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Resumo:
本书通过实验、计算和理论推导相结合的方法建立描述岩石流变性状的严谨的数学模型,并利用该模型来描述岩石随时间变化不可逆的变形过程.重点是建立在连续介质力学基础上的弹础塑性模型.
本书适用于从事石油勘探、水利水电、建筑、采矿、地震等相关领域从事岩石流变学研究与工程设计的科研人员和工程师,亦适用于相应专业的高等院校教师、研究生.
第一章 绪论
1.一维情况
2.平衡方程和波动理论基础
第二章 塑性力学和粘塑性力学中的一维本构方程、初值问题和边值问题
1.一维经典塑性力学问题的某些本构方程
2.半线性和拟线性率型本构方程
3.瞬态塑性应变的率型本构方程
4.特征线场,初值问题和边值问题
5.例子
第三章 理论的实验基础
1.静态实验
1.1常规试验
1.2长程试验
1.3短程试验
1.4Portevin-LeChatelier效应
2.杆的动态纵向撞击
3.重复加载试验
3.1静态加载后再动态加载
3.2动态加载后动态重复加载
第四章 用数值方法确定本构方程
1.用于数值例子中的本构方程
2.初始条件与边界条件
3.冲击波
4.数值例子
5.模型之间的比较
6.结论和某些评论
第五章 一维率型本构方程
1.动态重复加载实验对率型本构方程所加的限制条件
2.率型材料的稳态运动
3.关于率型材料的微分方程(5.1.2)的解
4.本构假设Ⅰ和Ⅱ的结论
5.关于动塑性中“平台”存在的评论
第六章 内变量描述的非弹性性状
1.加在带内变量的本构方程上的热力学限制
1.1状态空间,本构方程
1.2加在本构方程上的CLAUSIUS-DUHEM不等式的实质
2.加在本构方程的耗损部分上的热力学限制
3.构架无关原理.材料的同格群
4.对单位自由能限制的意义
5.具有内部状态变量的弹—粘塑性模型
6.具有内变量的一维塑性理论
第七章 具有内变量的材料中的加速度波
1.引言
2.拟线性假设
3.对称加速度波
4.强平衡态.强椭圆率条件
5.实加速度波
6.第二对称假设和强平衡态附近的热流
7.线性理论
8.半线性理论
第八章 经典粘塑性力学中的某些本构方程
1.BINGHAM刚/粘塑性模型
2.弹—粘塑性模型
3.拟线性模型
第九章 岩石的粘塑性本构方程
1.引言
2.标准压缩试验
3.蠕变试验
4.体积压缩性
5.结论
第十章 一维粘塑性本构方程在连续统物理的其他领域中的应用
1.引言
2.拟线性率型本构方程,电线上的实波和对称波
3.线性率型本构方程
4.关于模拟电晕效应的半线性率型本构方程
4.1一般考虑
4.2实验结果的简短描述
4.3本构方程用于数值例子
4.4数值结果与实验结果的比较
4.5关于所讲座的模型的评论和结论
5.电晕效应和波传播的与速率无关的模型
5.1引言
5.2问题的表述
5.3数值例子
5.4结论要点
第十一章 流变学模型在岩体工程中的应用
1.油井周围岩石的里面蠕变、膨胀及压缩
1.1基本方程
1.2线弹性解
1.3线性粘弹性岩石
1.4弹性/粘塑性岩石
1.5井眼周围岩石的膨胀/压缩及损伤
1.6更一般的原始应力状态
2.水平井段周围岩石的蠕变、膨胀及压缩
2.1基本方程
2.2弹性解
2.3线性粘弹性模型下水平井段周围岩石的蠕变
2.4弹性/粘塑性模型的蠕变
2.5水平井段周围岩石的蠕变、膨胀/压缩,损伤破坏
3.开挖后的岩体高边坡流变学性状的分析
3.1简介
3.2岩体流变学模型
3.3有限元分析
3.4数值结果
3.5结论
附录实验数据分析中所使用的数值方法和程序
1.引言
2.问题的表述
3.迭代方法的原理
4.卸载描述
5.边界条件
6.程序方框图
7.关于RI情况的要点
8.其他的特征线方法变量
9.要点
参考文献
Resumo:
本书介绍当前在计算固体和结构力学中广泛研究和应用的四种计算方法:有限元法、加权余量法、边界元法和无网络法,并系统论述了这四种方法的理论基础和相应的离散方法。
目录
1.1 弹性力学的基本方程和边界条件
1.2 弹性力学的变分原理
1.2.1 应变能和应变余能
1.2.2 虚位移原理和最小势能原理
1.2.3 虚应力原理和最小余能原理
1.2.4 Hellinger-Reissner变分原理
1.2.5 胡海昌-鹫津久一郎变分原理
1.2.6 参数变分原理
1.3 变分原理的应用实例
1.4 里茨法和伽辽金法
第二章 有限元法
2.1 协调模型——位移元
2.2 平衡模型Ⅰ
2.3 平衡模型Ⅱ
2.4 杂交应力模型
2.5 杂交位移模型
2.6 混合模型
第三章 常用的有限元单元
3.1 三角形单元族
3.2 等参数单元
3.3 奇异性单元
3.4 板壳单元
3.4.1 三角形薄板单元和薄壳单元
3.4.2 厚板单元和厚壳单元
第四章 材料非线性有限元法
4.1 弹塑性有限元分析
4.1.1 材料的屈服准则
4.1.2 强化理论
4.1.3 塑性本构关系
4.1.4 塑性流动理论的变分原理
4.1.5 弹塑性问题的有限元解法
4.2 蠕变的有限元分析
4.3 弹黏塑性的有限元分析
第五章 几何非线性有限元分析
5.1 有限应变与应力
5.2 变形率和本构关系
5.3 几何非线性有限元方程的建立
5.3.1 全拉格朗日列式法
5.3.2 更新的拉格朗日列式法
5.3.3 任意拉格朗日-欧拉描述法
第六章 热传导和热应力的有限元分析
6.1 热传导问题的有限元分析
6.1.1 导热的基本方程
6.1.2 稳态温度场的有限元解
6.1.3 瞬态温度场的有限元解
6.2 热弹性应力问题的有限元分析
第七章 弹性动力学问题的有限元法
第八章 加权余量法
第九章 边界元法
第十章 无网格法
第十一章 代数方程组的解法
参考文献
Resumo:
量纲分析是一门非常值得研究和学习的知识,它是探讨科学规律,解决科学和工程的一个有效的工具。熟练掌握量纲分析应当是科学和技术工作者应有的基本训练。
本书内容包括:量纲分析的基本概念;量纲分析在熟知的力学现象中的应用;量纲分析在某些经典的力学问题中的应用以及郑哲敏先生的研究集体近三四十年中在爆炸力学诸多的应用实例等几个部分。
写在前面
第1章 结论
1.1 量纲分析是分析和研究问题的有力手段和方法
1.2 物理量的度量
1.3 量纲:有量纲量和元量纲量
1.4 基本量和导出量
1.5 单摆
1.6 量纲分析的实质
1.7 量纲分析的简史
第2章 基本原理
2.1 量纲的幂次表示
2.2 II定理
2.3 自变量和基本量的选择
2.4 相似律
2.5 运用II的定理的注意点
第3章 流体力学问题
3.1 典型流动
3.2 流体力学问题中的相似准数[13]
3.3 其他相似准数
3.4 流体运动的分类
第4章 固体力学问题
4.1 弹性体的应力分析和简单结构的稳定性分析
4.2 弹性体的振动和波动
4.3 弹塑性体的应力分析
4.4 固体的拉伸断裂
第5章 固体中的热传导与热应力
5.1 固体中的热传导
5.2 弹性体内的热应力
第6章 流固耦合问题
6.1 水击
6.2 弹性和轴承
6.3 机翼的颤振
6.4 热交换器的气激振动
第7章 流体弹塑性模型
7.1 流体弹塑性体模型
7.2 化学炸药的爆炸效应问题中的相似参数
7.3 高速冲击问题中的相似参数
第8章 爆炸相似律
8.1 空中爆炸波和水中爆炸波
8.2 爆炸加工
8.3 爆破
第9章 冲击相似律
9.1 杆式穿甲弹
9.2 破甲——聚能射流的形成及其对装甲的侵彻
9.3 碎甲层裂
9.4 超高速冲击
9.5 金属射流与薄板的高速扩张断裂
9.6 煤与瓦斯突出——两相耦合介质动力学现象
第10章 数学模拟规整化
参考文献
主题索引
外国人名索引
Resumo:
《理性力学基础》为《中国科学院研究生教学丛书》之一。
《理性力学基础》系统地介绍了理性力学的主要科学体系和基本理论。《理性力学基础》由四部分,共十五章组成。第一部分综合介绍了理性力学的科学意义、方法和特点,从理性力学角度概括论述变形几何学与运动学、力学基本定律与场方程以及本构方程的一般原理。着重阐明张量和场方程的时空无差异原理,以及本构方程所应遵循的客观性原理。第二部分着重介绍简单物质的理论体系。作为典型范例进一步阐明弹性物质和简单流体的本构方程以及弹性体有限变形边值问题的分析方法。第三部分详细介绍黏弹性物质、弹塑性物质及晶体塑性的基本理论。第四部分主要介绍含缺陷物质的本构理论。
《理性力学基础》可作为力学、应用数学、理论物理等专业的研究生教材,也可供力学工作者及高等院校力学专业教师参考。
目录
第一章 绪论
1·1 理性力学目的和意义
1·2 理性力学的特点与体系
1·3 理性力学的方法
1·4 符号
第二章 变形几何学和运动学
2·1 直角坐标系的张量
2·2 物体的构形与运动
2·3 变形梯度
2·4 应变度量和面元、体元变形
2·5 应变率
第三章 基本定律与场方程
3·1 质量守恒定律
3·2 应力原理与动量守恒定律
3·3 能量守恒定律和熵定律
3·4 功共轭与应力度量
3·5 场方程
3·6 随体坐标系
第四章 本构方程的一般原理
4·1 时空系的变换
4·2 基本定律的客观性
4·3 本构方程的一般原理
第五章 简单物质
5·1 张量函数
5·2 张量函数表示定理
5·3 简单物质的本构方程
5·4 本构方程的简化形式
5·5 各向同性物质
5·6 简单固体
5·7 简单流体和流晶
5·8 内部约束
5·9 特殊类型物质
5·10 衰退记忆
第六章 弹性物质
6·1 弹性物质的本构方程
6·2 物质对称性
6·3 各向同性弹性固体
6·4 超弹性物质
6·5 各向同性超弹性物质
6·6 主轴表示
6·7 储能函数表示式
6·8 二次弹性
6·9 均匀变形场
6·10 储能函数的实验确定
第七章 弹性体有限变形边值问题
7·1 边值问题的提法
7·2 若干典型问题
7·3 平面应变问题
7·4 不可压缩各向同性弹性体
第八章 简单流体
8·1 直线流动
8·2 曲线流动
8·3 伸长历史恒定运动
8·4 定常测黏流动
8·5 Poiseuille流动
8·6 Couette流动
8·7 圆锥-平板流动
8·8 端部正应力效应
8·9 Stokes流体测黏流动
8·10 定常拉伸流动
第九章 黏弹性物质
9·1 线性黏弹性理论
9·2 非线性黏弹性固体
9·3 本构泛函展开
9·4 非线性黏弹性流体
第十章 弹塑性物质
10·1 微小变形塑性理论
10·2 张量的时间导数
10·3 有限塑性变形的本构方程
10·4 塑性大变形基本方程
10·5 Drucker公设与有限塑性变形
第十一章 晶体塑性理论
11·1 晶体塑性变形运动学
11·2 硬化规律
11·3 硬化系数表示式
11·4 晶体塑性本构关系
11·5 滑移剪切率γ(α)的存在性与惟一性
11·6 率相关流动规律
第十二章 缺陷连续统的线性理论
12·1 张量场的微分运算
12·2 协调条件
12·3 缺陷的几何意义
12·4 位错弹性理论
12·5 位错塑性理论
12·6 一般缺陷塑性理论
12·7 晶体塑性位错理论
12·8 Nye张量及缺陷塑性理论小结
12·9 位错塑性理论二维公式及算例
第十三章 非黎曼几何及流形简介
13·1 Euler空间张量场的绝对微分
13·2 曲率张量
13·3 线性空间
13·4 仿射联络空间
13·5 非完整变换
13·6 拓扑空间
13·7 微分流形
第十四章 缺陷连续统的非线性理论
14·1 非Niemann物质流形的构造
14·2 缺陷的几何意义
14·3 缺陷连续统的弹性理论
14·4 缺陷连续统的塑性理论
14·5 晶体塑性位错理论
第十五章 理性力学若干应用
15·1 有限变形的精确描述
15·2 曲线坐标的相应公式
15·3 本构方程的客观性原理
15·4 物质对称性
15·5 主轴法
15·6 客观应力率
附录 曲线坐标
1 基向量与度量张量
2 逆变导数
3 应力张
4 运动方程
Resumo:
气动声学是一门流动力学和声学之间的交叉学科,主要研究流动及其与物体相互作用产生噪声的机理。动用计算技术研究气动声学问题的手段称为计算气动声学。本文的目的是,基于高精度数值算法的研究,分别运用Lighthill比拟理论、Kirchhoff积分和直接数值模拟等方法,针对翼型绕流、激波-涡干扰和轴对称射流,研究了物面非定常脉动压力、涡脱落、激波-涡干扰以及涡对并等产生噪声的机理。首先针对声场与主流场在能级和特征尺度等方面的差异,从空间离散角度分析了几种差分格式,表明迎风紧致格式/对称紧致格式有较小的数值色散、耗散和各向异性误差,因而适用于气动噪声的计算。以Runge-Kutta格式为例,对时间离散带来的误差进行了分析。指出对声波计算来说,仅考虑格式稳定性是不够的,时间步长还受到允许色散误差和耗散误差的限制。基于保色戎关系的思想,构造了优化Runge-Kutta格式。处例显示优化Runge-Kutta格式相对于经典格式有更高的计算效率。采用3阶迎风紧致格式和3阶Runge-Kutta格式数值模拟了NACA0012翼型的可压缩非定常绕流流场,并将此流场作为近场声源,运用声学比拟理论对偶极子声和四极子声进行研究。结果指出,主流速度对远场声压有决定性影响,在来流马赫数较大时,四极子噪声和偶极子噪声具有相同量级,不能被忽略,表明了可压缩效应对声场的影响。采用5阶迎风紧致格式和4阶Runge-Kutta格式求解非定常可压缩Navier-Stokes方程,对激波-单涡/双涡干扰导致的声场进行了直接数值模拟。详细研究了激波-涡干扰产生噪声的机理,指出噪声的产生及其性质和激波变形密切相关。研究了近场噪声衰减和传播距离r的关系,发现噪声衰减大致和r~(4/5)而不是r~(1/2)成反比关系,提出这种差异是由流场的非线性效应引起的。构造了Kirchhoff积分和非定常流动计算相结合的算法。采用5阶迎风紧致格式和3阶Runge-Kutta格式对亚声速轴对称射流进行直接数值模拟。将射流流场作为近场声源,结合Kirchhoff方法求解远场 气动噪声。数值结果表明远场噪声具有方向性,噪声声压在离开对称轴20°处达到最大值。随着传播距离增大,噪声方向性逐渐减弱。
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A Constituinte começou a votar hoje o Título 4 da futura Carta, que trata da Organização dos Poderes e do Sistema de Governo. Está dividido em 5 capítulos: 1. Poder Legislativo, 2.Presidência da República,3. Governo, 4.Poder Judiciário e 5.Administração da Justiça. São ao todo 103 artigos, divididos em várias sessões, estabelecendo as tarefas de cada Poder da Nação. Os Líderes de todos os partidos começam a discutir os destaques para o primeiro capítulo, que trata do Poder Legislativo. No começo da Sessão foi aprovado todo o capítulo do Poder Legislativo, ressalvados os destaques. O primeiro destaque a ser votado foi que estabelecia o voto distrital misto. A emenda foi rejeitada. Enquanto isso o relator Bernardo Cabral se reunia com os relatores adjuntos para discutir o impasse da questão da greve dos servidores públicos. Já um texto básico, baseado no tratamento dado em outras constituições do hemisfério norte. Este texto assegura o direito de greve com restrições. Parlamentarista e presidencialistas fazem as contas a espera da votação do Sistema do Governo. Hélio Jaguaribe faz palestra em defesa do parlamentarismo. Os parlamentaristas já decidiram que não faram vinculação do Sistema de Governo com o mandato do Presidente Sarney. Segundo eles, o mandato é transitório enquanto o Sistema de Governo é permanente.Os presidencialistas convictos reagem e afirmam a vitória do presidencialismo. O presidente da Constituinte apela para que os constituintes estejam presentes no Plenário.
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Shortnose sturgeon (Acipenser brevirostrum), an endangered species, has experienced a several-fold increase in abundance in the Hudson River in recent decades. This population growth followed a substantial improvement in water quality during the 1970s to a large portion (c. 40%) of the species' summertime nursery area. Age structure and growth were investigated to evaluate the hypothesis that improvements in water quality stimulated population recovery through increased survival of young of the year juveniles. Specimens were captured using gill nets bi-monthly from November 2003 to November 2004 (n = 596). Annuli in fin spine sections were used to generate estimates of sturgeon age. Based upon a marginal increment analysis, annuli were determined to form at an annual rate. Age determinations yielded a catch composed of age 5-30 years for sizes 49-105cm Total Length (n = 554). Individual growth rate (von Bertalanffy coefficients: TL, = 1045mm, K = 0.07) for the population was similar to previous growth estimates within the Hudson River as well as proximal estuaries. Hindcast year-class strengths, based upon a recent stock assessment (Bain et al. 2000) and corrected for gill net mesh selectivity and cumulative mortality indicated high recruitments (28,000-43,000 yearlings)during 1986-1992, which were preceded and succeeded by c.5-year periods of lower recruitment (5,000-1 5,000 yearlings). Recruitment patterns were corroborated by trends in shortnose sturgeon bycatch from a Hudson utilities-sponsored monitoring program. Results indicated that Hudson River shortnose sturgeon abundance increased due to the formation of several strong year-classes occurring about five years subsequent to improved water quality in important nursery and forage habitats in the upper Hudson River estuary. (PDF contains 108 pages.)
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Background: Budesonide has a long history as intranasal drug, with many marketed products. Efforts should be made to demonstrate the therapeutic equivalence and safety comparability between them. Given that systemic availability significantly varies from formulations, the clinical comparability of diverse products comes to be of clinical interest and a regulatory requirement. The aim of the present study was to compare the systemic availability, pharmacodynamic effect, and safety of two intranasal budesonide formulations for the treatment of rhinitis. Methods: Eighteen healthy volunteers participated in this randomised, controlled, crossover, clinical trial. On two separated days, subjects received a single dose of 512 mu g budesonide (4 puffs per nostril) from each of the assayed devices (Budesonida nasal 64 (R), Aldo-Union, Spain and Rhinocort 64 (R), AstraZeneca, Spain). Budesonide availability was determined by the measurement of budesonide plasma concentration. The pharmacodynamic effect on the hypothalamic-adrenal axis was evaluated as both plasma and urine cortisol levels. Adverse events were tabulated and described. Budesonide availability between formulations was compared by the calculation of 90% CI intervals of the ratios of the main pharmacokinetic parameters describing budesonide bioavailability. Plasma cortisol concentration-time curves were compared by means of a GLM for Repeated Measures. Urine cortisol excretion between formulations was compared through the Wilcoxon's test. Results: All the enroled volunteers successfully completed the study. Pharmacokinetic parameters were comparable in terms of AUC(t) (2.6 +/- 1.5 vs 2.2 +/- 0.7), AUCi (2.9 +/- 1.5 vs 2.4 +/- 0.7), t(max) (0.4 +/- 0.1 vs 0.4 +/- 0.2), C(max)/AUC(i) (0.3 +/- 0.1 vs 0.3 +/- 0.0), and MRT (5.0 +/- 1.4 vs 4.5 +/- 0.6), but not in the case of C(max) (0.9 +/- 0.3 vs 0.7 +/- 0.2) and t(1/2) (3.7 +/- 1.8 vs 2.9 +/- 0.4). The pharmacodynamic effects, measured as the effect over plasma and urine cortisol, were also comparables between both formulations. No severe adverse events were reported and tolerance was comparable between formulations. Conclusion: The systemic availability of intranasal budesonide was comparable for both formulations in terms of most pharmacokinetic parameters. The pharmacodynamic effect on hypothalamic-pituitary-adrenal axis was also similar. Side effects were scarce and equivalent between the two products. This methodology to compare different budesonide-containing devices is reliable and easy to perform, and should be recommended for similar products intented to be marketed or already on the market.
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A systematic study on the available data of 26 metallic glasses shows that there is an intrinsic correlation between fragility of a liquid and bulk modulus of its glass. The underlying physics can be rationalized within the formalism of potential energy landscape thermodynamics. It is surprising to find that the linear correlation between the fragility and the bulk-shear modulus ratio exists strictly at either absolute zero temperature or very high frequency. Further analyses indicate that a real flow event in bulk metallic glasses is shear dominant, and fragility is in inverse proportion to shear-induced bulk dilatation. Finally, extension of these findings to nonmetallic glasses is discussed.
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Levels of concentration of lead in the hammerhead shark, Sphyrna couardi, off the Lagos Coast of Nigeria were investigated. The standard length of the specimens examined ranged from 31.4cm to 47.2cm while the weights ranged from 451.5 to 1,667g. The lead concentration ranged from 0.11 degree kg/G to 0.38 degree kg/G. The mean lead concentration was 0.56 degree kg/G (dry weight). The gill has the highest lead concentration. There was no linear correlation between the length and weight and the amount of lead concentrated
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Nutrient digestibility and amino acid availability were assessed in sharp-toothed catfish, Clarias gariepinus, fingerlings fed diets containing soyabean flour (SF) - Poultry meat meal (PMM) blends (25:75. 50:50, and 75:25) and 0.5 of 1.0%, Cr sub(2)0 sub(3). There was agreement between the pattern of overall protein digestibility and average amino acid availability despite the variability in individual amino acid availability the best dry matter, lipid and protein digestibility coefficients, and amino acid availability values were obtained with diets containing 0.5% Cr sub(2)0 sub(3). Chromic Oxide inclusion level appeared to affect nutrient availability. Increased marker level resulted into decreased nutrient digestibility coefficients. Similarly, these diets generated lower fecal crude protein than those with 1.0% Cr sub(2)0 sub(3). However, the latter group recorded higher protein retention efficiency. Dry mailer and lipid of diets containing more soyabean flour seemed to be more digestible than those of poultry meat meal. Similar trend was observed for the apparent availability of the amino acids. This investigation has indicated that low level of marker was better in digestibility study. Utilization of more SF than PMM in the diets of this catfish was more beneficial and should be encouraged in the feed industries producing catfish diets towards a better feed and waste management strategies in this aquaculture operation
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三次空气分级天然气燃烧器中稳焰器可以大幅度降低不完全燃烧热损失,但却提高了 NOx 的排放浓度,其最佳工况点为天然气管与一次风管、二次风管和三次风管的流通 面积之比为1 ∶5. 51 ∶1. 92 ∶3. 97 及天然气管与一次风管、二次风管的插深之比为 1 ∶0. 75 ∶0. 208 3 。试验表明,稳焰器的安装位置影响NOx 的排放量,烟气中NOx 最 低排放量为24. 26 mg/ m3 。
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The condensation of phenanthroline-5,6-dione (phendione) with polyamines is a versatile synthetic route to a wide variety of chelating ligands. Condensation with 2,3- napthalene diamine gives benzo[i]dipyrido[3,2-a:2',3'-c]phenazine (bdppz) a ligand containing weakly-coupled orbitals of benzophenazine (bpz) and 2,2' -bipyridinde(bpy) character. The bpy character gives Re and Ru complexes excited-state redox properties; intramolecular electron transfer (ET) takes place to the bpz portion of the ligand. The charge-separated state so produced has an extraordinarily-long 50 µs lifetime. The slow rate of charge recombination arises from a combination of extremely weak coupling between the metal center and the bpz acceptor orbital and Marcus "inverted region" behavior. Molecular orbital calculations show that only 3% the electron density in the lowest unoccupied molecular orbital lies on the bpy atoms of bdppz, effectively trapping the transferred electron on the bpz portion. The rate of charge recombination decreases with increasing driving force, showing that these rates lie in the inverted region. Comparison of forward and back ET rates shows that donor-acceptor coupling is four orders of magnitude greater for photoinduced electron transfer than it is for thermal charge recombination.
Condensation of phendione with itself or tetramines gives a series of binucleating tetrapyridophenazine ligands of incrementally-varying coordination-site separation. When a photoredox-active metal center is attached, excited-state energy and electron transfer to an acceptor metal center at the other coordination site can be studied as a function of distance. A variety of monometallic and homo- and heterodimetallic tetrapyridophenazine complexes has been synthesized. Electro- and magnetochemistry show that no ground-state interaction exists between the metals in bimetallic complexes. Excited-state energy and electron transfer, however, takes place at rates which are invariant with increasing donor-acceptor separation, indicating that a very efficient coupling mechanism is at work. Theory and experiment have suggested that such behavior might exist in extended π-systems like those presented by these ligands.
Condensation of three equivalents of 4,5-dimethyl-1,2-phenylenediamine with hexaketocyclohexane gives the trinucleating ligand hexaazahexamethyltrinapthalene (hhtn). Attaching two photredox-active metal centers and a third catalytic center to hhtn provides means by which multielectron photocatalyzed reactions might be carried out. The coordination properties of hhtn have been examined; X-ray crystallographic structure determination shows that the ligand's constricted coordination pocket leads to distorted geometries in its mono- and dimetallic derivatives.
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Coastal managers need accessible, trusted, tailored resources to help them interpret climate information, identify vulnerabilities, and apply climate information to decisions about adaptation on regional and local levels. For decades, climate scientists have studied the impacts that short term natural climate variability and long term climate change will have on coastal systems. For example, recent estimates based on Intergovernmental Panel on Climate Change (IPCC) warming scenarios suggest that global sea levels may rise 0.5 to 1.4 meters above 1990 levels by 2100 (Rahmstorf 2007; Grinsted, Moore, and Jevrejeva 2009). Many low-lying coastal ecosystems and communities will experience more frequent salt water intrusion events, more frequent coastal flooding, and accelerated erosion rates before they experience significant inundation. These changes will affect the ways coastal managers make decisions, such as timing surface and groundwater withdrawals, replacing infrastructure, and planning for changing land use on local and regional levels. Despite the advantages, managers’ use of scientific information about climate variability and change remains limited in environmental decision-making (Dow and Carbone 2007). Traditional methods scientists use to disseminate climate information, like peer-reviewed journal articles and presentations at conferences, are inappropriate to fill decision-makers’ needs for applying accessible, relevant climate information to decision-making. General guides that help managers scope out vulnerabilities and risks are becoming more common; for example, Snover et al. (2007) outlines a basic process for local and state governments to assess climate change vulnerability and preparedness. However, there are few tools available to support more specific decision-making needs. A recent survey of coastal managers in California suggests that boundary institutions can help to fill the gaps between climate science and coastal decision-making community (Tribbia and Moser 2008). The National Sea Grant College Program, the National Oceanic and Atmospheric Administration's (NOAA) university-based program for supporting research and outreach on coastal resource use and conservation, is one such institution working to bridge these gaps through outreach. Over 80% of Sea Grant’s 32 programs are addressing climate issues, and over 60% of programs increased their climate outreach programming between 2006 and 2008 (National Sea Grant Office 2008). One way that Sea Grant is working to assist coastal decision-makers with using climate information is by developing effective methods for coastal climate extension. The purpose of this paper is to discuss climate extension methodologies on regional scales, using the Carolinas Coastal Climate Outreach Initiative (CCCOI) as an example of Sea Grant’s growing capacities for climate outreach and extension. (PDF contains 3 pages)
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设计了一个激光光斑实时监测与光路自动准直装置,能够实时监测激光光斑并自动准直激光输出方向。基于透镜成像原理,使用CCD探测器获得光斑的二维成像,并根据两点确定一条直线原理和使用压电陶瓷电动调整架实现光路自动准直;监测控制程序采用虚拟仪器开发软件Lab View编写,可以实时监测激光光斑模式与光斑位置抖动情况,并进行反馈控制。经测试,设计装置的调整精度达0.5μrad,反馈控制频率约1 Hz,完全可降低或消除抖动周期在1 s以上的光斑飘移。