962 resultados para Pointing
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Pós-graduação em Educação Escolar - FCLAR
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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It is often assumed that the hydrogen atoms in the thiol groups of a benzene-1,4-dithiol dissociate when Au-benzene-1,4-dithiol-Au junctions are formed. We demonstrate, by stability and transport property calculations, that this assumption cannot be made. We show that the dissociative adsorption of methanethiol and benzene-1,4-dithiol molecules on a flat Au(111) surface is energetically unfavorable and that the activation barrier for this reaction is as high as 1 eV. For the molecule in the junction, our results show, for all electrode geometries studied, that the thiol junctions are energetically more stable than their thiolate counterparts. Due to the fact that density functional theory (DFT) within the local density approximation (LDA) underestimates the energy difference between the lowest unoccupied molecular orbital and the highest occupied molecular orbital by several electron-volts, and that it does not capture the renormalization of the energy levels due to the image charge effect, the conductance of the Au-benzene-1,4-dithiol-Au junctions is overestimated. After taking into account corrections due to image charge effects by means of constrained-DFT calculations and electrostatic classical models, we apply a scissor operator to correct the DFT energy level positions, and calculate the transport properties of the thiol and thiolate molecular junctions as a function of the electrode separation. For the thiol junctions, we show that the conductance decreases as the electrode separation increases, whereas the opposite trend is found for the thiolate junctions. Both behaviors have been observed in experiments, therefore pointing to the possible coexistence of both thiol and thiolate junctions. Moreover, the corrected conductance values, for both thiol and thiolate, are up to two orders of magnitude smaller than those calculated with DFT-LDA. This brings the theoretical results in quantitatively good agreement with experimental data.
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This paper deals with the Compositional Fidelity of the brachiopods assemblages, dominated by Bouchardia rosea, on the outer shelf and continental slope along São Paulo State. Samples were obtained during the Revizee-Score-Sul-Benthos program. The sampled stations are in sites as depth as 90 to 600 meters, along the outer continental shelf, the shelf break and the top of continental slope. The fidelity estimates were obtained directly from the comparisons between living biota and dead shells, from the same collecting stations. Data come from 66 sampling stations, and the vast majority of the Bouchardia rosea individuals collected (n=2393) were dead (n = 2342, 97.9%). Only 51 individuals were collected alive. When pooling the data from all collecting stations the dead/live frequency is of 2,1% only. The occurrences of Bouchardia rosea shells in siliciclastic bottoms are reduced and living individuals were not found on this type of bottom, at least during the sampling program. These results suggest low compositional fidelity (live-dead) or high compositional mismatch, pointing to a recent decrease in this specie population. The low compositional fidelity of the Bouchardia rosea assemblages in outer shelf sites may be due to changes in seawater temperature, nutrient availability and population history. All these issues must be investigated in the near future
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The ease and convenience provided by the Internet allow for the communication between the organization and its stakeholders to become rapid and effective. This fact can be good both for the organization and for the public. Keeping this in sight, the Internet as a public relations tool for communication between the organization and its stakeholders is the theme discussed throughout this study. Through bibliographic and exploratory research, this paper aims at pointing at effective tools afforded by the Internet that can be used by Public Relations. These tools can promote the relationship between organizations and its publics inserted on the Internet. In this way, the organization can influence publics in its favor. The present work investigates what strategies the Internet can contribute significantly to the field of Communication despite the fact that it is not able to completely replace traditional media
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The disordered occupation in several cities in Brazil, is very common, especially during the rainy season, there are numerous cases of gravitational mass movements, with deads of human and builds destruction. The main objective of this work was to identify and map areas to mass movements, through the geo, the municipality of Várzea Paulista, the state of Sao Paulo. For the purpose, were prepared thematic maps of slope, geology, pedology, geomorphology and land use and occupation, which were overlaid using ArcGIS GIS Multicriteria Analysis. Each subject received a weight of influence to the outbreak of such processes and the final result was obtained map of susceptibility to mass movements of the city of Várzea Paulista. This survey found that there are many occupied areas within the city that require monitoring of the Government, especially in the rainy months, because they are in very fragile in terms of geological and geomorphological features. Considering that the data on the physical and natural aspects are scarce in the literature for this region, the results obtained in this study as well as the gathering of information of the physical and cartographic products developed, will greatly contribute to the administration of the municipality, subsidies they provide for the proper use planning and land tenure, pointing out the weak areas of the city geotechnical point of view
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Business communication, and in it inserted Public Relations, has evolved in the past few years, and after that, new forms to deal with it were arised and developed. Considering this premise, the study talks about the communication inside companies, pointing out the current trend of outsourcing this process. This paper is based in integrated communication, mainly stated by Margarida Kunsch, and in brazilian communication consulting data. Besides, a communication agency was chosen as a study case, which helped at information search for the issue, and as subject to discussion. The study tries to analyze the process of communication service, when executed by an outsourced firm, the pros and cons, from a Public Relations perspective
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The growth and expansion in auto parts market are directly related to the ability of a company to innovate and gain new customers, increasing its portfolio of customers and products. For this purpose the process of prospecting for new business has become a key process in companies seeking this goal, which requires teams and structures dedicated to it. Besides counting on available resources to carry out prospecting, it is necessary to properly manage the process as a whole, whose main result is a business proposal, which may lead to closer relations with the potential client and the activation of a new business. Process failures and difficulties to formulate a commercial proposal lead to documents produced without the quality needed that makes it harder to obtain new business. The objective of this study is to evaluate the process of new businesses quotation in the auto parts industry and indicate opportunities for improving this process. This goal is achieved by mapping the current process, from the diagnosis of problems and the indication of tools that can prevent or minimize the problems diagnosed. The information supporting this study were obtained by the bibliographical research, participant observation of the process, unstructured interviews with some of the involved people in the process and prospecting tools that can improve it. It results the mapping of new business quotation process, the points indicated as failures and difficulties in the process and the appointment of project management tools that can bring improvements to the new business proposals and pointing the moment for your application in the process
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This study examines some characteristics of the contemporary reality and its influence on the dynamics of the organizational activities, in particular, related to the quality management. Discusses capitalist logic of maximization of profits that has been sophisticated in face of new scenarios that arise with society evolution. It also proposes a reflection on the philosophies and formats of management that fits with the desire to meet the needs of society through the expansion of quality - now a reference for the production processes and management systems. The work highlights the relations between communication and quality, pointing them as fundamental to the use of fissures on the evolution of the capitalist system in developing programs, philosophies and management systems. The intention is to turn able ways to contemplate the needs and interests of the largest number of public and variables in a different relation than the usual, in which a few wins and many lose
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The Environmental Protection Areas (EPA) are a type of sustainable use conservation unit, therefore its territory have public and private areas. To establish and reorganize the use of EPA’s territory, aiming the environment conservation along with human actions, it is necessary a management plan that should be conducted within five years from the date of its creation. The EPA Botucatu, established in 1983, does not have its management plan completed until the present day. The consequences of lack of organization about the use and occupation of its territory can be observed in a comparative study of territorial classification between the years 1985 and 2010, which was the objective of this study. As a result, it could be observed the decrease of the remaining fragments and intense fragmentation of them, pointing to the need for projects that aim the restoration, conservation and connectivity between these fragments and the subsequent application
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The work below boards critically the issues involved in the study of the microbiota of milk. It starts with a contextualization of the current dairy chain, in the presence of Normative Instruction - 51. Following are developed the most relevant concepts and definitions about the subject: the emergence of psychrotrophic, mesophilic acidifying metabolism, the injuries of marginal cooling. Next, the main genres that comprise the milky microbiota are described, in front of the following question: from what point the metabolism of these bacteria is no longer beneficial and becomes a deteriorating activity to the product? The paper does not end with classical conclusions or definite answers, but with questions, pointing out lines of research that can improve the quality of Brazilian milk, making it a differentiated and competitive product at the international market
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The object of this study was to analyze the process of implementing the compulsory education to nine years, according to the Law 11.274/06, in Rio Claro. Thus it was established a brief analysis of the trajectory of Brazilian educational policy that began with the Law of Directives and Bases 4.024/61 and was followed by the Law 5.692/71, the 1988 Federal Constitution, the Law of Directives and Bases 9394 / 96, the National Educational Plan - Law 10.172/01, Law 11.114/05, 11.274/06 and the Constitutional Amendment. 59/2009, pointing to increase access to education that aims to expand and ensure free education and compulsory basic education for children aging from 04 to 17 years old. The research has been based on collecting bibliographical data, information and data for the municipality of Rio Claro, through official documents, semi-structured interviews, and research on government websites. The expansion of basic education to nine years has been securing the rights gained over time through education. Moreover, this expansion of education promotes a questioning about the quality of teaching and a concern for the financial contributions required for education.
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Pós-graduação em Educação - IBRC