Biogenic and mineral composition and foraminiferal stratigraphy of sediment cores obtained in northern Germany

The Ratekau boring ended in clays of the so-called Asterigerina-Zone; these clays have shallow-water features in the uppermost samples. The clays are overlain by deep-water clays with pteropods; this formation is split into two parts by a shallow-water deposit. The fossiliferous series ends upward in sandy deposits with shallow-water fossils. The question is raised whether the two deep-water deposits might correspond to the Lower Doberg Beds (Eochattian) and the Upper Doberg Beds (Neochattian) at the Doberg hill, closer to the rim of the basin. All fossiliferous samples from this boring are thought to be of Late Oligocene age; the boundary towards the Middle Oligocene, however, could not be ascertained. The Vaale boring ended in rather typical Septaria clay of the Middle Oligocene. This clay is capped by some metres of unfossiliferous glauconite clays, which in turn are overlain by silts and silty clays with planktonic fossils identical to those found at Dingden locality. These deposits are tentatively dated as Early Miocene. The next higher series of samples consists of sands and clays deposited in shallower waters. They contain a rich fauna of benthic molluscs, which, according to the current notion in stratigraphy, would have a Reinbek Age. In addition, they contain a set of planktonic fossils which differs from the 'Lower Miocene' assemblages. These sands and clays are overlain by a thick series of marine sands very poor in fossils. Finally, four metres of clay with foraminifera, having Younger Miocene affinities, form the top of the fossiliferous sequence. The borings at Wulksfelde and Langenhorn were not far apart and their sediments are easily correlated. Both wells start below in continental 'Lignite Sands' and contain overlying shallow water sands and clays. These yielded Hemmoor benthic mollusca, supposed to indicate Lower Miocene in the relevant literature; however, we encountered their planktonic foraminifera in the uppermost Miocene as well. The same planktonic species were found in all samples of both borings. These deposits under discussion furthermore contain a particular pteropod species. They are overlain by a thick series of gypsiferous clays, with scarce fossils. The uppermost fossiliferous clays (probably Langenfelde Age) contain another pteropod species, not met with in other samples. The discrepancies between the plankton zonation and the traditional subdivision according to benthic molluscs in the borings of Vaale, Wulksfelde and Langenhorn (and in samples from Twistringen, Dingden and Antwerp localities as well) renders the time-stratigraphic value of the denominations Reinbek and Hemmoor rather doubtful. The samples of the Westerland boring can be placed in the Gram and Sylt stages of local chronostratigraphy on the strength of the Astarte series established by HINSCH. The Gram samples contain a typical pteropod species; both groups of samples contain the same planktonic foraminifera as the borings Wulksfelde and Langenhorn. Our material did not bring the problem of the Miocene-Pliocene boundary in this region any closer to a solution. In conclusion, it can be claimed that this investigation provides strong arguments that the usual recognition of Hemmoor and Reinbek does not correspond to well-defined chronostratigraphical units. A better chronostratigraphic subdivision has to be based on the examination of many more samples, and on a better understanding of the paleoecology of the fossils involved.

Drained thaw-lake basin soil characteristics of cores from Barrow, Alaska

Arctic soils contain a large fraction of Earth's stored carbon. Temperature increases in the Arctic may enhance decomposition of this stored carbon, shifting the role of Arctic soils from a net sink to a new source of atmospheric CO2. Predicting the impact of Arctic warming on soil carbon reserves requires knowledge of the composition of the stored organic matter. Here, we employ solid state 13C nuclear magnetic resonance (NMR) spectroscopy and Fourier transform infrared-photoacoustic spectroscopy (FTIR-PAS) to investigate the chemical composition of soil organic matter collected from drained thaw-lake basins ranging in age from 0 to 5500 years before present (y BP). The 13C NMR and FTIR-PAS data were largely congruent. Surface horizons contain relatively large amounts of O-alkyl carbon, suggesting that the soil organic matter is rich in labile constituents. Soil organic matter decreases with depth with the relative amounts of O-alkyl carbon decreasing and aromatic carbon increasing. These data indicate that lower horizons are in a more advanced stage of decomposition than upper horizons. Nonetheless, a substantial fraction of carbon in lower horizons, even for ancient thaw-lake basins (2000-5500 y BP), is present as O-alkyl carbon reflecting the preservation of intrinsically labile organic matter constituents. Climate change-induced increases in the depth of the soil active layer are expected to accelerate the depletion of this carbon.

Age determination of sediment cores from the Weddell Sea

We report here the results of a study aimed at providing radiometric age control on glacial events in the Weddell Sea during the late Quaternary. Sediment cores from the eastern continental shelf, where the East Antarctic ice sheet was grounded, have recovered glacial-marine sediments resting on tills and the latter deposits predate the isotope stage 2 last glacial maximum. Sediment cores from the continental slope and rise sampled a prominent ice-rafted debris layer, and radiocarbon ages indicate that this ice-rafting event took place prior to 26 000 yr B.P. Thus, the combined data indicate that significant deglaciation of the Weddell Sea continental shelf took place prior to the last glacial maximum. Our data also suggest that the ice masses that border the Weddell Sea are more extensive than they were during the previous glacial minimum.

Age determination of sediment cores from the northern Mid-Atlantic Ridge

We construct age models for a suite of cores from the northeast Atlantic Ocean by means of accelerator mass spectrometer dating of a key core, BOFS 5K, and correlation with the rest of the suite. The effects of bioturbation and foraminiferal species abundance gradients upon the age record are modeled using a simple equation. The degree of bioturbation is estimated by comparing modeled profiles with dispersal of the Vedde Ash layer in core 5K, and we find a mixing depth of roughly 8 cm for sand-sized material. Using this value, we estimate that age offsets between unbioturbated sediment and some foraminifera species after mixing may be up to 2500 years, with lesser effect on fine carbonate (< 10 µm) ages. The bioturbation model illustrates problems associated with the dating of 'instantaneous' events such as ash layers and the 'Heinrich' peaks of ice-rafted detritus. Correlations between core 5K and the other cores from the BOFS suite are made on the basis of similarities in the downcore profiles of oxygen and carbon isotopes, magnetic susceptibility, water and carbonate content, and via marker horizons in X radiographs and ash beds.

X-ray fluorescence (XRF) measurements of two sediment cores from the Ceara Rise

Die XRF-Daten wurden an Archivhälften der Schwerelotkerne GeoB4402-2 und GeoB4407-3 erhoben, die am Nordwest-Hang des Ceará-Rückens gezogen wurden. Der Ceará-Rücken liegt im westlichen, äquatorialen Atlantik im Ablagerungsgebiet des Amazonas. Die Messdaten wurden mit dem XRF-Kern-Scanner "CORETEX (Corescanner Texel)" im Marum in Bremen erhoben, der auf dem Prinzip der Röntgenfluoreszenzanalyse beruht (gemessene Auflösung: 1 cm). Der Sedimenteintrag, speziell der Eintrag von terrigenem Material (durch Verwitterung entstandenes Material auf den Kontinenten), in die Ozeane ist ein immer noch schlecht verstandener Prozess, der aber für eine Vielzahl von geologischen Fragestellungen von entscheidender Bedeutung ist. Der terrigene Sedimenteintrag am Ceará-Rücken ist nahezu ausschließlich vom Amazonas geprägt. Die abgelagerten Sedimente auf dem Ceará-Rücken können als Zwei-Komponentensystem beschrieben werden. Eine Quelle ist der terrigene Eintrag aus dem Amazonas. Die zweite Quelle ist biogenes Kalziumkarbonat, dass vom kalkigen Plankton (vor allem Coccolithophoriden und zum Teil Foraminiferen) aus der oberen Wassersäule stammt. Heutzutage ist der westliche, tropische Atlantik die Hauptpassage des Transfers von warmem Oberflächenwasser vom Süd- in den Nordatlantik. Die Abgabe von Wärme und Feuchtigkeit aus den Tropen könnte im Zusammenhang mit kurzfristigen Klimawechseln stehen. Untersuchungen an Hand von Aufzeichnungen aus der nördlichen Hemisphäre weisen darauf hin, dass kurzfristige Klimaschwankungen der Nordhemisphäre zu Veränderungen der atmosphärischen Zirkulation in niedrigen Breiten auf einer Zeitskala von nur wenigen Tausenden Jahren führen können. Eine wichtige Frage dabei ist, wie der spätpleistozäne Eintrag von Terrigen-Material durch den Amazonas gesteuert ist durch Klimaschwankungen in den Tropen in Wechselwirkung mit den Vereisungs- und Abschmelzphasen der Nordhemisphäre. Hierbei sind sowohl die Glazial-Interglazial Zyklen als auch kurzfristige Klimaschwankungen wie die Dansgaard-Oeschger-Zyklen und die mit ihnen verbundenen Heinrich-Ereignisse von Bedeutung.