非均匀性对岩石破裂过程影响的研究

Rock heterogeneity plays an important role in rock fracturing processes. However, because fracturing is a dynamic process and it is very difficult to quantify materials' heterogeneity, most of the theories dealing with local failure were based on the homogeneity assumption, very few involving stress distribution heterogeneity and successive local failure due to rock heterogeneity. Therefore, based on various references, the author studied the laws and mechanism of influences of heterogeneity on rock fracturing processes, under the frame of the project "Study on Associate Mechanism between Rock Mass Fracture and Strength Failure", funded by Nation Natural Science Fund. the research consists of such aspects as size effect correction to rock fracture parameters, SEM (Scanning Electron Microscope) real-time observation on rock samples under different loads, micro-hardness testing, and numerical simulating based on microstructure. There are some important research results as followed: 1. Unifying formula for nonlinear and non-singularity correction, simplifying the complex process of correcting size effect on rock fracture toughness. 2. Using the methods of micro-hardness testing mineral grain and random jointing micrograph digitizing mineral slice, preliminarily solving the problems of numerical simulating and quantitatively describing the heterogeneous strength and its distribution rules, which has certain innovation and better practicability. 3. Based on SEM real-time observation, studying the micro-process of fracturing in marble, sandstone, granite, and mushroom stone samples with premanufactured cracks under tension, pure-shear and compression-shear conditions. Strength Failure was observed: there was some kind failure occurred before Fracture Failure in marble and sandstone samples with double cracks under pure-shearing. It is believed that the reason of strength failure developing is that stress concentrations is some locations are larger than that near the end of pre-manufactured cracks. 4. Based on the idea that rock macro-constitute is composed of complex microstructure, the promising method used to handle heterogeneity considers not only the heterogeneity of the rock medium, but also the heterogeneity of the rock structure. 5. Putting forward two types of rock strength failure: medium strength failure induced by heterogeneity of rock medium and structure strength failure induced by heterogeneity rock structure. 6. By evaluating potential fracture cell with proper failure priority, the numerical simulating method solved the problem of simulating the coextensive strength failure and fracture failure with convention strength failure rules. The result of numerical analysis shows that the influence of heterogeneity on rock fracturing processes is evident. The sinuosity of the rock fracture-propagation path, and the irregular fluctuation of loading displacement curve, is mainly controlled by the heterogeneity of rock medium.

Theoretical study of the separation mechanism of ionizable compounds in capillary electrochromatography

The migration mechanism of ionizable compounds in capillary electrochromatography (CEC) is more complicated than in high performance liquid chromatography (HPLC) due to the involvement of electrophoresis and the second chemical equilibrium. The separation mechanism of ionizable compounds in CEC has been studied theoretically. The electrochromatographic capacity factors of ions (k *) in CEC and in the pressurized CEC are derived by phenomenological approach. The influence of pH, voltage, pressure on k* is discussed. in addition, the k * of weak acid and weak base are derived based on acid-base equilibrium and the influence of pH on k * is studied theoretically.