Contact electrification induced by monolayer modification of a surface and relation to acid-base interactions

Electrical charge separation following contact between two materials (contact electrification or the triboelectric effect) is well known to occur between different materials as a consequence of their different electronic structures. Here we show that the phenomenon occurs between two surfaces of the same material if one is coated with a single chemisorbed monolayer. We use the surface force apparatus to study contact electrification and adhesion between two silica surfaces, one coated with an amino-silane. The presence of this monolayer results in significantly enhanced adhesion between the surfaces, owing to electrostatic attraction following contact electrification, in accord with Derjaguin's electrostatic theory of adhesion. At the same time, the observed increase in adhesion is consistent with Fowkes' acid-base model (in which acid-base interactions between surface groups are considered to be the predominant factor determining adhesion), as the monolayer converts the originally acidic silica surface to a basic (amine-terminated) one. These observations demonstrate a link between acid- base interactions and contact electrification.

Electrical charge separation following contact between two materials (contact electrification or the triboelectric effect) is well known to occur between different materials as a consequence of their different electronic structures. Here we show that the phenomenon occurs between two surfaces of the same material if one is coated with a single chemisorbed monolayer. We use the surface force apparatus to study contact electrification and adhesion between two silica surfaces, one coated with an amino-silane. The presence of this monolayer results in significantly enhanced adhesion between the surfaces, owing to electrostatic attraction following contact electrification, in accord with Derjaguin's electrostatic theory of adhesion. At the same time, the observed increase in adhesion is consistent with Fowkes' acid-base model (in which acid-base interactions between surface groups are considered to be the predominant factor determining adhesion), as the monolayer converts the originally acidic silica surface to a basic (amine-terminated) one. These observations demonstrate a link between acid-base interactions and contact electrification.

Data-driven computation of contact dynamics during two-point manipulation of deformable objects

This study represents a preliminary step towards data-driven computation of contact dynamics during manipulation of deformable objects at two points of contact. A modeling approach is proposed that characterizes the individual interaction at both points and the mutual effects of the two interactions on each other via a set of parameters. Both global as well as local coordinate systems are tested for encoding the contact mechanics. Artificial neural networks are trained on simulated data to capture the object behavior. A comparison of test data with the output of the trained system reveals a mean squared error percentage between 1% and 3% for simple interactions.

Robust learning of discriminative projection for multicategory classification on the Stiefel manifold

Learning a robust projection with a small number of training samples is still a challenging problem in face recognition, especially when the unseen faces have extreme variation in pose, illumination, and facial expression. To address this problem, we propose a framework formulated under statistical learning theory that facilitates robust learning of a discriminative projection. Dimensionality reduction using the projection matrix is combined with a linear classifier in the regularized framework of lasso regression. The projection matrix in conjunction with the classifier parameters are then found by solving an optimization problem over the Stiefel manifold. The experimental results on standard face databases suggest that the proposed method outperforms some recent regularized techniques when the number of training samples is small.

Supervised subspace learning with multi-class Lagrangian SVM on the Grassmann manifold

Learning robust subspaces to maximize class discrimination is challenging, and most current works consider a weak connection between dimensionality reduction and classifier design. We propose an alternate framework wherein these two steps are combined in a joint formulation to exploit the direct connection between dimensionality reduction and classification. Specifically, we learn an optimal subspace on the Grassmann manifold jointly minimizing the classification error of an SVM classifier. We minimize the regularized empirical risk over both the hypothesis space of functions that underlies this new generalized multi-class Lagrangian SVM and the Grassmann manifold such that a linear projection is to be found. We propose an iterative algorithm to meet the dual goal of optimizing both the classifier and projection. Extensive numerical studies on challenging datasets show robust performance of the proposed scheme over other alternatives in contexts wherein limited training data is used, verifying the advantage of the joint formulation.

Life expectancy of rigid gas permeable and high water content contact lenses

Purpose: The purpose of this study was to evaluate the life expectancy of various rigid gas permeable (RGP) lens materials used on a daily wear basis and to compare these results with the life expectancy of a matched group of soft lens wearers.

Methods: We retrospectively analyzed the records of 600 contact lens wearing patients (300 soft contact lens users and 300 RGP lens users) fit between September 1987 and September 1994. None of the subjects wore lenses on a planned replacement system. For the purposes of the study, RGP lenses were divided into three groups: <40 Dk were considered low-Dk; 41-89 Dk were considered mid-Dk; and >90 Dk were considered high-Dk. All soft lenses were high water content lenses (>60% water content). Lenses were included if they were replaced due to loss, breakage, deposition, or poor wettability but not if replaced because of changes in fit or prescription.

Results; The mean (+SD) life-spans of each lens type in months were 19.9 +/- 17 for low-Dk RGP lenses, 15.9 +/-13.3 for mid-Dk RGP lenses, 9.0+8.2 for high-Dk RGP lenses, and 6.4 +/-5.2 for high water content soft lenses. Statistical analysis using a one-way ANOVA on ranks indicated that these results were statistically significant (P< 0.0001).

Conclusions: Patients should be informed that high-Dk lenses (RGP and soft) provide substantial clinical benefits and that they should expect to replace high-Dk RGP lenses after approximately 6 months. This lends further credence to the use of high-Dk lenses on a planned replacement basis.

Clinical performance of an innovative back surface multifocal contact lens in correcting presbyopia

Purpose: This prospective study was designed to subjectively and objectively evaluate the performance of an aspheric multifocal back surface rigid gas permeable (RGP) contact lens. The multifocal element of this lens design consisted of an aspheric optical zone that varied according to the patient's ametropia, corneal topography, and required reading addition.

Methods: We fit 28 presbyopic subjects with an aspheric multifocal back surface RGP contact lens (age range: 45 to 68 years). Reading additions ranged from +0.75 D to +2.50 D. Subjects were assessed initially and at 2, 6, and 12 weeks for ocular changes, visual performance, and subjective responses.

Results: We required 116 RGP lenses to achieve an acceptable fit and visual acuity in 28 subjects (55 eyes). At the final visit, the distance logMAR acuity with the multifocal contact lens (+0.12 +/-0.10) was not statistically different (t=-0.623, P= 0.5388) from spectacle acuity at the initial visit (+0.10 +/-0.12). The near logMAR acuity with the multifocal contact lens at the final visit (0.36 +/- 0.12) was not statistically different from that for near acuity with spectacles at the initial visit (0.33 +/- 0.13). No slit lamp signs worsened during the study. A reduction in myopia of 0.67 D was noted by the final visit. Spectacle blur was noted if the acuity at the initial refraction was compared to the acuity with the same refraction at the final visit (t= -3.287, P= 0.0028) but not when the refractive changes were incorporated (t= 1.058, P= 0.3127). All subjects rated the performance of the lenses very highly: comfort, 86%; distance acuity, 83%; near acuity, 73%; and stability of vision, 74%. Twenty-four subjects (86%) chose the multifocal contact lens as their preference.

Conclusion: We demonstrated that a multifocal design is able to provide acceptable distance and near correction for presbyopic patients. The aspheric geometry required can be optimized for a given patient by considering his/her degree of ametropia, as well as the corneal topography.

An international survey of contact lens prescribing for presbyopia

Purpose:  The aim was to determine world-wide patterns of fitting contact lenses for the correction of presbyopia.

Methods:  Up to 1,000 survey forms were sent to contact lens fitters in each of 38 countries between January and March every year over five consecutive years (2005 to 2009). Practitioners were asked to record data relating to the first 10 contact lens fittings or refittings performed after receiving the survey form.

Results:  Data were received relating to 16,680 presbyopic (age 45 years or older) and 84,202 pre-presbyopic (15 to 44 years) contact lens wearers. Females are over-represented in presbyopic versus pre-presbyopic groups, possibly reflecting a stronger desire for the cosmetic benefits of contact lenses among older women. The extent to which multifocal and monovision lenses are prescribed for presbyopes varies considerably among nations, ranging from 79 per cent of all soft lenses in Portugal to zero in Singapore. There appears to be significant under-prescribing of contact lenses for the correction of presbyopia, although for those who do receive such corrections, three times more multifocal lenses are fitted compared with monovision fittings. Presbyopic corrections are most frequently prescribed for full-time wear and monthly replacement.

Conclusions:  Despite apparent improvements in multifocal design and an increase in available multifocal options in recent years, practitioners are still under-prescribing with respect to the provision of appropriate contact lenses for the correction of presbyopia. Training of contact lens practitioners in presbyopic contact lens fitting should be accelerated and clinical and laboratory research in this field should be intensified to enhance the prospects of meeting the needs of presbyopic contact lens wearers more fully.

Trends in Australian contact lens prescribing during the first decade of the 21st century (2000–2009)

Purpose:  The aim was to document contact lens prescribing trends in Australia between 2000 and 2009.

Methods:  A survey of contact lens prescribing trends was conducted each year between 2000 and 2009. Australian optometrists were asked to provide information relating to 10 consecutive contact lens fittings between January and March each year.

Results:  Over the 10-year survey period, 1,462 practitioners returned survey forms representing a total of 13,721 contact lens fittings. The mean age (± SD) of lens wearers was 33.2 ± 13.6 years and 65 per cent were female. Between 2006 and 2009, rigid lens new fittings decreased from 18 to one per cent. Low water content lenses reduced from 11.5 to 3.2 per cent of soft lens fittings between 2000 and 2008. Between 2005 and 2009, toric lenses and multifocal lenses represented 26 and eight per cent, respectively, of all soft lenses fitted. Daily disposable, one- to two-week replacement and monthly replacement lenses accounted for 11.6, 30.0 and 46.5 per cent of all soft lens fittings over the survey period, respectively. The proportion of new soft fittings and refittings prescribed as extended wear has generally declined throughout the past decade. Multi-purpose lens care solutions dominate the market. Rigid lenses and monthly replacement soft lenses are predominantly worn on a full-time basis, whereas daily disposable soft lenses are mainly worn part-time.

Conclusions:  This survey indicates that technological advances, such as the development of new lens materials, manufacturing methods and lens designs, and the availability of various lens replacement options, have had a significant impact on the contact lens market during the first decade of the 21st Century.