Urea-Functionalized Self-Assembled Molecular Prism for Heterogeneous Catalysis in Water

Reaction of a ditopic urea ``strut'' (L-1) with cis-(tmen)Pd(NO3)(2) yielded a 3+3] self-assembled molecular triangle (T)L-1 = 1,4-di(4-pyridylureido)benzene; tmen = N,N,N',N'-tetrame-thylethane-1,2-diamine]. Replacing cis-(tmen)Pd(NO3)(2) in the above reaction with an equimolar mixture of Pd(NO3)(2) and a clip-type donor (L-2) yielded a template-free multicomponent 3D trigonal prism (P) decorated with multiple urea moieties L-2 = 3,3'-(1H-1,2,4-triazole-3,5-diyl)dipyridine]. This prism (P) was characterized by NMR. spectroscopy, and the structure was confirmed by X-ray crystallography. The P was employed as an effective hydrogen-bond-donor catalyst for Michael reactions of a series of water-insoluble nitro-olefins in an aqueous medium. The P showed better catalytic activity compared to the urea based ligand L-1 and the triangle T. Moreover, the confined nanospace of P in addition to large product outlet windows makes this 3D architecture a perfect molecular vessel to catalyze Diels-Alder reactions of 9-hydroxymethylanthracene with N-substituted maleimide in the aqueous medium. The present results demonstrate new observations on catalytic aqueous Diels-Alder and Michael reactions in heterogeneous fashion employing a discrete 3D architecture of Pd(II). The prism was recycled by simple filtration and reused several tithes without significant loss of activity.

IMAGE DENOISING USING OPTIMALLY WEIGHTED BILATERAL FILTERS: A SURE AND FAST APPROACH

The bilateral filter is known to be quite effective in denoising images corrupted with small dosages of additive Gaussian noise. The denoising performance of the filter, however, is known to degrade quickly with the increase in noise level. Several adaptations of the filter have been proposed in the literature to address this shortcoming, but often at a substantial computational overhead. In this paper, we report a simple pre-processing step that can substantially improve the denoising performance of the bilateral filter, at almost no additional cost. The modified filter is designed to be robust at large noise levels, and often tends to perform poorly below a certain noise threshold. To get the best of the original and the modified filter, we propose to combine them in a weighted fashion, where the weights are chosen to minimize (a surrogate of) the oracle mean-squared-error (MSE). The optimally-weighted filter is thus guaranteed to perform better than either of the component filters in terms of the MSE, at all noise levels. We also provide a fast algorithm for the weighted filtering. Visual and quantitative denoising results on standard test images are reported which demonstrate that the improvement over the original filter is significant both visually and in terms of PSNR. Moreover, the denoising performance of the optimally-weighted bilateral filter is competitive with the computation-intensive non-local means filter.

Properties of tetrahedral amorphous carbon deposited by a filtered cathodic vacuum arc

The properties of a highly sp3 bonded form of amorphous carbon denoted ta-C deposited from a filtered cathodic vacuum arc (FCVA) are described as a function of ion energy and deposition temperature. The sp3 fraction depends strongly on ion energy and reaches 85% at an ion energy of 100 eV. Other properties such as density and band gap vary in a similar fashion, with the optical gap reaching a maximum of 2.3 eV. These films are very smooth with area roughness of order 1 nm. The sp3 fraction falls suddenly to almost zero for deposition above about 200 °C.

Stainless steel sandwich

The Cambridge University's Gordon Laboratory, in collaboration with Fibertech and the Defence Science and Technology Laboratory in the UK, has developed a novel melt spun fiber bore called 'Fibrecore', fabricated entirely from stainless steel with thin faceplates. Fibrecore is typically manufactured by 5mm-long and 70μm thick stainless steel fibers, produced by a melt overflow process. Its entirely metallic construction allows spot welding and tungsten inert gas welding without difficulty. Fibrecore exhibits different energy absorption mechanisms such as core cushioning, core-faceplate delamination, and plastic faceplate deformation, often in a concertina-like fashion. Its low-cost, high structural efficiency and good energy absorption characteristics make it attractive for a range of commercial and military applications. Such applications being evaluated include vehicle body panels, exhaust system noise reduction, low cost filters, and lightweight physical protection. In addition to these characteristics, Fibrecore exhibits properties such as corrosion protection, vibrational damping, and thermal insulation, which also extend its applications.

Las mujeres mozárabes : identidades híbridas y campo de acción del colectivo femenino entre Al- Andalus y la cristianidad

Resumen: La historia de los mozárabes de la Península Ibérica ha sido abordada desde múltiples perspectivas. Sin embargo, la situación de las mujeres de este colectivo no ha sido objeto de mayores estudios. El propósito del presente trabajo será realizar un primer acercamiento a la situación de las mujeres mozárabes, sus características y sus posibilidades de actuación tanto bajo las leyes islámicas, como bajo las normas cristianas. El análisis de esta cuestión se realizará teniendo en cuenta la naturaleza plástica de la identidad mozárabe, como así también el conjunto de normas internas y externas al grupo que modelaron sus posibilidades de acción.

Dilemas del paraíso : viaje, utopía ymundanidad en la literatura árabe

Resumen: La utopía y el relato de viaje conforman dos narrativas complementarias que describen mundos desconocidos, pero largamente anhelados. No obstante, en el contexto medieval, no podemos interpretar el concepto de utopía en el sentido político propio de la Modernidad, moriano, del término, sino como un proceso de construcción de expectativas que, a partir de un mismo modelo formal que se mantendrá a lo largo del tiempo en todas las manifestaciones de un país o sociedad ideal, tiende a ubicar en una lejanía inaccesible pero narrable la satisfacción de las necesidades de un presente difícil. Este es el caso de la Abundantia, la más antigua forma de utopía, vinculada al reino de Saturno y a sus múltiples versiones medievales: la Cucaña, el país de Jauja, el Dorado. Presente bajo diferentes formas en prácticamente todas las literaturas europeas occidentales, también la literatura árabe medieval hará un uso particular de la utopía y del relato de viaje, en donde incorporará su propia y específica visión religiosa y cultural. Nos proponemos entonces describir el modelo formal propio de la literatura utópica y la modalidad que adquirió el relato utópico de la Abundantia en el Islam, en particular en la leyenda de la Ciudad de Cobre, del geógrafo andalusí Abu Hamid al-Garnati, y su posterior desarrollo en Las mil y una noches.

Scaling the iHMM: Parallelization versus Hadoop

This paper compares parallel and distributed implementations of an iterative, Gibbs sampling, machine learning algorithm. Distributed implementations run under Hadoop on facility computing clouds. The probabilistic model under study is the infinite HMM [1], in which parameters are learnt using an instance blocked Gibbs sampling, with a step consisting of a dynamic program. We apply this model to learn part-of-speech tags from newswire text in an unsupervised fashion. However our focus here is on runtime performance, as opposed to NLP-relevant scores, embodied by iteration duration, ease of development, deployment and debugging. © 2010 IEEE.

UK guidance on the initial evaluation of an infant or an adolescent with a suspected disorder of sex development

It is paramount that any child or adolescent with a suspected disorder of sex development (DSD) is assessed by an experienced clinician with adequate knowledge about the range of conditions associated with DSD. If there is any doubt, the case should be discussed with the regional team. In most cases, particularly in the case of the newborn, the paediatric endocrinologist within the regional DSD team acts as the first point of contact. The underlying pathophysiology of DSD and the strengths and weaknesses of the tests that can be performed should be discussed with the parents and affected young person and tests undertaken in a timely fashion. This clinician should be part of a multidisciplinary team experienced in management of DSD and should ensure that the affected person and parents are as fully informed as possible and have access to specialist psychological support. Finally, in the field of rare conditions, it is imperative that the clinician shares the experience with others through national and international clinical and research collaboration. © 2011 Blackwell Publishing Ltd.

Peregrinación a la cibdat de gygantes : configuración del imaginario geográfico bíblico en La fazienda de Ultramar

Resumen: Dado que la imaginación medieval del mundo se nutre de ideas directamente heredadas de la Biblia, a menudo en contienda con la exploración empírica del globo terrestre, el estudio de los relatos de viajes en general, y de las guías de peregrinos a Tierra Santa en particular, nos permite comprender el modo en que el hombre de letras medieval se apropiaba del imaginario bíblico para darle forma a un mundo cuyos límites exóticos cobraban familiaridad por ser el escenario de las historias más apreciadas por los lectores de la época. Dentro del repertorio de literatura de viajes hispánica, La fazienda de Ultramar, cuya redacción se habría llevado a cabo a comienzos del siglo XIII, es un texto de singular importancia, por ser una de las más antiguas versiones en romance de la Biblia. No solo es un texto fundacional para una tradición que cambió la forma en que el hombre medieval se acercaba a las Sagradas Escrituras, sino que, debido a su carácter de itinerarium, nos permite conocer el modo en que la Biblia afectaba la imaginación del lector medieval acerca de la geografía de Tierra Santa. Es por ello que el propósito de esta comunicación será analizar el modo en que la estructura de itinerarium incide sobre el tratamiento del texto sagrado y la forma en que la lógica narrativa de los episodios bíblicos se subordina a la geográfica. De esta forma, se intentará echar luz sobre algunas cuestiones que han limitado el estudio de esta obra.

An approximate likelihood method for estimating static parameters in multi-target tracking models

This paper considers a class of dynamic Spatial Point Processes (PP) that evolves over time in a Markovian fashion. This Markov in time PP is hidden and observed indirectly through another PP via thinning, displacement and noise. This statistical model is important for Multi object Tracking applications and we present an approximate likelihood based method for estimating the model parameters. The work is supported by an extensive numerical study.

Eli, Eli, Lama Shabaqtani” la condición cristiana en el Medio Oriente

Resumen: El artículo enfoca la situación de los cristianos del Medio Oriente y trata de formular su destino colectivo en términos de “la condición cristiana”. El argumento central sostiene que la tragedia de la condición cristiana en el Medio Oriente se explica por la crisis del Estado secular provocada tanto por el factor del Islam, así como las intervenciones de potencias europeas desde las cruzadas hasta el período colonial e intervención militar de Estados Unidos en Irak en 2003. En este sentido, la actualidad no es la repetición de la historia, sino la continuidad del mismo padrón de inequidad en distintos períodos históricos dentro de las sociedades musulmanas y el intervencionismo externo/occidental que, tanto en el pasado como en la actualidad, muy pocas veces se ha preocupado por el destino de la cristiandad del Medio Oriente.

Molecular dynamics simulation of crack-tip processes in copper

The crack tip processes in copper under mode II loading have been simulated by a molecular dynamics method. The nucleation, emission, dislocation free zone (DFZ) and pile-up of the dislocations are analyzed by using a suitable atom lattice configuration and Finnis & Sinclair potential. The simulated results show that the dislocation emitted always exhibits a dissociated fashion. The stress intensity factor for dislocation nucleation, DFZ and dissociated width of partial dislocations are strongly dependent on the loading rate. The stress distributions are in agreement with the elasticity solution before the dislocation emission, but are not in agreement after the emission. The dislocation can move at subsonic wave speed (less than the shear wave speed) or at transonic speed (greater than the shear wave speed but less than the longitudinal wave speed), but at the longitudinal wave speed the atom lattice breaks down.

Turnout Intention and Social Networks

How can networking affect the turnout in an election? We present a simple model to explain turnout as a result of a dynamic process of formation of the intention to vote within Erdös-Renyi random networks. Citizens have fixed preferences for one of two parties and are embedded in a given social network. They decide whether or not to vote on the basis of the attitude of their immediate contacts. They may simply follow the behavior of the majority (followers) or make an adaptive local calculus of voting (Downsian behavior). So they either have the intention of voting when the majority of their neighbors are willing to vote too, or they vote when they perceive in their social neighborhood that elections are "close". We study the long run average turnout, interpreted as the actual turnout observed in an election. Depending on the combination of values of the two key parameters, the average connectivity and the probability of behaving as a follower or in a Downsian fashion, the system exhibits monostability (zero turnout), bistability (zero turnout and either moderate or high turnout) or tristability (zero, moderate and high turnout). This means, in particular, that for a wide range of values of both parameters, we obtain realistic turnout rates, i.e. between 50% and 90%.

Pertsonaia protagonista femeninoen ezaugarriak eta bilakaera euskal narratiba garaikidean

361 p.

Evaluation of wheat or corn dried distillers' grains with solubles on performance and carcass characteristics of feedlot steers

[EN]A study was conducted on crossbred steers (n=275; 376±924 kg) to evaluate performance and carcass quality of cattle fed wheat or corn dried distillers’ grains with solubles (DDGS). The control ration contained 86.6% rolled barley grain, 5.7% supplement and 7.7% barley silage (DM basis). The four treatments included replacement of barley grain at 20 or 40% of the diet (DM basis) with wheat or corn DDGS. Steers were slaughtered at a common end weight of 645 kg with 100 steers randomly (n=20 per treatment) selected for determination of the retail yield of sub-primal boneless boxed beef (SPBBB). Data were analyzed as a completely randomized design using pen as the experimental unit. Feeding increasing levels of wheat DDGS led to a quadratic increase in dry matter intake (DMI) (P<0.01), whereas increasing levels of corn DDGS led to a quadratic decrease in DMI (P=0.01). Average daily gain was not influenced (P=0.13) by feeding wheat or corn DDGS, but cattle fed corn DDGS exhibited a quadratic increase (P=0.01) in gain:feed. As a result, a quadratic increase (P<0.01) in calculated NEg of the diet was observed as corn DDGS levels increased. A linear decrease (P=0.04) in days on feed (169, 166 and 154 d) was noted when increasing levels of wheat DDGS (0, 20 and 40%) were fed. Dressing percentage increased in a linear fashion with wheat DDGS (P<0.01) inclusion level and in a quadratic fashion (P=0.01) as corn DDGS inclusion level increased although other carcass traits were not affected (P=0.10) by treatment. The results indicate that replacement of barley grain with corn or wheat DDGS up to 40% of the diet (DM) can lead to superior performance (improved gain:feed or reduced days on feed, respectively) with no detrimental effect on quality grade or carcass SPBBB yield.