Bioactive coating on titanium implants modified by Nd:YVO4 laser

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Electronic spectra, ESR and crystal structure of tetrahedral halocuprates(II). The existence of cations (2tbpo·H+) with a very short hydrogen bond

Two compounds [2tbpo·H+)2[CuCl4]= (yellow) and (2tbpo·H+)2[CuBr4]= (dark purple) (tbpo = tribenzylphosphine oxide) have been prepared and investigated by means of crystal structure, electronic, vibrational and ESR spectra. The crystal structure of the (2tbpo·H+)2[CuCl4]= complex was determined by three-dimensional X-ray diffraction. The compound crystallizes in the space group P42/n with unit-cell dimensions a = 19.585(2), c = 9.883(1)Å, V = 3790 (1)Å3, Z = 2, Dm = 1.303 (flotation) Dx = 1.302 Mg m-3. The structure was solved by direct methods and refined by blocked full-matrix least-squares to R = 0.053 for 2583 observed reflections. Cu(II) is coordinated to four chlorides in a tetrahedral arrangement. Tribenzylphosphine oxide molecules, related by a centre of inversion, are connected by a short hydrogen bridge. Chemical analysis, electronic and vibrational spectra showed that the bromide compound is similar to the chloride one and can be formulated as (2tbpo·H+)2[CuBr4]=. The position of the dd transition bands, the charge transfer bands, the ESR and the vibrational spectra of both complexes are discussed. The results are compared with analogous complexes cited in the literature. © 1983.

Spectroscopic studies on copper(II)triphenylarsine oxide square planar complexes

Electronic and ESR spectra of the complexes [Cu(II)(tpaso)4][Cu(I)Cl2]2,[Cu(tpaso)4](NO3)2 and [Cu(tpaso)4](ClO. © 1985.

Crystal structure of the triclinic form of (2tbpo·H +)2tetrachlorocuprate(II){[(PhCH2) 3PO]2H}2CuCl4: The presence of extremely short O-H-O interactions

The structure of {[(PhCH2)3PO]2H} 2CuCl4 has been shown to contain four [(PhCH 2)3PO]2H+ cations with extremely short O-H-O distances of 2.295, 2.364, 2.394, and 2.404 Å, respectively.

Synthesis, structure, and electronic and EPR spectra of copper(II) complexes containing the [CuBr4]2- anion and triphenylarsine oxide

The preparation and characterization of (Ph3AsOH)2[CuBr4] and [Cu(Ph3AsO)4][CuBr4] are reported (Ph3AsO = triphenylarsine oxide). Crystallographic analysis of the monoclinic crystals of (Ph3AsOH)2[CuBr4] (space group C2/c, a = 17.569 (3) Å, b = 13.090 (2) Å, c = 16.933 (2) Å, and β = 105.64 (2)°, R = 0.055 and Rw = 0.057) revealed the presence of compressed [CuBr4]2- tetrahedra of C2 symmetry with Cu-Br distances of 2.340 (1) and 2.437 (1) Å and trans-Br-Cu-Br angles of 139.2 (1) and 122.4 (1)°. The oxonium cations hydrogen bond to the bromine atoms involved in the longer Cu-Br bonds and the smaller trans-Br-Cu-Br angle. Single-crystal electronic and EPR spectra are interpreted in terms of the observed [CuBr4]2- geometry. Analysis of the electronic and EPR spectra of [Cu(Ph3AsO)4][CuBr4] led to the postulation of the presence of planar [Cu(Ph3AsO)4]2+ cations and distorted tetrahedral [CuBr4]2- anions. © 1992 American Chemical Society.

Comparative mechanical study of isolated papillary muscle from Wistar-Kyoto and Wistar rats

Isolated papillary muscles have often been used in myocardial mechanical function studies. The objective of the present study was to compare the mechanical function of papillary muscle isolated from left ventricle between Wistar (W) and Wistar-Kyoto (WKY) rats of different ages (1, 3, 6 and 12 months), in order to examine whether there is a difference in intrinsic mechanical properties of muscle between the two rat strains. Muscles were perfused with Krebs-Henseleit solution at 28°C and studied isometrically and isotonically at a stimulation rate of 0.2 Hz. The W and WKY showed statistically significant differences during both isometric and isotonic contractions. During isometric contraction? (l) the peak developed tension (DT) and + dT/dt were lower in WKY rats in the 1 mo groups, (2) the resting tension (RT) was greater in WKY at 3, 6 and 12 mo. (3) time to peak tension (TPT) was greater in WKY at 3 and 12 mo, (4) time for tension to fall from peak to 50% of peak tension (RT 1/2) was greater in WKY at 3 mo and (5) - dT/dt was lower in WKY at 1 and 3 mo. During isotonic contraction, (1) the peak shortening (PS) and -dL/dt were lower in WKY at 12 mo, (2) the time to peak shortening (TPS) was greater in WKY at 3 and 12 mo; (3) + dL/dt was lower in WKY at 3, 6, and 12 mo and (4) the relative variation of length (Lmax-PS)/Lmax was greater in WKY at 6 and 12 mo. These data showed a difference in mechanical behaviour of the papillary muscle between Wistar and Wistar-Kyoto rats of different age.

Toxicologic evaluation of acute and subacute oral administration of Cucurbita maxima seed extracts to rats and swine

The extract prepared from dried seeds of Cucurbita maxima was administered to rats and pigs. Following a single dose or 4 weeks of daily oral administration, the extract produced no changes in serum glucose, urea, creatinine, total protein, uric acid, GOT, GPT, LDH or blood counts. Urine analysis (urea, uric acid, creatinine, total protein, Na and K), as well as histopathological investigation, showed no abnormalities. These results taken as a whole indicate that the seeds of C. maxima as used in Brazilian folk medicine are not toxic for rats and swine.

Efeito dos reguladores de crescimento vegetal nas características agronômicas do algodoeiro e no controle de insetos

The experiment was carried out in 1993/94, in Jaboticabal, São Paulo State, Brazil, to verify the efficiency of plant growth regulators on agronomic characteristics of cotton and as pest control technique. The experimental design was a complete randomized block with four replications and seven treatments: 1) control; 2) ethephon + cyclanilide (720 + 90 g/ha a.i.); 3) ethephon + cyclanilide (960 + 120 g/ha a.i.); 4) ethephon + cyclanilide (1200 + 150 g/ha a.i.); 5) ethephon (960 g/ha a.i.); 6) ethephon (1200 g/ha a.i.) and 7) cyclanilide 150 g/ha a.i.). Results suggest that plant growth regulators can reduce harvest time in 15 days, contributing significantly to decreased late-season squares and immature bolls that serve as feeding and oviposition sites to boll weevils and pink bollworm.

Efeito de aldicarb em populações de pulgão em artrópodes benéficos e na fisiologia do algodoeiro

In order to study the efficiency of aldicarb against aphids, beneficial arthropods, and on cotton physiology, a trial was made at Jaboticabal, SP, Brazil, in 1992/93. The experimental design was a complete randomized block with seven replications and three treatments: 1) aldicarb 750 g of a.i./ha; 2) aldicarb 1050 g of a.i./ha; and 3) control. The results showed that aldicarb was effective in the control of aphids. Aldicarb applied in the furrow significantly increased boll number per plant, yield, and precociousness. The beneficial arthropods were not affected.

Avaliação da silagem de milho das variedades granífera e forrageira no desempenho de bovinos das raças nelore e cachim em regime de confinamento

The experiment was carried out to evaluate corn grain and corn forage varieties productivity and nutritive value for silage comparing to the performance of Nellore and Canchim cattle in a feedlot. A completely randomized design was used with a 2 x 2 factorial arrangement based on two breeds (Nellore and Canchim) and two corn varieties (grain and forage). Harvest was made after 120 days sowing, when plants showed more than 2/3 of dry. leaves and grains were in dough stage. The silage was stored in a 400 tons. The experimental diet consisted of grain and forage corn silage, 7,2 liters of liquid yeast (1,5 kg of dry yeast/ head/day) and 1,1 kg of ground corn (1,0 kg of dry matter/head/day). The experiment duration was 110 days, with a 20 days adaptation period and 90 days for data collection. Animals were regularly weighted every 28 days. It was concluded that corn grain was more appropriate for silage than corn forage, and in the same stage it showed a higher dry matter content and a 41.3% higher grain yield, promoting higher weight gain and better feed/gain ratio in the feedlot beef cattle.

Gênese e Classificação da Coquina de Camaquã, Formação Corumbataí (Neopermiano), na Região de Rio Claro, SP

Analysis of the taphonomic signatures of a well preserved, silicifled coquina (Pinzonella neotropica assemblage) from the Camaquã outcrop, upper part of the Corumbataí Formation (Late Permian), in the Rio Claro region, state of Sáo Paulo, allowed interpretation of processes involved in its origin as related to high energy events (storms). The coquina occurs as a lenticular body, 2-11 cm thick and extending laterally for about 120 m. Basal contact of the coquina is sharp and erosive. Its upper contact is sharp. The concentration is dominated by pelecypods including the shallow burrowers (Pinzonella neotropica, Jacquesia brasiliensis), intermediate burrower (Pyramus anceps) and semi-infaunal forms (Naiadopsis lamellosus). All these species are suspension feeders. Besides sand-sized or even smaller shell fragments, there occur disarticulated, complete shells which are commonly abraded but do not show any signs of bioerosion or incrustation. In vertical side view, the shells are mainly convex-up, nested or stacked, while in plan-view they show random orientation. Multiple discontinuous grading is visible. These taphonomic signatures suggest that the origin of the skeletal accumulation is related to high energy events (possibly storm flows) in a proximal environment. The amalgamated nature of the Camaquã coquina records several episodes of erosion and deposition.

Syntheses and luminescent properties of tetrahedral nickel(0) complexes

Tetrahedral nickel(0) complexes [NiL4], [Ni(dppe)2] and [Ni(CO)2(SbPh3)2] (L=AsPh3, SbPh3, P(OPh)3, dppe=1,2-bis(diphenylphosphino)ethane) were prepared by reduction of NiCl2·6H2O with NaBH4 under N2 or CO atmosphere in the presence of the ligand. The complex [Ni(SbPh3)4] was also obtained by electrolysis at -1.3 V (Ag/Ag+), under a platinum gauze, of the system NiCl2·6H2O/SbPh3 (molar ratio=1:4). These complexes, both in the solid state and in solution, show an orange emission at room temperature, when excited with UV radiation. A qualitative molecular orbital diagram for the [NiL4] complexes is proposed. Electronic absorption spectra of the complexes show bands near 400 nm assigned as MLCT π*2e←d2t2. A 1A1←3T1 transition is suggested for the emission observed in these systems. Lifetimes in microsecond range were estimated from time-resolved emission spectra. Spectroscopic properties of the free ligands have also been investigated.

Substituição do farelo de soja pelo de guandu na alimentação de frangos de corte

The objective of this work was to evaluate the nutritive value of pigeon pea meal (PPM) with methionine substituting soybean meal (SM) in diets for 1-28 day-old broiler chicks. The experimental design was that of random blocks, in a 3 × 3 factorial scheme with three substitution levels - 15,30 and 45% - and three methionine supplementation levels in relation to the requirements, that is: 100, 66 and 33%, with four repetitions. It was found that PPM treated for 20 minutes at 100°C substituted up to 30% of the SM, even without methionine supplementation, in relation to liveweight (p<0.01), to food conversion and to the efficiency of utilization of metabolizable energy and to protein (p<0.05). At the 66% level of methionine supplementation, the same results as for these parameters were obtained at all of the levels of substitution of SM by PPM. The 30% or 45% substitution of SM protein by that of PPM affected (p<0.01) the efficiency of methionine utilization. The sulphur amino acid utilization efficiency was affected (p<0.01) beginning at 66% methionine supplementation in the diets.

Torta de dendê em dieta para a tilápia-do-nilo: Desempenho produtivo

To evaluate the nutritional value of African palm kernel meal (Elaeis guineensis) on the performance of Nile tilapia (Oseochromis niloticus), five isonitrogenous (30% crude protein), isoenergetic (2,800 Kcal/kg of digestible energy), and isofibrous (10% crude fiber) diets, with increasing levels of African palm kernel meal (0, 7, 14, 21, 28 and 35%) were fed ad libitum for 18 weeks to Nile tilapia (Oreochromis niloticus) fingerlings, averaging 1.52 ± 0.04 g of body weight, housed for 120 days in 60 liter aquaria with six fingerlings. To determine the production traits, weight gain, apparent food conversion, specific growth rate, protein efficiency ratio, weight gain percentage, net protein utilization, and body composition, fish were weighted at six-week intervals. Statistical analysis of recorded data were performed through multivariate profile analysis and polynomial regression models. Results showed that feeding fingerling Nile tilapia with ratios containing up to 35% of African palm kernel meal does not affect production performance.