云南个旧塘子凹锡多金属矿床夕卡岩地质地球化学特征

从地质产状、矿物组合和岩石化学成分等方面探讨了个旧塘子凹接触带不同类型夕卡岩的特征。该夕卡岩带从内侧到外侧常具有辉石夕卡岩带和石榴子石夕卡岩带交替出现的现象，其岩石化学成分也相应地发生韵律变化，表现为在辉石夕卡岩带中SiO2和MgO含量较高，而在石榴子石夕卡岩带中CaO、TFe和Al2O3含量较高。认为夕卡岩带中的韵律变化一方面与被交代围岩中存在灰质白云岩和大理岩的互层带有关，另一方面与岩浆期后热液的渗滤交代作用有关。围岩中的灰质白云岩层被交代后形成辉石带，大理岩层被交代后形成石榴子石带。

Textural and structural properties of bioactive glasses in the system CaO-SiO2

Gel-derived CaO-SiO2 binary glasses of CaO mole fractions 0. 2, 0.3 and 0. 4 have been prepared and characterised. Pore diameter specific pore volume, skeletal density and porosity were found to increase with increasing CaO-content, whereas a concomitant decrease in specific surface area was observed. Si-29 NMR indicated that the 0.2 CaO mole fraction glass consisted of higly polymerized Q(4) and Q(3) silicate species, with some Q(2) units. With increasing CaO mole fraction, these silicate species became progressively depolymerised such that isolated SiO4 tetrahedra were detected within the 0.4 CaO glass matrix. Unusually, the glasses retained a proportion of Q(4) and Q(3) species as the CaO mole fraction was increased. All glass formulations exhibited in vitro bioactivity. The rate of hydroxyapatite precipitation followed the order 0.2 CaO > 0.4 CaO > > 0.3 CaO, an effect that is attributed to differences in the rate of dissolution of calcium from these glasses. This, in turn, appears to be dependent upon the proportion of Ca 21 participating in the formation of the glassy network.

Estudio del diagrama de fases CaO-Al2O3-CoO

Tesis (Maestría en Ciencias con Especialidad en Ingeniería Cerámica) UANL

Obtención de un material cerámico compuesto de MgAl2O4 en matriz de Al2O3 bajo la influencia de CaO por medio de microondas

Tesis (Maestría en Ciencias con Especialidad en Ingeniería Cerámica) U.A.N.L.

Sustitución del SiO? en el sistema Cao-Al?O?-SiO?, por el MnO? y su posible aplicación como pigmento cerámico.

Tesis (Maestría en Ciencias con Orientación en Química de los Materiales) UANL, 2011

Nuevo desarrollo de materiales a base de MgO-Espinel (MgO.Al2O3) - carbón por Oscar Díaz Toledo

Tesis (Doctor en Ing. de Materiales) U.A.N.L.

Influencia del hierro en la estructura del espinel en el sistema MgO-Al2O3-Fe2O3 sinterizado en horno convencional y mediante microondas

Tesis (Doctor en Ciencias de la Ingeniería de Materiales) UANL, 2001.

Estudio de las reacciones en fase sólida, dentro de la región formadora de vidrio en el sistema Na2O-CaO-SiO2 por Bellanira Garza Montoya.

[Tesis] (Doctor en Ciencias con Orientación en Ingeniería Cerámica) U.A.N.L.

Coherent tunnelling in Cu2+- and Ag2+-doped MgO and CaO: Cu2+ explored through ab initio calculations

The observation of coherent tunnelling in Cu2+ - and Ag2+ -doped MgO and CaO:Cu2+ was a crucial discovery in the realm of the Jahn-Teller (JT) effect. The main reasons favoring this dynamic behavior are now clarified through ab initio calculations on Cu2+ - and Ag2+ -doped cubic oxides. Small JT distortions and an unexpected low anharmonicity of the eg JT mode are behind energy barriers smaller than 25 cm-1 derived through CASPT2 calculations for Cu2+ - and Ag2+ -doped MgO and CaO:Cu2+ . The low anharmonicity is shown to come from a strong vibrational coupling of MO610- units (M=Cu,Ag) to the host lattice. The average distance between the d9 impurity and ligands is found to vary significantly on passing from MgO to SrO following to a good extent the lattice parameter.

Crystallization of SiO2-CaO-Na2O Glass Using Sugarcane Bagasse Ash as Silica Source

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)