Esiselvitys puupolttoaineen jalostamisesta torrefiointitekniikalla

Fossiilisten polttoaineiden käytöstä aiheutuvia kasvihuonekaasupäästöjä pyritään vähentämään EU:ssa mm. päästökaupan avulla. Uusiutumattomien polttoaineiden tilalle kehitetään biopolttoaineita, joita voidaan hyödyntää olemassa olevien voimalaitosten polttolaitteistoilla. Biopolttoaineiden etuna on, ettäniiden ei katsota lisäävän hiilidioksidipäästöjä, koska biomassa sitoo itseensä kasvaessaan poltossa vapautuvan määrän hiiltä. Eräs kiinnostavimmista jalostetuista biopolttoaineista on torrefioitu puu, joka vastaa useimmilta ominaisuuksiltaan kivihiiltä ja jota voidaan käyttää hiilivoimalaitoksissa ilman laitteistomuutoksia. Torrefiointi on puun eräänlaista paistamista hapettomissa olosuhteissa 250-270ºC:ssa, jolloin siitä saadaanpoistettua vesi ja osa haihtuvista aineista. Puun väri muuttuu suklaanruskeaksi, se kevenee, ei savuta poltettaessa, hylkii vettä, jauhautuu hyvin sekä sillä on pienet hiukkaspäästöt. Käsitellyn puun ominaisuudet muuttuvat säilyvyydeltään ja käyttöominaisuuksiltaan merkittävästi raaka-aineeseen verrattuna. Torrefioinnilla saavutetaan puulle polttoainekäytön kannalta myös paremmat ja kestävämmät ominaisuudet kuin hiiltämällä. Torrefiointiprosessia on tutkittu jonkin verran ja torrefioidun biomassan polttoa voimalaitosmittakaavassa on kokeiltu pienessä mittakaavassa. Torrefioitu materiaali on alhaisen tiheytensä vuoksi hankalaa ja kallista kuljettaa,joten sen tiheyttä tulee nostaa kuljetuksia varten tiivistämällä esim.pelletöimällä. Torrefionti yhdistettynä pelletöintiin on parhaimmillaan kilpailukykyinen vaihtoehto, kun kivihiiltä korvaavaa biomassaa jalostetaan kaukana käyttöpaikasta ja kuljetetaan irtotavarana aluskuljetuksina. Torrefioitua puuta on tiettävästi poltettu vain hollantilaisessa voimalaitoksessa. Tässä esiselvityksessä kootun tiedon perusteella torrefioidun puupolttoaineen tuottamiseen Suomen olosuhteissa arvioidaan olevan teknis-taloudellisia mahdollisuuksia. Kuitenkin torrefiointiprosessin soveltaminen suomen olosuhteisiin ja kotimaisiin raakaaineisiin vaatii panostusta jatkotutkimukseen ennen varsinaiseen toteutusvaiheeseen siirtymistä.

Reduction of Greenhouse Gas Emissions in North-West Russia - Finnish Business Opportunities

Tutkimus suomalaisten yritysten liiketoimintamahdollisuuksista hiilidoksidipäästöjen vähentämisen parissa Luoteis-Venäjällä.

Formation and Control of Trace Metal Emissions in Co-Firing of Biomass, Peat, and Wastes in Fluidised Bed Combustors

Environmentally harmful consequences of fossil fuel utilisation andthe landfilling of wastes have increased the interest among the energy producers to consider the use of alternative fuels like wood fuels and Refuse-Derived Fuels, RDFs. The fluidised bed technology that allows the flexible use of a variety of different fuels is commonly used at small- and medium-sized power plants ofmunicipalities and industry in Finland. Since there is only one mass-burn plantcurrently in operation in the country and no intention to build new ones, the co-firing of pre-processed wastes in fluidised bed boilers has become the most generally applied waste-to-energy concept in Finland. The recently validated EU Directive on Incineration of Wastes aims to mitigate environmentally harmful pollutants of waste incineration and co-incineration of wastes with conventional fuels. Apart from gaseous flue gas pollutants and dust, the emissions of toxic tracemetals are limited. The implementation of the Directive's restrictions in the Finnish legislation is assumed to limit the co-firing of waste fuels, due to the insufficient reduction of the regulated air pollutants in the existing flue gas cleaning devices. Trace metals emission formation and reduction in the ESP, the condensing wet scrubber, the fabric filter, and the humidification reactor were studied, experimentally, in full- and pilot-scale combustors utilising the bubbling fluidised bed technology, and, theoretically, by means of reactor model calculations. The core of the model is a thermodynamic equilibrium analysis. The experiments were carried out with wood chips, sawdust, and peat, and their refuse-derived fuel, RDF, blends. In all, ten different fuels or fuel blends were tested. Relatively high concentrations of trace metals in RDFs compared to the concentrations of these metals in wood fuels increased the trace metal concentrations in the flue gas after the boiler ten- to hundred-folds, when RDF was co-fired with sawdust in a full-scale BFB boiler. In the case of peat, lesser increase in trace metal concentrations was observed, due to the higher initial trace metal concentrations of peat compared to sawdust. Despite the high removal rate of most of the trace metals in the ESP, the Directive emission limits for trace metals were exceeded in each of the RDF co-firing tests. The dominat trace metals in fluegas after the ESP were Cu, Pb and Mn. In the condensing wet scrubber, the flue gas trace metal emissions were reduced below the Directive emission limits, whenRDF pellet was used as a co-firing fuel together with sawdust and peat. High chlorine content of the RDFs enhanced the mercuric chloride formation and hence the mercury removal in the ESP and scrubber. Mercury emissions were lower than theDirective emission limit for total Hg, 0.05 mg/Nm3, in all full-scale co-firingtests already in the flue gas after the ESP. The pilot-scale experiments with aBFB combustor equipped with a fabric filter revealed that the fabric filter alone is able to reduce the trace metal concentrations, including mercury, in the flue gas during the RDF co-firing approximately to the same level as they are during the wood chip firing. Lower trace metal emissions than the Directive limits were easily reached even with a 40% thermal share of RDF co-firing with sawdust.Enrichment of trace metals in the submicron fly ash particle fraction because of RDF co-firing was not observed in the test runs where sawdust was used as the main fuel. The combustion of RDF pellets with peat caused an enrichment of As, Cd, Co, Pb, Sb, and V in the submicron particle mode. Accumulation and release oftrace metals in the bed material was examined by means of a bed material analysis, mass balance calculations and a reactor model. Lead, zinc and copper were found to have a tendency to be accumulated in the bed material but also to have a tendency to be released from the bed material into the combustion gases, if the combustion conditions were changed. The concentration of the trace metal in the combustion gases of the bubbling fluidised bed boiler was found to be a summary of trace metal fluxes from three main sources. They were (1) the trace metal flux from the burning fuel particle (2) the trace metal flux from the ash in the bed, and (3) the trace metal flux from the active alkali metal layer on the sand (and ash) particles in the bed. The amount of chlorine in the system, the combustion temperature, the fuel ash composition and the saturation state of the bed material in regard to trace metals were discovered to be key factors affecting therelease process. During the co-firing of waste fuels with variable amounts of e.g. ash and chlorine, it is extremely important to consider the possible ongoingaccumulation and/or release of the trace metals in the bed, when determining the flue gas trace metal emissions. If the state of the combustion process in regard to trace metals accumulation and/or release in the bed material is not known,it may happen that emissions from the bed material rather than the combustion of the fuel in question are measured and reported.

Ash Particle Erosion on Steam Boiler Convective Section

In this study, equations for the calculation of erosion wear caused by ash particles on convective heat exchanger tubes of steam boilers are presented. Anew, three-dimensional test arrangement was used in the testing of the erosion wear of convective heat exchanger tubes of steam boilers. When using the sleeve-method, three different tube materials and three tube constructions could be tested. New results were obtained from the analyses. The main mechanisms of erosionwear phenomena and erosion wear as a function of collision conditions and material properties have been studied. Properties of fossil fuels have also been presented. When burning solid fuels, such as pulverized coal and peat in steam boilers, most of the ash is entrained by the flue gas in the furnace. In bubbling andcirculating fluidized bed boilers, particle concentration in the flue gas is high because of bed material entrained in the flue gas. Hard particles, such as sharp edged quartz crystals, cause erosion wear when colliding on convective heat exchanger tubes and on the rear wall of the steam boiler. The most important ways to reduce erosion wear in steam boilers is to keep the velocity of the flue gas moderate and prevent channelling of the ash flow in a certain part of the cross section of the flue gas channel, especially near the back wall. One can do this by constructing the boiler with the following components. Screen plates can beused to make the velocity and ash flow distributions more even at the cross-section of the channel. Shield plates and plate type constructions in superheaters can also be used. Erosion testing was conducted with three types of tube constructions: a one tube row, an inline tube bank with six tube rows, and a staggered tube bank with six tube rows. Three flow velocities and two particle concentrations were used in the tests, which were carried out at room temperature. Three particle materials were used: quartz, coal ash and peat ash particles. Mass loss, diameter loss and wall thickness loss measurements of the test sleeves were taken. Erosion wear as a function of flow conditions, tube material and tube construction was analyzed by single-variable linear regression analysis. In developing the erosion wear calculation equations, multi-variable linear regression analysis was used. In the staggered tube bank, erosion wear had a maximum value in a tube row 2 and a local maximum in row 5. In rows 3, 4 and 6, the erosion rate was low. On the other hand, in the in-line tube bank the minimum erosion rate occurred in tube row 2 and in further rows the erosion had an increasing value, so that in a six row tube bank, the maximum value occurred in row 6.

Paleontología cultural y Etnopaleontología. Dos nuevos enfoques sobre el registro fósil

En este artículo se dan a conocer las características de una nueva línea de investigación, abierta y desarrollada por el autor, que integra conocimientos provenientes de cuatro disciplinas académicas distintas: Paleontología, Lingüística, Literatura y Etnología. Asimismo se apuntan algunas posibilidades de aplicación educativa y/o de vinculación curricular.

Espeleotoponímia de motivació paleontològica i antracotoponímia de les Illes Balears

En aquest treball es recopilen i estudien, des d’una perspectiva etnopaleontològica, les aportacions i influencies exercides pels fòssils en relació al patrimoni onomàstic toponímic relacionat amb cavitats càrstiques de l’àmbit geogràfic de les Illes Balears. Generalment es tracta de microtopònims moderns o recents, en vies de popularització i/o tradicionalització (neotopònims), establerts pels científics que estudien les coves i/o esportistes del món de l’espeleologia (topocultismes). Es poden distingir entre espeleotopònims de primer ordre (quan es refereixen a cavitats completes) i de segon ordre (quan es refereixen a un sector d’una cavitat). També es realitza una primera aproximació als topònims referits a mines d’extracció de carbó fòssil (antracotopònims).

Nuevos datos sobre los yacimientos wurmienses del litoral catalán

We present a new bed of cold Malacological fauna of the Wrm in the Catalan littoral, one af its species is dated for the first time iii the hlediterranean (Sipho curtus). We point out the predorninance of Gasteropoda as regards Bivalves in comparison with the other cold beds known.

Reexposure and advection of C-14-depleted organic carbon from old deposits at the upper continental slope

Outcrops of old strata at the shelf edge resulting from erosive gravity-driven flows have been globally described on continental margins. The reexposure of old strata allows for the reintroduction of aged organic carbon (OC), sequestered in marine sediments for thousands of years, into the modern carbon cycle. This pool of reworked material represents an additional source of C-14-depleted organic carbon supplied to the ocean, in parallel with the weathering of fossil organic carbon delivered by rivers from land. To understand the dynamics and implications of this reexposure at the shelf edge, a biogeochemical study was carried out in the Gulf of Lions (Mediterranean Sea) where erosive processes, driven by shelf dense water cascading, are currently shaping the seafloor at the canyon heads. Mooring lines equipped with sediment traps and current meters were deployed during the cascading season in the southwestern canyon heads, whereas sediment cores were collected along the sediment dispersal system from the prodelta regions down to the canyon heads. Evidence from grain-size, X-radiographs and Pb-210 activity indicate the presence in the upper slope of a shelly-coarse surface stratum overlying a consolidated deposit. This erosive discontinuity was interpreted as being a result of dense water cascading that is able to generate sufficient shear stress at the canyon heads to mobilize the coarse surface layer, eroding the basal strata. As a result, a pool of aged organic carbon (Delta C-14 = -944.5 +/- 24.7%; mean age 23,650 +/- 3,321 ybp) outcrops at the modern seafloor and is reexposed to the contemporary carbon cycle. This basal deposit was found to have relatively high terrigenous organic carbon (lignin = 1.48 +/- 0.14 mg/100 mg OC), suggesting that this material was deposited during the last low sea-level stand. A few sediment trap samples showed anomalously depleted radiocarbon concentrations (Delta C-14 = -704.4 +/- 62.5%) relative to inner shelf (Delta C-14 = -293.4 +/- 134.0%), mid-shelf (Delta C-14 = -366.6 +/- 51.1%), and outer shelf (Delta C-14 = -384 +/- 47.8%) surface sediments. Therefore, although the major source of particulate material during the cascading season is resuspended shelf deposits, there is evidence that this aged pool of organic carbon can be eroded and laterally advected downslope.

Natural or naturalized? phylogeography suggests that the abundant sea urchin arbacia lixula Is a recent Colonizer of the Mediterranean

We present the global phylogeography of the black sea urchin Arbacia lixula, an amphi-Atlantic echinoid with potential to strongly impact shallow rocky ecosystems. Sequences of the mitochondrial cytochrome c oxidase gene of 604 specimens from 24 localities were obtained, covering most of the distribution area of the species, including the Mediterranean and both shores of the Atlantic. Genetic diversity measures, phylogeographic patterns, demographic parameters and population differentiation were analysed. We found high haplotype diversity but relatively low nucleotide diversity, with 176 haplotypes grouped within three haplogroups: one is shared between Eastern Atlantic (including Mediterranean) and Brazilian populations, the second is found in Eastern Atlantic and the Mediterranean and the third is exclusively from Brazil. Significant genetic differentiation was found between Brazilian, Eastern Atlantic and Mediterranean regions, but no differentiation was found among Mediterranean sub-basins or among Eastern Atlantic sub-regions. The star-shaped topology of the haplotype network and the unimodal mismatch distributions of Mediterranean and Eastern Atlantic samples suggest that these populations have suffered very recent demographic expansions. These expansions could be dated 94-205 kya in the Mediterranean, and 31-67 kya in the Eastern Atlantic. In contrast, Brazilian populations did not show any signature of population expansion. Our results indicate that all populations of A. lixula constitute a single species. The Brazilian populations probably diverged from an Eastern Atlantic stock. The present-day genetic structure of the species in Eastern Atlantic and the Mediterranean is shaped by very recent demographic processes. Our results support the view (backed by the lack of fossil record) that A. lixula is a recent thermophilous colonizer which spread throughout the Mediterranean during a warm period of the Pleistocene, probably during the last interglacial. Implications for the possible future impact of A. lixula on shallow Mediterranean ecosystems in the context of global warming trends must be considered.

Catálogo sistemático y estratigráfico de los Pectínidos del Neógeno del NE de España (Excepto Baleares)

Se da un catálogo sistemático y estratigráfico de los pectnidos del Negeno del NE de España.

Sobre el Garumniense de Claret (Tremp-Lérida) y su 'contaminación' por el Ilerdiense.

El estudio de la serie marina del Ilerdiense del Oeste (le Tremp (Lérida), sobre todo en el corte de la Carretera de Tremp a Pont de Montañana, ha sido ya realizado y sus resultados publicados parcialmente (DE REKZI 1965 y en prensa)...

Pienten biopolttolaitosten modulointi

Biopolttoaineiden käyttö energiantuotannossa lisääntyy ja syrjäyttää samalla fossiilisia polttoaineita. Etenkin puupohjaisten polttoaineiden käyttö pienenergiantuotannossa on lisääntynyt nopeasti. Tätä kehitystä puoltavat tiukentuneet päästörajat ja yleinen mielipide fossiilisia polttoaineita vastaan sekä biopolttoaineiden verottomuus. Tästä johtuen biopolttoainetta käyttävien laitosten kysyntä kasvaa jatkuvasti. Kysynnän kasvaessa biopolttolaitosten valmistajien on pystyttävä nopeaan, tehokkaaseen ja laadukkaaseen toimintaan, sekä täyttämään asiakkaan tarpeet pystyäkseen vastaamaan alan kasvavaan kilpailuun. Tässä diplomityössä kehitetään standardoitua moduulirakennetta Sermet BioGrate ja BioGrate compact kattilalaitoksille. Moduloinnin tarkoituksena on helpottaa laitoskonseptin kokoonpanon suunnittelua, tarjousten ja tarjouslaskelmien tekemistä sekä yhtenäistää toimintatapoja, mikä vähentää työmäärää ja nopeuttaa toimituksia.

Moluscos y crustáceos: una relación traumática. Evidencias en el Plioceno catalán

Se estudian y comparan las trazas de depredación realizadas presumiblemente por crustáceos dedópodos sobre conchas degasterpodos y bivalvos procedentes de las áreas pliocéanicas catalanas del Baix Llobregat y del Empordà.

Euthyneura del Plioceno del Empordà (Girona). Descriptiva y sistemática

En el presente trabajo se describen.16 especies de Euthyneura procedentes del Plioceno ael Empordh. Girona. Para ello se ha tenido en cuenta tanto el material nuevo como el procedente de las colecciones ya existentes, Cuando el numero dc individuos lo ha permitido, la descripcion ha sido acompañada por los siguientes datos numericos: valor maximo (M), minimo (m), media (x). desviación tipica (S). varianza (s2). intervalos media y varianza. asi como elcoeficiente de correlación (r).

Moluscos y crustáceos: una relación traumática. Evidencias en el Plioceno catalán

Se estudian y comparan las trazas de depredación realizadas presumiblemente por crustáceos dedópodos sobre conchas degasterpodos y bivalvos procedentes de las áreas pliocéanicas catalanas del Baix Llobregat y del Empordà.