含油废水处理工艺中细菌多样性

从辽河油田曙光污水处理厂含油废水样品中直接抽提细菌总DNA,并对总DNA中16SrRNAV3可变区序列作PCR扩增、变性梯度凝胶电泳(DGGE),与常规水质分析相结合对系统中不同处理阶段细菌种群多样性和水质之间的关系进行分析。结果表明,处理系统的不同处理阶段细菌的多样性有明显差异,既存在共同的细菌种属,也存在着各自独特的细菌种属,且细菌种群的多样性与水质CODcr和总石油烃(TPH)的浓度呈负相关,细菌种群的多样性越高,CODcr和TPH的浓度越低,反之则越高。在处理过程中,随着样品中细菌多样性的增加,种群结构之间的相似性指数(Cs)逐渐升高,最后形成了稳定的种群结构。

The Early Diagenetic Formation of Organic Sulfur in the Sediments of Mangrove Lake, Bermuda

Due to a low mineral content, the sapropelic sediments depositing in Mangrove Lake, Bermuda, provide an excellent opportunity to explore for possible additions of sulfur to organic matter during the early stages of diagenesis. We evaluated early diagenetic organic sulfur transformations by monitoring the concentrations and stable isotopic compositions of a number of inorganic and organic sulfur pools, thereby accounting for all of the sulfur in the sediments. We have identified and quantified the following sulfur pools: porewater sulfate, porewater sulfide, elemental sulfur, pyrite sulfur, hydrolyzable organic sulfur (HYOS), chromium-reducible organic sulfur (CROS), and nonchromium-reducible organic sulfur (Non-CROS). Of the organic sulfur pools, the Non-CROS pool is by far the largest, followed by CROS, and finally HYOS. By 60 cm depth these pools contribute, respectively, to 85, 7.9, and 3.6% of the total solid phase sulfur. The HYOS pool is probably of biological origin and shows no interaction with the sulfur compounds produced during diagenesis. By contrast, CROS is produced, most likely, from the diagenetic addition of polysulfides to functionalized lipids in the upper, H2S-poor, elemental sulfur-rich, region of the sediment. A portion of this sulfur pool is unstable and decomposes on contact with the H2S-rich porewaters. The portion of CROS that remains in the sulfidic waters appears to readily exchange sulfur isotopes with H2S. While some of the Non-CROS pool is of biological origin, some is also formed by the diagenetic addition of sulfur to organic compounds in the upper H2S-poor region of the sediment. By contrast with CROS, Non-CROS is not diagenetically active in the H2S-rich porewaters. Overall, somewhere between 27 and 53 % of the organic sulfur buried in Mangrove Lake sediments is of diagenetic origin, with the remaining organic sulfur derived from biosynthesis. We extrapolate our Mangrove Lake results and calculate that in typical coastal marine sediments between 11 and 29 μmol g−1 of organic sulfur will form during early diagenesis, of which 2–5 μmol g−1 will be chromium reducible.

适量添加微量元素,促进科学合理施肥

<正>农业生产中使用化肥是从单元肥料开始,由于单一营养元素的肥料不能满足作物的需求,而要施用多种单元肥料,这使施肥工序操作麻烦且难以做到科学合理。因此,复混肥料的出现是农业发展需求的结果。

土壤水分变化对长白山主要树种蒙古栎幼树生长的影响

选择长白山红松阔叶林主要优势树种蒙古栎为研究对象 ,人工控制 3种施水量研究蒙古栎幼树形态、生物量效应和光合生理特征对土壤含水量变化的响应 .结果表明 ,不同土壤含水量变化显著影响蒙古栎叶片、枝、根的生物量及其分配格局和叶片光合气体交换特征 .水分胁迫改变幼树树冠结构 ,抑制幼树树高、地径、叶片大小、地上和地下生物量 ;同时 ,蒙古栎幼树根冠生物量比随着土壤水分含量的减少显著提高 ;供水量减少对幼树净光合速率、CO2 利用率和碳利用率等特征有显著的负向影响 ;而叶片气孔导度、蒸腾速率和水分利用率对不同土壤含水量反应较复杂 ,只在土壤含水量较低时 ,幼树气孔导度、蒸腾速率明显降低 ,叶片水分利用率升高 ,表现出蒙古栎树种是干旱可变植物 ,长期水分胁迫可提高树种的耐旱能力 .

土壤中有机污染物的老化概念探讨

有机污染物进入土壤后,随着其与土壤颗粒接触时间的延长,生物可利用性明显下降,发生老化现象,存在锁定行为.国内外已经广泛开展了与土壤中有机污染物老化相关的研究,但对老化的概念和内涵却没有明确界定,造成了理解上的偏差.基于目前国内外学者对老化的理解和认识,在明确生物可利用性的基础上,阐述了老化的概念及内涵,并对其进行了清晰的界定,同时对国内外现存的相关概念进行了区分.这些探讨将为相关研究的深入开展奠定基础,为土壤中有机污染物的环境化学行为与生物修复研究提供理论支持.

站在新的历史起点上推进生态文明建设

<正>生态文明的提出是历史的必然人类历史是一部人与自然关系发展的历史,它经历了一个从被动适应到主动适应的过程。在原始社会,即渔猎文明时期,人类只是被动地适应自然,对自然界没有实质性破坏和威胁,并处处受自然界的束缚,形成了原始的文明意识,此间历时百万年。随着农业的诞生,特别是铁器生产工具的出现,人们从被动适应自然过渡到主动适应自然,并出现了农业文明,此间历时万余年。在这一时期,人们为了自身的

中国三瓣苔属(Tritomaria(Hepaticae))一新记录变型

报道了三瓣苔属(Tritomaria)的一中国新记录变型密叶三瓣苔小叶变型(Tritomariaquinquuedentata f.gracilis(Jens.)Schust.),并对该属的分类情况进行了讨论。

Integrated processing-structure-property analysis on rubber in-mold vulcanization

On the basis of the quantitative relationship among rubber processing, structure and property, the methodology of the integrated processing-structure-property analysis on rubber in-mold vulcanization is presented, and then the temporal evolution and spatial distribution characteristics of silicone rubber hot processing parameters, crosslinking structure parameters and mechanical property parameters are obtained by means of the finite element method. The present work is helpful for optimizing curing conditions, and then the design of rubber vulcanization processes according to certain requirements can be done.

Structure and luminescent properties of YAG : Eu, Bi synthesized by sol-gel method

(Y1-xEux)(3)Al5O12 and (Y1-x-yEuxBiy)(3)Al5O12 were prepared by so-gel method. Their structures of the luminophor are similar to that of YAG, which is recorded on the ASTM card and belongs to a cubic system. The luminescent properties show that the reaction temperature of the current sol-gel method is in the range of 400-500 degrees C, which is lower than that of the conventional solid state reaction. The luminophors have the strongest emission intensity when the values of x and y are 0.06 and 0.013, respectively.

YAG∶Eu~(3+)、Bi~(3+)的溶胶-凝胶法合成及其结构和发光性能

溶胶－凝胶法以其各组分混合均匀性好、反应温度低、节省能源等诸多优点而引起了人们极大兴趣［１，２］．近年来，利用该法研制玻璃和陶瓷等无机材料的报道越来越多［３，４］．但研制稀土固体发光材料的报道则较少．钇铝石榴石Ｙ３Ａｌ５Ｏ１２（ＹＡＧ）是一种很好的基…

Gas transport property of homo- and copolyimides from isomeric thiaphthalic dianhydride and oxydianiline

Gas transport properties of home- and copolyimides prepared from 3,3',4,4'- and 2,2',3,3'-thiaphthalic dianhydride (p-TDPA and m-TDPA, respectively) with 4,4-oxydianiline (ODA) were investigated. The fractional free volume of m-TDPA-ODA is larger than that of p-TDPA-ODA, and the chain segmental mobility of the former is lower than that of the latter. The permeability coefficients of m-TDPA-ODA to H-2, CO2, and O-2 are more increased by 48, 69 and 75%, at 30 degrees C and 10 atm, respectively, than those of p-TDPA-ODA; but the permselectivities of m-TDPA-ODA for H-2, CO2, and O-2 toward N-2 are more decreased by 33, 77, and 26%, respectively, than those of p-TDPA-ODA. The permeability coefficients and the diffusion coefficients of the copolyimides can be described by the following equations: log P = Phi(p) log P-p + Phi(m), log P-m and log D-a = D-a = Phi(p) log(D-alpha)(p) + Phi(m) log(D-a)(m), respectively. The variation of the permselectivity is controlled predominantly by diffusivity selectivity. These observations are interpreted in terms of variations in the fractional free volume of polyimides. (C) 1997 John Wiley & Sons, Inc.