991 resultados para soil organic matter, SOM


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Decomposition of plant material influences soil aggregation dynamics in ways that are still poorly understood, especially for Oxisols, in which oxides are believed to play a dominant role. In an incubation experiment, we investigated (i) the effect of plant material addition from selected monocot and dicot species on soil organic C (SOC), carbohydrate composition, fungal and total microbial biomass, and aggregation of an Oxisol; and (ii) the relationship among these properties and C mineralization patterns. The experiment was carried out at 25 °C for 180 d after addition of 11 plant materials (4 g C kg-1 soil) and a control (no plant material added). Mineralization of C during the incubation was described considering two pools of C (labile and non-labile) using a first-order plus linear fitting. Compared to the control, corn materials showed larger pentose input, greater mineralization rates for the non-labile C pool (k), greater soil pentose content (xylose + arabinose) and larger mean weight diameter of soil water-stable aggregates at 180 d of incubation. These effects were independent of changes in SOC content, suggesting that total C accrual and macroaggregation may be decoupled processes in this Oxisol. Our results support the hypothesis that the non-labile plant C pool contributes to the long-lasting stability of macroaggregates of this Oxisol and that this effect is mediated by plant and soil pentoses. We propose that plant pentose content and the decomposition rate of the slow pool (k) are useful parameters for the prediction of plant effects on aggregation dynamics of Oxisols and the selection of soil conservation practices. © 2012.

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In this paper, we report on a field experiment being carried out in a Typic Eutrorthox. The experiment was initiated in the 1997-98 agricultural season as a randomized block design with four treatments (0, 5, 10, and 20 t ha -1) of sewage sludge and five replicates. Compound soil samples were obtained from 20 subsamples collected at depths of 0-0.1 and 0.1-0.2 m. Cu, Fe, Mn, and Zn concentrations were extracted with DTPA pH 7.3; 0.1 mol L -1 HCl, Mehlich-I, Mehlich-III, and 0.01 mol L-1 CaCl 2. Metal concentrations were determined via atomic absorption spectrometry. Diagnostic leaves and the whole above-ground portion of plants were collected to determine Cu, Fe, Mn, and Zn concentrations extracted by nitric-perchloric digestion and later determined via atomic absorption spectrometry. Sewage sludge application caused increases in the concentrations of soil Cu, Fe, and Mn in samples taken from the 0-0.1 m depth evaluated by the extractants Mehlich-I, Mehlich-III, 0.01 mol L-1 HCl and DTPA pH 7.3. None of the extractants provided efficient estimates of changes in Mn concentrations. The acid extractants extracted more Cu, Fe, Mn, and Zn than the saline and chelating solutions. The highest concentrations of Cu, Fe, and Zn were obtained with Mehlich-III, while the highest concentrations of Mn were obtained with HCl. We did not observe a correlation between the extractants and the concentrations of elements in the diagnostic leaves nor in the tissues of the whole maize plant (Zea mays L.). © 2013 Springer Science+Business Media Dordrecht.

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Impacts on the environment and soil biological activity result in changes in the processes of formation of biogenic and fisiogenic aggregates. Aiming to evaluate the influence on physical and biological genesis of aggregates of Cerrado soils and determine the main environmental factors that determine the characteristics of households in the area of production under integrated crop-livestock (ICL), was developed this study in Farm Cabeceira, Maracaju-MS, in areas of ICL. The areas evaluated were: Savana, pasture/maize, corn/cotton and cotton/soybeans being evaluated during the dry (May/2009) and rainy (March 2010) season. To identify the pathways of aggregation were used morphological patterns, and established three clusters: fisiogenic, biogenic and intermediates. The aggregates were analyzed for exchangeable cations, carbon and aggregate stability, soil was analyzed for the exchangeable cations, particle size fractionation of soil organic matter, oxidizable fractions of total organic carbon, particle size analysis and soil macrofauna. In all areas studied, in the dry season, the highest values were quantified aggregate intermediates, while in the rainy season, in general, no differences were observed aggregates formed by different routes in areas except cotton/soybeans. The aggregates showed positive correlation with biogenic carbon and were found in lesser amounts compared to fisiogenic and intermediates. The different types of aggregates formed, besides having different characteristics morphological also differ as to chemical characteristics.

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Pós-graduação em Agronomia (Energia na Agricultura) - FCA

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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A simple procedure for recovering potassium dichromate (K2Cr2O7 ) from treatment of residual sulphochromic solution was proposed in the present work by means of cooling crystallization. The decrease of temperature favored the crystallization of K2Cr2O7 due to the decrease of solubility. 5.0 L of sulphochromic wastes containing 48.08 g L-1 of Cr(VI) were treated and the process of crystallization was performed in three steps until crystals were not formed anymore. On each step the content of Crtotal was determined by flame atomic absorption spectrometry and Cr(VI) by colorimetric method with 1,5- diphenylcarbazide, resulting in the removal of 91% and 92% of Crtotal and Cr(VI), respectively. After the last step, the remaining Cr(VI) in the solution was reduced to Cr(III) from the addition of NaHSO3 , recovering via precipitation in pH 8 approximately 36.13 g of Cr(OH)3 . The final supernatant was discarded since chromium content was below the maximum limit established by the Brazilian legislation for effluents discharge, which corresponds to 0.10 and 1.0 mg L-1 of Cr(VI) and Cr(III), respectively. 628.4 g of K2Cr2O7 were recovered and the salt was characterized by X-ray diffraction and differential thermal analysis. Its applicability was compared to the standard K2Cr2O7 when determining the soil organic matter, in which there was no significant difference, thus inferring that the recovered compound may be incorporated on routine analyses. This recovering process allowed the reuse of K2Cr2O7 , thus reducing costs with the acquisition of new reagents and environmental impacts caused by the inadequate discard of sulphochromic solutions.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)