Domingos Leite Pereira: intervenção política e acção governativa durante a Primeira República

Este trabalho tem como objecto de estudo a intervenção política e a acção governativa de Domingos Leite Pereira (1882-1956) durante a Primeira República. Nesse sentido, pretendemos estudar a sua actividade parlamentar, partidária e governativa, apontando as suas principais linhas de força, incindindo, especialmente, no quadro de grande instabilidade política, social e económica que caracterizaram o regime republicano português após a I Guerra Mundial. Por outro lado, este trabalho procura estudar a luta pelo controlo e liderança do Partido Republicano Português, no mesmo período de tempo, incindindo, com mais pormenor, na dissidência partidária que Domingos Pereira lidera entre 1920 e 1921.

Optimização de rotas na recolha de leite

O presente relatório tem por objectivo apresentar e descrever de forma detalhada o projecto “Optimização de rotas na recolha de leite”. Este projecto foi conduzido no âmbito do estágio curricular, realizado na parte não-lectiva do Mestrado em Sistemas de Informação de Gestão, do Instituto Superior de Contabilidade e Administração de Coimbra, tendo decorrido na empresa Lacticoop entre 03 de Outubro de 2011 e 27 de Julho de 2012. O projecto surge da necessidade da empresa optimizar as suas rotas de recolha de leite. Essa optimização pode ser subdividida em duas partes distintas: i) a recolha de dados, características e processos relativos à empresa e aos sistemas com que labora; ii) e o desenvolvimento do software necessário para a optimização de uma componente desses sistemas, associada ao processo de recolha de leite. O primeiro ponto envolve a recolha de informação sobre a política interna da empresa, a recolha de dados acerca dos veículos, rotas, consumos e condutores, assim como o levantamento de procedimentos e tecnologias utilizadas. O segundo ponto envolve a modelação do problema em estudo, o levantamento das necessidades de software para implementar o sistema de informação, a avaliação de soluções de software e desenvolvimento/adaptação da aplicação informática, assim como a implementação do software desenvolvido / adaptado e testes. Actualmente a empresa não dispõe de qualquer automatismo para a definição de rotas, sendo o processo de escalonamento de rotas feito manualmente. Este processo é bastante moroso e complexo, envolvendo a troca de informações entre o gestor e os condutores das viaturas. É um processo gradual, numa sequência de detecção de erros e correcção desses mesmos erros. Esta metodologia conduz a soluções bastante ineficientes, desde logo pela desactualização das soluções relativamente à efemeridade dos dados, especialmente ao nível de quantidades de recolha do produto. A razão da escolha de um sistema informático que permita optimizar as rotas prende-se essencialmente com a rapidez na obtenção de soluções e na capacidade de integração de dados actualizados. Este processo recorre a técnicas e modelos de optimização que envolvem o problema de Rotas de Veículos (Vehicle Routing Problem), sendo, em geral, um problema de difícil resolução em função do número de clientes envolvidos. Todavia, trata-se de um sistema que traz enormes benefícios no apoio ao processo de decisão por parte do gestor. Neste estágio pretendeu-se, como objectivo principal, desenvolver uma aplicação que permita optimizar as rotas dos veículos envolvidos no processo de recolha de leite. Os benefícios do sistema na diminuição de distâncias percorridas pelas viaturas de recolha e no aumento da eficiência do sistema de transportes, serão evidenciados no trabalho desenvolvido. A aplicação foi criada no software Eclipse (utilizando a linguagem Java). Na primeira fase do projecto estava previsto monitorizar as rotas e consumos dos veículos através da tecnologia de geo-posicionamento por satélite (GPS), de forma a atribuir comissões sobre a poupança de combustível aos condutores dos veículos. Não foi possível concluir esta fase devido à inexistência dessa tecnologia nas viaturas e pelo facto de a empresa ter retirado essa prioridade a esse investimento.

Cuba y la enmienda Platt; relaciones políticas entre Cuba y los Estados Unidos de la América del Norte, derivados del tratado permanente celebrado entre ambos pueblos. Conferencia pronunciada en el círculo del Partido republicano, sito en Amistad y Neptuno, Habana, isla de Cuba, en la noche del 28 de diciembre de 1914,

1. pte. Génesis del status cubano.--2. pte. Crítica del status cubano.

Memoria sobre a preferencia do leite de vaccas ao leite de cabras para o sustento das crianças principalmente nas grandes casas dos expostos e sobre algumas outras materias .../

Mode of access: Internet.

Inventario dos livros, jouraes, manuscriptos e mappas do Ernesto do Canto legados á Bibliotheca Publica de Ponta Delgada (ilha de S. Miguel) e entregues por sua viuva d. Margarida Leite do Canto.

Mode of access: Internet.

Duas sentenças proferidas no tempo da guerra da acclamação. Primeira, contra o aleivoso Domingos Leite Pereira, que quiz matar atraiçoadamente ao senhor rei D. João IV em 1647. Segunda, contra o traidor D. Fernando Telles de Faro, que desamparou a embaixada de Hollanda e fugio para Castella em 1659. Agora impressas pela primeira vez, como documentos mui necessarios á certeza da historia daquelles tempos, e exemplo dos presentes.

Mode of access: Internet.

Methodos officiaes para as analyses dos vinhos, vinagres e azeites. Sequidos da indicção summaria dos processos empregados nos laboratorios do Estado para o exame do leite e lacticinios; alcooes e aguardentes.

Mode of access: Internet.

WENCESLAU BRAZ E A POLÍTICA CAFÉ COM LEITE: Estratégias de comunicação e marketing político que o elegeram Presidente da República do Brasil

Esta pesquisa retratou o processo de comunicação e marketing político na vida pública de Wenceslau Braz, presidente do Brasil de 1914 a 1918. Ela abordou a política brasileira daquela época e mostrou as estratégias de convencimento usadas para indicação do mineiro ao cargo, revelando de que maneira a imprensa da época reagiu nesse período eleitoral. A metodologia que norteou essa dissertação foi a de Estudo de Caso , baseado nos conceitos básicos de Robert Yin, onde foram realizados vários estudos bibliográficos, documentais e entrevistas com familiares e amigos de Wenceslau. Complementarmente quatro publicações da imprensa brasileira foram analisadas. Conclui-se que a participação da imprensa nesse processo foi bem irrelevante e o processo eleitoral foi ditado pelo regime político da época.

Obtenção de organovermiculitas utilizando tensoativos e microemulsões e suas aplicações na separação de isômeros do Xileno

Surfactants are versatile organic compounds that have, in a single molecule, double chemical affinity. The surfactant molecule is composed by a hy drophobic tail group, a hydrocarbon chain (linear, branched, or mixed), and by a hydrophilic head group, which contains polar groups that makes it able to be applied in the organophilization process of natural clays. Microemulsions are microheterogeneous b lends composed by: a surfactant, an oily phase (non - polar solvent), an aqueous phase, and, sometimes, a co - surfactant (short - chain alcohol). They are systems with thermodynamic stability, transparent, and have high solubility power. Vermiculite is a clay m ineral with an expandable crystalline structure that has high cation exchange capacity. In this work vermiculite was used to obtain organoclays. The ionic surfactants dodecyl ammonium chlori de (DDAC) and cetyltrimethylammonium bromide (C 16 TAB) were used in the organophilization process. They were used as surfactant aqueous solutions and, for DDAC, as a microemulsion system. The organoclays were used to promote the separation of binary mixtures of xylene isomers (ortho - and meta - xylene). Dif ferent analytical techniques were used to characterize microemulsion systems and also the nanoclays. It was produced a water - rich microemulsion system with 0.92 nm droplet average diameter. The vermiculite used in this work has a cationic exchange capacity of 172 meq/100g and magnesium as main cation (24.25%). The basal spacing of natural vermiculite and organo - vermiculites were obtained by X - ray Diffraction technique. The basal spacing was 1.48nm for natural vermiculite, 4.01nm for CTAB - vermiculite (CTAB 4 ) , and 3.03nm for DDAC - vermiculite (DDAC M1A), that proves the intercalation process. Separation tests were carried out in glass columns using three binary mixtures of xylene (ortho - xylene and meta - xylene). The results showed that the organovermiculite pre sented an enhanced chemical affinity by the mixture of hydrocarbons, when compared with the natural vermiculite, and also its preference by ortho - xylene. A factorial experimental design 2 2 with triplicate at the central point was used to optimize the xylen e separation process. The experimental design revealed that the initial concentration of isomers in the mixture and the mass of organovermiculite were the significant factors for an improved separation of isomers. In the experiments carried out using a bin ary mixture of ortho - xylene and meta - xylene (2:1), after its percolating through the organovermiculite bed (DDAC M1), it was observed the preference of the organoclay by the ortho - xylene isomer, which was retained in greater quantity than the meta - xylene o ne. At the end of the treatment, it was obtained a final concentration in meta - xylene of 47.52%.

Estudo comparativo de diferentes sistemas de injeção de vapor aplicados à remediação de solos contaminados por diesel

Among the potentially polluting economic activities that compromise the quality of soil and groundwater stations are fuel dealers. Leakage of oil derived fuels in underground tanks or activities improperly with these pollutants can contaminate large areas, causing serious environmental and toxicological problems. The number of gas stations grew haphazardly, without any kind of control, thus the environmental impacts generated by these enterprises grew causing pollution of soil and groundwater. Surfactants using various techniques have been proposed to remedy this kind of contamination. This study presents innovation as the application of different systems containing surfactant in the vapor phase and compares their diesel removal efficiencies of soil containing this contaminant. For this, a system that contains seven injection wells the following vaporized solutions: water, surfactant solution, microemulsion and nanoemulsion, The surfactants used were saponified coconut oil (OCS), in aqueous solution and an ethoxylated alcohol UNTL-90: aqueous solution , and nanoemulsion and microemulsion systems. Among the systems investigated, the nanoemulsion showed the highest efficiency, achieving 88% removal of residual phase diesel, the most ecologically and technically feasible by a system with lower content of active matter

Quintosana e seus derivados conjugados com ácido gálico: avaliação de seu potencial antioxidante e de interferência na formação de cristais de oxalato de cálcio

Chitin is the second most abundant polysaccharide in nature and its derivative chitosan has been widely studied due to its unique chemical and pharmacological properties. However, studies show that when this molecule is used as food, drug, etc. it tends to accumulate in renal tissue and promotes an increase in calcium excretion. Nevertheless, the effect of chitosan on the formation of calcium oxalate (OxCa) crystals has never been evaluated. The formation of kidney stones (urolithiasis) is the disease that most often affects the kidneys and the urinary system. In addition, this is a disease with high prevalence and recurrence. Many molecules with antioxidant activity have been shown to decrease the potential for in vitro OxCa crystals formation. Thus, the aim of this study was to evaluate the effect of low molecular weight chitosan and its derivatives conjugated to gallic acid (AG) as antioxidant and inhibitor of OxCa crystals formation. The physico-chemical analysis confirmed the identity of chitosan. This molecule was subjected to five antioxidant tests and showed an excellent copper chelating activity. However, chitosan did not show other significant antioxidant activity. When chitosan was subjected to in vitro crystal formation tests, it increased the number of OxCa monohydrate crystals, modified the morphology of the crystals, modified the proportions between populations of crystals in solution and increased the zeta potential of these crystals formed. Four molecules of chitosan conjugated with GA were obtained. The physico-chemical analysis confirmed that chitosan and AG were covalently bonded. However, the amount of GA liked to chitosan did not increase even when 10 times more GA was used in experiment. When these derivatives were subjected to antioxidant tests, all chitosan conjugates showed higher antioxidant potential than their precursors. However, they showed different activity between them, which indicating that the position where AG is conjugated is an important factor for chitosan-GA activity. When conjugated chitosans were submitted to in vitro crystal formation tests, a reduction in the crystals number was observed when compared with those formed in the presence of unconjugated chitosan. Chitosan has a strong capacity for inducing OxCa monohydrate crystal formation, as well as modify their morphology and zeta potential. Over all, the process of conjugating AG to chitosan led to an increase in antioxidant potential of this molecule and was also able to decrease its capacity of inducing in vitro crystal formation

Avaliação térmica e desempenho do processo de secagem de misturas de graviola e leite em secador de leito de jorro

The soursop (A. muricata) is a fruit rich in minerals especially the potassium content. The commercialization of soursop in natura and processed has increased greatly in recent years. Drying fruit pulp in order to obtain the powdered pulp has been studied, seeking alternatives to ensure the quality of dehydrated products at a low cost of production. The high concentration of sugars reducing present in fruits causes problems of agglomeration and retention during fruit pulp drying in spouted bed dryers. On the other hand in relation to drying of milk and fruit pulp with added milk in spouted bed, promising results are reported in the literature. Based on these results was studied in this work drying of the pulp soursop with added milk in spouted bed with inert particles. The tests were based on a 24 factorial design were evaluated for the effects of milk concentration (30 to 50% m/m), drying air temperature (70 to 90 °C), intermittency time (10 to 14 min), and ratio of air velocity in relation to the minimum spout (1.2 to 1.5) on the rate of production, of powder moisture, yield, rate of drying and thermal efficiency of the process. There were physical and chemical analysis of mixtures, of powders and of mixtures reconstituted by rehydration powders. Were adjusted statistical models of first order to data the rate of production, yield and thermal efficiency, that were statistically significant and predictive. An efficiency greater than 40% under the conditions of 50% milk mixture, at 70 ° C the drying air temperature and 1.5 for the ratio between the air velocity and the minimum spout has been reached. The intermittency time showed no significant effect on the analyzed variables. The final product had moisture in the range of 4.18% to 9.99% and water activity between 0.274 to 0.375. The mixtures reconstituted by rehydration powders maintained the same characteristics of natural blends.

Produção do espaço e reestruturação produtiva do setor de laticínio no Rio Grande do Norte

Since the 1970s, Brazil has gone through several changes in its economic and productive structures, which have symbiotic relationship with the organization and dynamics of the Brazilian territory. This set of economic, social and technical-scientific transformations developed in the amid the productive capital restructuring, a process that occurs on a global scale, but that effective with particularities in different places. Adopting this presuposition the present research had as main objective analyze the productive restructuring of the dairy sector in Rio Grande do Norte, highlighting its relationship with production process / organization of space and its impact on the social relations of production. The adopted methodology to elaborate of this study was based on the achievement a bibliographic review with regard to proceedings of production of space and productive restructuring, document research about the dynamics of the dairy sector in Rio Grande do Norte, as well as on regulatory instructions governing the dairy production in Brazil, we achieve parallel secondary data collection, with official organs such as IBGE, EMATER and SINDLEITE. Another important methodological resource was the realization of the field research, which enabled us to empirically understand the distinct realities lived by agents acting on milk production system in Rio Grande do Norte. The analyzes performed nevertheless evidence that the restructuring process in the dairy sector is fomented, greatly by state,that finance, encourages and normatizes the production of milk in the country. In the specific case of Rio Grande do Norte, this process is boosted by the creation of "Programa do Leite," which by constituting of an institutional market, contributes to the strengthening and expansion of industries, the detriment of the artisanal processing sector. Nevertheless family farmers continue to act in the activity, be only producing and trading fresh milk, supplying milk to processing units, mediating the production of their peers or by the craft benefiting milk in traditional cheese factories presents in the entire state of Rio Grande do Norte. The results reveal that it is a complex web of social relations of production that are established at the heart of laticinista activity in the Rio Grande Norte, these are summarily marked by relations of competition and complementarity between industrial and artisanal processing of milk

Desenvolvimento de novos biolubrificantes hidráulicos derivados dos óleos de maracujá e de moringa in natura e epoxidados

With the increasing environmental awareness, maximizing biodegradability and minimizing ecotoxicity is the main driving force for new technological developments. Thus, can be developed new biodegradable lubricants for use in environmentally sensitive areas. The aim of this study was to obtain new bio-lubricants from passion fruit (Passiflora edulis Sims f. flavicarpa Degener) and moringa (Moringa oleifera Lamarck) epoxidized oils and develop a new additive package using experimental design for their use as a hydraulic fluid. In the first stage of this work was performed the optimization of the epoxidation process of the oils using fractional experimental design 24-1 , varying the temperature, reaction time, ratio of formic acid and hydrogen peroxide. In the second step was investigated the selectivity, thermodynamics and kinetics of the reaction for obtaining the two epoxides at 30, 50 and 70 °C. The result of the experimental design confirmed that the epoxidation of passion fruit oil requires 2 hours of reaction, 50 °C and a ratio H2O2/C=C/HCOOH (1:1:1). For moringa oil were required 2 hours reaction, 50 °C and a ratio of H2O2/C=C/HCOOH (1:1:1.5). The results of the final conversions were equal to 83.09% (± 0.3) for passion fruit oil epoxide and 91.02 (±0,4) for moringa oil epoxide. Following was made the 23 factorial design to evaluate which are the best concentrations of corrosion inhibitor and anti-wear (IC), antioxidant (BHA) and extreme pressure (EP) additives. The bio-lubricants obtained in this step were characterized according to DIN 51524 (Part 2 HLP) and DIN 51517 (Part 3 CLP) standards. The epoxidation process of the oils was able to improve the oxidative stability and reduce the total acid number, when compared to the in natura oils. Moreover, the epoxidized oils best solubilized additives, resulting in increased performance as a lubricant. In terms of physicochemical performance, the best lubricant fluid was the epoxidized moringa oil with additives (EMO-ADI), followed by the epoxidized passion fruit oil with additives (EPF-ADI) and, finally, the passion fruit in natura oil without additives (PFO). Lastly, was made the investigation of the tribological behavior under conditions of boundary lubrication for these lubricants. The tribological performance of the developed lubricants was analyzed on a HFRR equipment (High Frequency Reciprocating Rig) and the coefficient of friction, which occurs during the contact and the formation of the lubricating film, was measured. The wear was evaluated through optical microscopy and scanning electron microscopy (SEM). The results showed that the addition of extreme pressure (EP) and anti-wear and corrosion inhibitor (CI) additives significantly improve the tribological properties of the fluids. In all assays, was formed a lubricating film that is responsible for reducing the coefficient of metal-to-metal wear. It was observed that the addition of EP and IC additives in the in natura vegetable oils of passion fruit and moringa did not favor a significant reduction in wear. The bio-lubricants developed from passion fruit and moringa oils modified via epoxidation presented satisfactory tribological properties and shown to be potential lubricants for replacement of commercial mineral-based fluids.