymmetry that could constrain the shape of the structures that form within the filament. Here the results are applied to a fiducial interstellar filament, but could be extended for other astrophysical systems, such as cosmological filaments and tidal tails.

Design and Testing of a Control System for Supply Side Electrical Load Management

India's energy demand is increasing rapidly with the intensive growth of economy. The electricity demand in India exceeded the availability, both in terms of base load energy and peak availability. The efficient use of energy source and its conversion and utilizations are the viable alternatives available to the utilities or industry. There are essentially two approaches to electrical energy management. First at the supply / utility end (Supply Side Management or SSM) and the other at the consumer end (Demand Side Management or DSM). This work is based on Supply Side Management (SSM) protocol and consists of design, fabrication and testing of a control device that will be able to automatically regulate the power flow to an individual consumer's premise. This control device can monitor the overuse of electricity (above the connected load or contracted demand) by the individual consumers. The present project work specially emphasizes on contract demand of every consumer and tries to reduce the use beyond the contract demand. This control unit design includes both software and hardware work and designed for 0.5 kW contract demand. The device is tested in laboratory and reveals its potential use in the field.

Influence of surfactant solubility on the deformation and breakup of a bubble or capillary jet in a viscous fluid

In a previous study [M. Hameed, J. Fluid Mech. 594, 307 (2008)] the authors investigated the influence of insoluble surfactant on the evolution of a stretched, inviscid bubble surrounded by a viscous fluid via direct numerical simulation of the Navier-Stokes equations, and showed that the presence of surfactant can cause the bubble to contract and form a quasisteady slender thread connecting parent bubbles, instead of proceeding directly toward pinch-off as occurs for a surfactant-free bubble. Insoluble surfactant significantly retards pinch-off and the thread is stabilized by a balance between internal pressure and reduced capillary pressure due to a high concentration of surfactant that develops during the initial stage of contraction. In the present study we investigate the influence of surfactant solubility on thread formation. The adsorption-desorption kinetics for solubility is in the diffusion controlled regime. A long-wave model for the evolution of a capillary jet is also studied in the Stokes flow limit, and shows dynamics that are similar to those of the evolving bubble. With soluble surfactant, depending on parameter values, a slender thread forms but can pinch-off later due to exchange of surfactant between the interface and exterior bulk flow. © 2009 American Institute of Physics.

El redescubrimiento de la filosofía personalista de Jacques Maritain

Resumen: El autor sostiene que la búsqueda de nuevos modelos empresariales y de política económica nos invita a redescubrir la filosofía personalista de Maritain. En el núcleo de la obra Humanismo integral (1936) del filósofo francés aparece la idea de que el hombre es una persona "de naturaleza espiritual, dotada de libre albedrío, y por lo tanto autónoma en relación con el mundo". El artículo estudia la naturaleza del bien común temporal, que para Maritain se relaciona con la vida buena de la toda la comunidad –el bien común o bonum commune– tanto en el sentido material como moral. Este bonum commune no es el objetivo final del orden temporal, sino que está subordinado a lo que trasciende el bienestar temporal de la persona humana –la realización de la libertad y la perfección espiritual. En última instancia, el orden nunca se completa. El balance definitivo o telos nunca se obtiene ya que el hombre está siempre en camino.

Verba doctoris : la fecundidad educativa de las palabras del maestro

Resumen: En el mundo educativo actual las corrientes pedagógicas se han visto sumidas en lo que podríamos denominar «el olvido del maestro», pues este se torna ininteligible cuando no hay una verdad que comunicar. La educación se convierte entonces en una construcción por parte del alumno de un mundo de significados subjetivos y cambiantes, que el maestro solo estimula. Frente a esto encontramos la enseñanza de santo Tomás de Aquino, Doctor Humanitatis, quien nos recuerda que las palabras del maestro, verba doctoris, son comunicativas de la verdad ya conocida. Solo fundados en este principio es posible devolver a la palabra educativa la fecundidad que le corresponde, tan necesaria para el perfeccionamiento del hombre y de la sociedad. En este artículo se presenta una reflexión acerca del lugar que ocupa la palabra verdadera en la educación de los hombres, mostrando cómo la vida humana no tiende solo a expresarse en la palabra, sino a ser fecunda en la palabra educativa.

El acto de ser en la distinción hombre y persona de Santo Tomás de Aquino

Resumen: Santo Tomás obtuvo la distinción de hombre y persona de la evidencia del mal humano, cuyas manifestaciones más importantes son los padecimientos corporales y espirituales, que culminan en la muerte, la debilidad de la razón y la carencia de armonía y de orden en sus facultades. Para la comprensión adecuada del hombre, lo sitúa en la escala de los entes según los grados de perfección. Desde ella, se advierte que el hombre tiene un único ser, aunque esté compuesto de cuerpo y espíritu, que le anima. Es el acto de ser de un espíritu, que unifica todos los constitutivos humanos y que proporciona una mayor individualidad que la que poseen los otros entes. La individualidad o incomunicabilidad única del hombre se expresa con el término «persona», que tiene un estatuto lógico y gramatical especial. La persona expresa directamente al ser, sin la mediación de la esencia y los trascendentales, que explican su gran perfección.

La estructura del orden moral : una introducción a la ética de cuño aristotélico-tomista

Resumen: El texto realiza un análisis sobre el orden moral en su objeto material (la conducta humana) y el objeto formal (el bien o la perfección). Se detiene en la experiencia moral planteando los problemas, las dudas y las dificultades tales como la naturaleza humana, el fin natural, la libertad, las pasiones, la necesidad de indigencia y la deóntica, entre otros. Luego estudia el esquema de la estructura del orden moral en el orden moral vivido, disposicional, subjetivo, normativo y de fines. Estas dimensiones se integran a través de la causalidad final.

Progress In Modeling Of Fluid Flows In Crystal Growth Processes

Modeling of fluid flows in crystal growth processes has become an important research area in theoretical and applied mechanics. Most crystal growth processes involve fluid flows, such as flows in the melt, solution or vapor. Theoretical modeling has played an important role in developing technologies used for growing semiconductor crystals for high performance electronic and optoelectronic devices. The application of devices requires large diameter crystals with a high degree of crystallographic perfection, low defect density and uniform dopant distribution. In this article, the flow models developed in modeling of the crystal growth processes such as Czochralski, ammonothermal and physical vapor transport methods are reviewed. In the Czochralski growth modeling, the flow models for thermocapillary flow, turbulent flow and MHD flow have been developed. In the ammonothermal growth modeling, the buoyancy and porous media flow models have been developed based on a single-domain and continuum approach for the composite fluid-porous layer systems. In the physical vapor transport growth modeling, the Stefan flow model has been proposed based on the flow-kinetics theory for the vapor growth. In addition, perspectives for future studies on crystal growth modeling are proposed. (c) 2008 National Natural Science Foundation of China and Chinese Academy of Sciences. Published by Elsevier Limited and Science in China Press. All rights reserved.

La confesión en el Salmo 106 (107) de la traducción jerónima iuxta Hebraeos

Resumen: El salmo 106 (107) es una confesión de la misericordia de Dios que hace desvanecer las necesidades y angustias de quien clama a Él en distintas instancias de su camino de purificación y perfección. A la vez que confiesa, exhorta a la confesión. Esta confesión está estrechamente unida a la confianza y al abandono en Dios a las que, a su vez, se dirige dicha purificación. En la traducción jerónima iuxta Hebraeos hay marcas lingüísticas que indican el sentido de esta confesión, especialmente mediante la estructura confiteor + dativo.

John Locke : las posesiones o los derechos políticos como garantía de la libertad

Este artículo busca reflexionar sobre las garantías que el contrato social de John Locke ofrece a la libertad. Así, apartándose de la corriente de interpretación dominante, se intenta realizar una aproximación hermenéutica a su obra que de cuenta del campo semántico en el cual se desarrolla. De esta manera, aflorará la propia voz del autor permitiendo dilucidar cuál es el contenido y el alcance de la libertad en el contrato social lockeano.

El objeto formal de la vis cogitativa en Santo Tomás de Aquino

Resumen: De acuerdo a la mente de Santo Tomás de Aquino, la potencia de conocimiento sensible que se denomina «cogitativa » es susceptible de una doble consideración. Por un lado, es la estimativa animal y, como tal, aprehende su mismo objeto formal quod, esto es, las intenciones de beneficio o perjuicio a nivel sensible. Pero a causa de su particular modo de operar, esas intenciones no son conocidas por ella solamente en orden a la conservación del individuo humano o de la especie a la que él pertenece. El reconocimiento de una doble dimensión de la cogitativa está en Santo Tomás justificado por la particular relación que existe entre ella y la razón universal. Por un lado, la cogitativa no es una facultad distinta de la estimativa natural. Por esto, ella aprehende las intenciones necesarias para la perfección de la vida sensitiva humana. Por otro lado, la razón ejerce sobre la cogitativa un influjo particular que la hace operar a su modo, esto es, de manera discursiva. Este carácter móvil en la aprehensión de la cogitativa permite la conformación de una experiencia a nivel sensible, en virtud de la cual su objeto formal se ve ampliado. Esto resulta aún más razonable si se tiene en cuenta que el conocimiento sensorial del hombre prepara el intelectual. De esta manera, la cogitativa no aprehende simplemente al individuo como beneficioso o perjudicial para la subsistencia del cognoscente, sino como sujeto de una cierta naturaleza.