Hydrogeochemistry of surface and spring waters in the surroundings of the CO2 injection site at Hontomín–Huermeces (Burgos, Spain)

In this paper the very first geochemical and isotopic data related to surface and spring waters and dissolved gases in the area of Hontomín–Huermeces (Burgos, Spain) are presented and discussed. Hontomín–Huermeces has been selected as a pilot site for the injection of pure (>99%) CO2. Injection and monitoring wells are planned to be drilled close to 6 oil wells completed in the 1980s for which detailed stratigraphical logs are available, indicating the presence of a confined saline aquifer at the depth of about 1500 m into which less than 100,000 tons of iquid CO2 will be injected, possibly starting in 2013. The chemical and features of the spring waters suggest that they are related to a shallow hydrogeological system as the concentration of the Total Dissolved Solids approaches 800 mg/L with a Ca2+(Mg2+)-HCO3− composition, similar to that of the surface waters. This is also supported by the oxygen and hydrogen isotopic ratios that have values lying between those of the Global and the Mediterranean Meteoric Water Lines. Some spring waters close to the oil wells are haracterized by relatively high concentrations of NO3− (up to 123 mg/L), unequivocally suggesting an anthropogenic source that adds to the main water–rock interaction processes. The latter can be referred to Ca-Mg-carbonate and, at a minor extent, Al-silicate dissolution, being the outcropping sedimentary rocks characterized by Palaeozoic to Quaternary rocks. Anomalous concentrations of Cl−, SO42−, As, B and Ba were measured in two springs discharging a few hundred meters from the oil wells and in the Rio Ubierna. These contents are significantly higher than those of the whole set of the studied waters and are possibly indicative of mixing processes, although at very low extent, between deep and shallow aquifers. No evidence of deep-seated gases interacting with the Hontomín–Huermeces waters was recognized in the chemistry of the disolved gases. This is likely due to the fact that they are mainly characterized by an atmospheric source as highlighted by the high contents of N2, O2 and Ar and by N2/Ar ratios that approach that of ASW (Air Saturated Water) and possibly masking any contribution related to a deep source. Nevertheless, significant concentrations (up to 63% by vol.) of isotopically negative CO2 (<−17.7‰ V-PDB) were found in some water samples, likely related to a biogenic source. The geochemical and isotopic data of this work are of particular importance when a monitoring program will be established to verify whether CO2 leakages, induced by the injection of this greenhouse gas, may be affecting the quality of the waters in the shallow hydrological circuits at Hontomín–Huermeces. In this respect, carbonate chemistry, the isotopic carbon of dissolved CO2 and TDIC (Total Dissolved Inorganic Carbon) and selected trace elements can be considered as useful parameters to trace the migration of the injected CO2 into near-surface environments.

CO2 soil flux baseline at the technological development plant for CO2 injection at Hontomin (Burgos, Spain)

From the end of 2013 and during the following two years, 20 kt of CO2sc are planned to be injected in a saline reservoir (1500 m depth) at the Hontomín site (NE Spain). The target aquifers are Lower Jurassic limestone formations which are sealed by Lower Cretaceous clay units at the Hontomín site (NE Spain). The injection of CO2 is part of the activities committed in the Technology Development phase of the EC-funded OXYCFB300 project (European Energy Program for Recovery – EEPR, http://www.compostillaproject.eu), which include CO2 injection strategies, risk assessment, and testing and validating monitoring methodologies and techniques. Among the monitoring works, the project is intended to prove that present-day technology is able to monitor the evolution of injected CO2 in the reservoir and to detect potential leakage. One of the techniques is the measurement of CO2 flux at the soil–atmosphere interface, which includes campaigns before, during and after the injection operations. In this work soil CO2 flux measurements in the vicinity of oil borehole, drilled in the eighties and named H-1 to H-4, and injection and monitoring wells were performed using an accumulation chamber equipped with an IR sensor. Seven surveys were carried out from November 2009 to summer 2011. More than 4000 measurements were used to determine the baseline flux of CO2 and its seasonal variations. The measured values were low (from 5 to 13 g m−2 day−1) and few outliers were identified, mainly located close to the H-2 oil well. Nevertheless, these values cannot be associated to a deep source of CO2, being more likely related to biological processes, i.e. soil respiration. No anomalies were recognized close to the deep fault system (Ubierna Fault) detected by geophysical investigations. There, the CO2 flux is indeed as low as other measurement stations. CO2 fluxes appear to be controlled by the biological activity since the lowest values were recorded during autumn-winter seasons and they tend to increase in warm periods. Two reference CO2 flux values (UCL50 of 5 g m−2 d−1 for non-ploughed areas in autumn–winter seasons and 3.5 and 12 g m−2 d−1 for in ploughed and non-ploughed areas, respectively, in spring–summer time, and UCL99 of 26 g m−2 d−1 for autumn–winter in not-ploughed areas and 34 and 42 g m−2 d−1 for spring–summer in ploughed and not-ploughed areas, respectively) were calculated. Fluxes higher than these reference values could be indicative of possible leakage during the operational and post-closure stages of the storage project.

Characterization of underground cellars in the Duero Basin by GNSS, LIDAR and GPR techniques

The underground cellars of the Duero River basin are part of spread and damaged agricultural landscape which is in danger of disappearing. These architectural complexes are allocated next to small towns. Constructions are mostly dug in the ground with a gallery down or "barrel" strait through which you access the cave or cellar. This wider space is used to make and store wine. Observation and detection of the winery both on the outside and underground is essential to make an inventory of the rural heritage. Geodetection is a non-invasive technique, suitable to determinate with precision buried structures in the ground. The undertaken works include LIDAR survey techniques, GNSS and GPR obtained data. The results are used to identify with centimetric precision construction elements forming the winery. Graphic and cartographic obtained documents allow optimum visualization of the studied field and can be used in the reconstruction of the place.

Water chemistry at Hontomín-Huermeces (Burgos, Spain): insights for a pre-, intra- and post-CO2 injection geochemical monitoring.

In this study, the very first geochemical and isotopic data related to surface and spring waters and dissolved gases in the area of Hontomín-Huermeces (Burgos, Spain) are presented and discussed. Hontomín-Huermeces was selected as a pilot site for the injection of pure (>99 %) CO2. Injection and monitoring wells are planned to be drilled close to 6 oil wells completed in the 1980’s. Stratigraphical logs indicate the presence of a confined saline aquifer at the depth of about 1,500 m into which less than 100,000 tons of liquid CO2 will be injected, possibly starting in 2013. The chemical and isotopic features of the spring waters suggest the occurrence of a shallow aquifer having a Ca2+(Mg2+)-HCO3- composition, relatively low salinity (Total Dissolved Solids _800 mg/L) and a meteoric isotopic signature. Some spring waters close to the oil wells are characterized by relatively high concentrations of NO3- (up to 123 mg/L), unequivocally indicating anthropogenic contamination that adds to the main water-rock interaction processes. The latter can be referred to Ca-Mg-carbonate and, at a minor extent, Al-silicate dissolution, being the outcropping sedimentary rocks characterized by Palaeozoic to Quaternary rocks. Anomalous concentrations of Cl-, SO42-, As, B and Ba were measured in two springs discharging a few hundreds meters from the oil wells and in the Rio Ubierna, possibly indicative of mixing processes, although at very low extent, between deep and shallow aquifers. Gases dissolved in spring waters show relatively high concentrations of atmospheric species, such as N2, O2 and Ar, and isotopically negative CO2 (<-17.7 h V-PDB), likely related to a biogenic source, possibly masking any contribution related to a deep source. The geochemical and isotopic data of this study are of particular importance when a monitoring program will be established to verify whether CO2 leakages, induced by the injection of this greenhouse gas, may affect the quality of the waters of the shallow Hontomín-Huermeces hydrological circuit. In this respect, carbonate chemistry, the isotopic carbon of dissolved CO2 and TDIC (Total Dissolved Inorganic Carbon) and selected trace elements can be considered as useful parameters to trace the migration of the injected CO2 into near-surface environments.

Underground dwellings in the Tajuña valley, Madrid, Spain and their bioclimatic adaptation

Underground dwellings are the maximum example of the vernacular architecture adaptation to the climatic conditions in areas with high annual and daily thermal fluctuations. This paper summarizes the systematic research about the energy performance of this popular architecture and their adaptation to the outdoor conditions in the case of the low area of the River Tajuña and its surroundings. Some considerations on their maintenance and renovation arise from the research.

Observation and Detection of Underground Cellars in the Duero Basin By GNSS, Lidar and Ground Penetrating Radar Techniques

The underground cellars that appear in different parts of Spain are part of an agricultural landscape dispersed, sometimes damaged, others at risk of disappearing. This paper studies the measurement and display of a group of wineries located in Atauta (Soria), in the Duero River corridor. It is a unique architectural complex, facing rising, built on a smooth hillock as shown in Fig. 1. These constructions are excavated in the ground. The access to the cave or underground cellar has a shape of a narrow tube or down gallery. Immediately after, this space gets wider. There, wine is produced and stored [1]. Observation and detection of the underground cellar, both on the outside and underground, it is essential to make an inventory of the rural patrimony [2]. The geodetection is a noninvasive technique, adequate to accurately locate buried structures in the ground. Works undertaken include topographic work with the LIDAR techniques and integration with data obtained by GNSS and GPR.

Caracterización geoquímica orgánica de los materiales de la zona de Hontomín para almacenamiento de Co2

Ante la perspectiva del Cambio Global propiciado por la acción antrópica debido al vertido de CO2 a la atmósfera desde el inicio de la Era Industrial, el Protocolo de Kyoto (firmado en 1997), seguido de las tímidas propuestas derivadas de la Reunión de Copenhague, más acciones derivadas de la reunión de los ministros de medio ambiente en Sevilla, la acción de captura y secuestro del CO2inevitablemente generado por la industria pesada y la generación de energía ha ido adquiriendo un progresivo interés al estar la Península Ibérica constituida en más del 50% de su superficie por rocas sedimentarias susceptibles de constituir almacenamientos subterráneos. El objetivo fundamental de este proyecto fin de carrara, es determinar los cambios que se producen en los compuestos orgánicos de las posibles rocas almacén y sello de la zona de Páramos de la Lora en Burgos, (donde se pretende realizar el secuestro de CO2) después de la inyección de CO2 supercrítico en experimentos. Fundamentalmente, el estudio se centra en la familia de alcanos, cetonas y ácidos. Para ello se realizará una caracterización geoquímica orgánica de los materiales antes y después de haber inyectado CO2 a altas presiones (100 bar – 120 bar) y en las condiciones térmicas existentes a la profundidad del almacén (40º C - 50º C) durante períodos de tiempo variables, para lo que se empleará cámara hiperbárica del Grupo de Estudios Ambientales. Abstract In view Global Change led by the anthropic action due to the discharge of CO2 into the atmosphere since the start of the Indistrual Era, the Protocolo de Kyoto (signed in 1997), followed by the timid proposals arising from the Copenhague Meeting, more action arising of the meeting of the environment minister in Sevilla, the action of captura and sequestration of CO2 inevitably generated by heavy industry and the energy generation has acquired a progressive interest because de Península Ibérica is formed in more than fifty percent of the surface by sedimentary rock susceptible of provide underground storage. The objetive of this Project is determining the changes produced in organics compounds of potential reservoir rocks and seal rocks in Páramos de la Lora in Burgos, after injection supercritical CO2 in experiment. Fundamentally, the study focuses in the alcanos, cetonas and ácidos family. For this, a geochemical characterizacion will be performed in the materials before and after injection of high pressure CO2 (100bar-120bar) and in the existing termal conditions in the depth of the warehouse (40º C-50º C) for varying period of time, for what is used hyperbaric chamber environmental studies group.

High-frequency signal generation using 1550 nm VCSEL subject to two-frequency optical injection

We experimentally investigate high-frequency microwave signal generation using a 1550 nm single-mode VCSEL subject to two-frequency optical injection. We first consider a situation in which the injected signals come from two similar VCSELs. The polarization of the injected light is parallel to that of the injected VCSEL. We obtain that the VCSEL can be locked to one of the injected signals, but the observed microwave signal is originated by beating at the photodetector. In a second situation we consider injected signals that come from two external cavity tunable lasers with a significant increase of the injected power with respect to the VCSEL-by-VCSEL injection case. The polarization of the injected light is orthogonal to that of the free-running slave VCSEL. We show that in this case it is possible to generate a microwave signal inside the VCSEL cavity. © (2013) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

One-dimensional linear analysis of the liquid injection or removal in a liquid bridge

The filling-withdrawal process of a long liquid bridge is analyzed using a one-dimensional linearized model for the dynamics of the liquid column. To carry out this study, a well-known standard operational method (Laplace transform) has been used, and time variation of both liquid velocity field and interface shape are obtained.

Asymptotic analysis of vertical geothermal boreholes in the limit of slowly varyng heat injection rates

Theoretical models for the thermal response of vertical geothermal boreholes often assume that the characteristic time of variation of the heat injection rate is much larger than the characteristic diffusion time across the borehole. In this case, heat transfer inside the borehole and in its immediate surroundings is quasi-steady in the first approximation, while unsteady effects enter only in the far field. Previous studies have exploited this disparity of time scales, incorporating approximate matching conditions to couple the near-borehole region with the outer unsteady temperatura field. In the present work matched asymptotic expansion techniques are used to analyze the heat transfer problem, delivering a rigorous derivation of the true matching condition between the two regions and of the correct definition of the network of thermal resistances that represents the quasi-steady solution near the borehole. Additionally, an apparent temperature due to the unsteady far field is identified that needs to be taken into account by the near-borehole region for the correct computation of the heat injection rate. This temperature differs from the usual mean borehole temperature employed in the literatura.

Characterization of Underground Cellars in the Duero Basin by GNSS, LIDAR and GPR Techniques

The underground cellars that appear in different parts of Spain are part of an agricultural landscape dispersed, sometimes damaged, others at risk of disappearing. This paper studies the measurement and display of a group of wineries located in Atauta (Soria), in the Duero River corridor.

Assessment of Underground Wine Cellars Using Geographic Information Technologies

Geographic information technologies (GIT) are essential to many fields of research, such as the preservation and dissemination of cultural heritage buildings, a category which includes traditional underground wine cellars. This article presents a methodology based on research carried out on this type of rural heritage building. The data were acquired using the following sensors: EDM, total station, close-range photogrammetry and laser scanning, and subsequently processed with a specific software which was verified for each case, in order to obtain a satisfactory graphic representation of these underground wine cellars. Two key aspects of this work are the accuracy of the data processing and the visualization of these traditional constructions. The methodology includes an application for geovisualizing these traditional constructions on mobile devices in order to contribute to raising awareness of this unique heritage.

Selective injection of magnetic domain walls in Permalloy nanostripes

Selective injection of magnetic domain walls in Permalloy nanostripes

The NH3-Abating effect of Slurry Injection as Influenced by Soil Moisture in a Semiarid Arable Soil

Accumulation of large volumes of dilute slurries is considered one of the major problems related to intensive farming (Sommer et al., 2004). In the EU-27, more than half of the total N excretion is applied to croplands due to technical advantages for farmers (e.g. reuse of nutrients). However, the N use efficiency of slurries produced by livestock is low, i.e. only 20-52% of the excreted N is recovered by crops. Much of the remainder can be lost into the atmosphere as ammonia (NH3), nitrous oxide (N2O), dinitrogen (N2) and nitrogen oxides (NOx).

Intrastriatal injection of an adenoviral vector expressing glial-cell-line-derived neurotrophic factor prevents dopaminergic neuron degeneration and behavioral impairment in a rat model of Parkinson disease

Glial-cell-line-derived neurotrophic factor (GDNF) is a potent neurotrophic factor for adult nigral dopamine neurons in vivo. GDNF has both protective and restorative effects on the nigro-striatal dopaminergic (DA) system in animal models of Parkinson disease. Appropriate administration of this factor is essential for the success of its clinical application. Since it cannot cross the blood–brain barrier, a gene transfer method may be appropriate for delivery of the trophic factor to DA cells. We have constructed a recombinant adenovirus (Ad) encoding GDNF and injected it into rat striatum to make use of its ability to infect neurons and to be retrogradely transported by DA neurons. Ad-GDNF was found to drive production of large amounts of GDNF, as quantified by ELISA. The GDNF produced after gene transfer was biologically active: it increased the survival and differentiation of DA neurons in vitro. To test the efficacy of the Ad-mediated GDNF gene transfer in vivo, we used a progressive lesion model of Parkinson disease. Rats received injections unilaterally into their striatum first of Ad and then 6 days later of 6-hydroxydopamine. We found that mesencephalic nigral dopamine neurons of animals treated with the Ad-GDNF were protected, whereas those of animals treated with the Ad-β-galactosidase were not. This protection was associated with a difference in motor function: amphetamine-induced turning was much lower in animals that received the Ad-GDNF than in the animals that received Ad-β-galactosidase. This finding may have implications for the development of a treatment for Parkinson disease based on the use of neurotrophic factors.