General synthesis of two-dimensional patterned conducting polymer-nanobowl sheet via chemical polymerization

A general method for the generation of two-dimensional (2D) ordered, large-area, and liftable conducting polymer-nanobowl sheet has been demonstrated via chemical polymerization for the first time. The sheet is made using the monolayer self-assembled from polystyrene (PS) spheres at the aqueous/air interface as template, followed by depositing conducting polymer on the part of PS monolayer submerging in the aqueous phase via chemical polymerization, and core extraction. During the process of polymerization, no substrate is required, which caused the as-prepared patterned conducting polymer sheet can be easily lifted-off and deposited, in full size, on any flat substrate. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Fourier transform infrared (FTIR) spectrum were used to characterize the products

Temperature conditions during 'cold' sheet metal stamping

This paper investigates the friction and deformation-induced heating that occurs during the stamping of high strength sheet steels, under room temperature conditions. A thermo-mechanical finite element model of a typical plane strain stamping process was developed to understand the temperature conditions experienced within the die and blank material; and this was validated against experimental measurements. A high level of correlation was achieved between the finite element model and experimental data for a range of operating conditions and parameters. The model showed that the heat generated during realistic production conditions can result in high temperatures of up to 108 °C and 181 °C in the blank and die materials, respectively, for what was traditionally expected to be 'cold' forming conditions. It was identified that frictional heating was primarily responsible for the peak temperatures at the die surface, whilst the peak blank temperatures were caused by a combination of frictional and deformation induced heating. The results provide new insights into the local conditions within the blank and die, and are of direct relevance to sheet formability and tool wear performance during industrial stamping processes. © 2014 Elsevier B.V. All rights reserved.