浙江省金华山苔藓植物区系初报

首次报道了浙江省金华山 38科、77属 1 4 0种苔藓植物 .其中 ,苔类 1 4科 1 6属 2 0种 ,藓类 2 4科 61属1 2 0种 ;浙江省新记录种 30种 ,新记录属 7个 .该地区的苔藓植物以东亚、北温带和世界广布成分为主 ,分别占总种数的 4 0 .4 2 %、1 9.86%和 1 6.31 % ,热带成分的比例为 9.2 2 % .藓类植物中 ,主要的科为丛藓科 ( Potti-aceae)、羽藓科 ( Thuidiaceae)、青藓科 ( Brachytheciaceae)、真藓科 ( Bryaceae)和凤尾藓科 ( Fissidentaceae) ,真藓属 ( Bryum)、青藓属 ( Brachythecium)、凤尾藓属 ( Fissidens)、羽藓属 ( Thuidium)和走灯藓属 ( Plagiomnium)为5个主要属 .比较了金华山与中国其它 8个山地藓类区系的相似性 .

蛭弧菌BDG-9质粒不稳定性研究

本文建立了研究难于单独连续培养的专性蛭弧菌质粒稳定性的方法体系。应用此方法体系发现并证明了在专性蛭弧菌BDG9中所含的质粒pSTⅠ存在着独特的质粒缺失现象,当蛭弧菌BDG9单独培养时,在通常决定质粒稳定性的复制功能和分配功能都正常的情况之下,随着细胞的传代,质粒pSTⅠ逐渐丢失,蛭弧菌的生长繁殖也逐渐停止,表明质粒pSTⅠ的存在对BDG9细胞单独生长有重要作用。

1990～2000年中国土壤碳氮蓄积量与土地利用变化

基于2473个土壤剖面资料和1980年代末~1990年代末陆地卫星TM影像分析中国1990~2000年林地、草地、耕地之间的土地利用变化对土壤碳氮蓄积量的影响。IPCC建议的国家温室气体清单方法计算表明从1990~2000年中国林地、草地、耕地土壤(30cm)有机碳氮库分别损失了77.6±35.2TgC(1Tg=106t)和5.6±2.6TgN,年均损失约7.76TgC/yr和0.56TgN/yr,其中耕地土壤碳库分别增加了79.0±7.7TgC和9.0±0.7TgN,草地土壤碳氮蓄积量分别损失了100.7±25.9TgC和9.8±2.2TgN,林地土壤碳氮蓄积量分别损失了55.9±17.0TgC和4.9±1.1TgN。同时根据中国6大行政区林地、耕地和草地之间的相互转换面积、土壤有机碳氮密度的变化率进行估算,表明土壤(30cm和100cm)有机碳氮蓄积量分别损失了53.7TgC、5.1TgN和99.5TgC、9.4TgN。由于中国不同地区土地利用变化的空间格局差异显著,从而导致东北地区土壤碳氮蓄积量变化较大,而华东地区变化较小。

中国云南轿子雪山自然保护区昆虫资源与生物多样性调查及齿颚卷象科Byctiscini族分类研究（鞘翅目，齿颚卷象科

本论文由两个单元组成，第一部分主要对中国云南轿子雪山自然保护区的昆虫资源分布、物种组成及生物多样性变化做了系统的研究探讨。第二部分是对中国齿颚卷叶象甲科(Rhynchitidae)的绿卷象族的分类系统及生物学进行了初步探讨。轿子雪山是距离昆明最近的自然保护区，并是少数著名的低纬度高海拔雪山之一。轿子雪山自然保护区的生态平衡影响着整个昆明地区的生态环境。但是对于此保护区的生物资源及多样性方面研究至今仍缺乏。作者于2006年8月至2007年8月对云南轿子雪山自然保护区昆虫资源进行了进一步摸底调查，并以地表甲虫为主要研究对象对其物种组成及生物多样性季节变化进行了连续跟踪调查。调查结果如下：1，共获得昆虫标本3725头，分别隶属于14目76科385种。经物种鉴定及对记录资料的进一步整理，得到轿子雪山自然保护区昆虫名录12目72科327种。2，通过对4种典型微环境样地(草地、灌丛、林地以及农田生态系统）的三次跟踪连续调查，共获得标本2451头，分别隶属于24科。其中步甲科(Carabidae)为优势类群，占总数的62.10%；隐翅虫科(Staphylinidae)其次，占12.77% 。可能由于海拔、气温等因素影响，该地区昆虫活动高峰期较短。3，通过对4种典型微生态环境中地表甲虫的生物多样性的比较，表明不同生境内甲虫的多样性指数存在动态变化，在不同生境片区内甲虫存在迁移活动，甲虫多在灌丛中越冬，并随季节及食物源迁移。卷叶象甲绿卷象族(Byctiscini)隶属于鞘翅目(Coleoptera)齿颚卷象科(Rhynchitidae)。以其独特的繁育后代方式——筑造多叶摇篮而闻名。其主要危害杨、苹果、梨、桦、盐肤木等许多重要经济树木。本文根据对文献资料的归纳整理和对现有昆虫标本的检视，对中国齿鄂卷象科(Rhynchitidae)的绿卷象族昆虫进行了较详细的分类系统学研究。共记述了绿卷象族卷叶象甲5属(Byctiscus、Aspidobyctiscus、Byctiscidius、Listrobyctiscus、Baikovius)43种，其中包括1中国新纪录种(Byctiscu regularis)。作者对本族昆虫的生物学及地理分布做了概括性描述，结果显示此族昆虫以东洋区为多数(48.84%)，古北区其次(34.88%)，东洋-古北共有种则占9.30%。此外，根据文献记述及标本检视，纠正一处物种记录错误，并针对部分物种编写了检索表。

Red-light-emitting iridium complexes with hole-transporting 9-arylcarbazole moieties for electrophosphorescence efficiency/color purity trade-off optimizationE

The synthesis, structures, photophysics, electrochemistry and electrophosphorescent properties of new red phosphorescent cyclometalated iridium(III) isoquinoline complexes, bearing 9-arylcarbazolyl chromophores, are reported. The functional properties of these red phosphors correlate well with the results of density functional theory calculations

Red-Light-Emitting Iridium Complexes with Hole-Transporting 9-Arylcarbazole Moieties for Electrophosphorescence Efficiency/ Color Purity Trade-off Optimization

The synthesis, structures, photophysics, electrochemistry and electrophosphorescent properties of new red phosphorescent cyclometalated iridium(III) isoquinoline complexes, bearing 9-arylcarbazolyl chromophores, are reported. The functional properties of these red phosphors correlate well with the results of density functional theory calculations. The highest occupied molecular orbital levels of these complexes are raised by the integration of a carbazole unit to the iridium isoquinoline core so that the hole-transporting ability is improved in the resulting complexes relative to those with I-phenylisoquinoline ligands. All of the complexes are highly thermally stable and emit an intense red light at room temperature with relatively short lifetimes that are beneficial for highly efficient organic light-emitting diodes (OLEDs).

Hole-transporting polymers containing carbazol-3,9-diyl and 1,4-phenylene fragments in the main chain

New carbazole-based polymers, which contain various content of electro-active fragments in the main chain connected via alkylene spacers, have been synthesized by Ni(0)-catalyzed Yamamoto-type aryl-aryl coupling reactions. These compounds represent amorphous materials of high thermal stability with glass-transition temperatures of 139-151 degrees C and thermal decomposition starting at temperatures above 400 degrees C. UV-vis absorption and photoluminescence emission spectra of the materials confirmed that the conjugated segments in the macromolecules are rather short.

Mo的掺杂对Ce_(0.8)Gd_(0.2)O_(1.9)烧结温度及电性能的影响

掺杂的CeO2基固体电解质因其在中低温条件下(500￣700℃)具有高氧离子电导率而成为有希望的IT-SOFCs(intermediate temperature-solid oxide fuel

Facile synthesis of 9,10-diarylphenanthrenes and poly(9,10-diarylphenanthrene)s

One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.

Phase transition behavior and molecular orientation of oligo(9,9 '-dioctylfluorene-alt-bithiophene)

A novel conjugated oligomer, oligo(9,9'-dioctylfluorene-alt-bithiophene) (OF8T2), was found to exhibit a unique phase transition between crystalline and liquid-crystalline states, and a liquid-crystalline glass was easily generated, offering better TFT device performance. In thin films, upon annealing the OF8T2 molecules oriented preferentially with their planes of conjugation being normal to the substrate, and both film thickness and annealing temperature were critical to the film morphology and the molecular orientation. When the OF8T2 film was deposited on a rubbed polyimide surface and annealed, the molecules aligned their long axes along the rubbing direction.

SiO2 nanoparticles as scatterers for random organic laser action in red fluorescent dye 4-(dicyanomethylene)-2-tert-butyl-6(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran doped polystyrene films

Random multimode lasers are achieved in 4-(dicyanomethylene)-2-tert-butyl-6(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB) doped polystyrene thin films by introducing silicon dioxide (SiO2) nanoparticles as scatterers. The devices emit a resonance multimode peak at a center wavelength of 640 nm with a mode linewidth less than 0.87 nm. The threshold excitation intensity is as low as 0.25 mJ pulse(-1) cm(-2). It can be seen that the microscopic random resonance cavities can be formed by multiple scattering of SiO2 nanoparticles.

Ti0.8Zr0.2V1.1Mn0.9-xNi0.4Crx固溶体贮氢合金结构和电化学性能

研究了Ti_(0.8)Zr_(0.2)V_(1.1)Mn_(0.9-x)Ni_(0.4)Cr_x(x为0～0.4)固溶体电极合金的结构和电化学性能。结果表明,Ti_(0.8)Zr_(0.2)V_(1.1)Mn_(0.9-x)Ni_(0.4)Cr_x系列合金是由具有体心立方(BCC)结构的V基固溶体相和C14Laves第二相组成的双相合金。

Electrolytic Deposition and Diffusion of Lithium onto Magnesium-9 Wt Pct Yttrium Bulk Alloy in Low-Temperature Molten Salt of Lithium Chloride and Potassium Chloride

The electrolytic deposition and diffusion of lithium onto bulk magnesium-9 wt pct yttrium alloy cathode in molten salt of 47 wt pct lithium chloride and 53 wt pct potassium chloride at 693 K were investigated. Results show that magnesium-yttrium-lithium ternary alloys are formed on the surface of the cathodes, and a penetration depth of 642 mu m is acquired after 2 hours of electrolysis at the cathodic current density of 0.06 A center dot cm(-2). The diffusion of lithium results in a great amount of precipitates in the lithium containing layer. These precipitates are the compound of Mg41Y5, which arrange along the grain boundaries and hinder the diffusion of lithium, and solid solution of yttrium in magnesium. The grain boundaries and the twins of the magnesium-9 wt pct yttrium substrate also have negative effects on the diffusion of lithium.

Hydrothermal Synthesis, Structures, and Luminescent Properties of Seven d(10) Metal-Organic Frameworks Based on 9,9-Dipropylfluorene-2,7-Dicarboxylic Acid (H(2)DFDA)

A series of Zn(II) and Cd(II) metal-organic frameworks, namely, [Zn(DFDA)] (1), [Cd(DFDA)(C2H5OH)] (2), [Zn-2(DFDA)(2)(L-1)(2)](2) center dot 3H(2)O (3), [Cd-2(DFDA)(2)(L-1)(2)] (4), [Zn(DFDA)(L-2)] (5), [Cd(DFDA)(L-2)(DMF)] (6), and [Zn(DFDA)(L-3)] (7) (where DFDA = 9,9-dipropylfluorene-2,7-dicarboxylate anion, L-1 = 1,4-bis(imidazol-1-ylmethyl)benzene, L-2 = 1,1'-(1,4-butanediyl) bis(imidazole), L-3 = 2,2'-bipyridine) have been synthesized under hydrothermal conditions and structurally characterized. Compound 1 exhibits a three-dimensional (3D framework containing one-dimensional (1D) Zn(II)-O clusters, with (4(8).6(7)) topology. Compound 2 contains hydrophobic channels built from infinite 1D Cd(II)-O clusters, with (4(8).5(4).6(3)) topology.

Synthesis and Characterizations of Poly(9,10-bisarylethynyl-2,6-anthrylene)s and Poly(9,10-bisalkynyl-2,6-anthrylene)

A poly(9,10-bisalkynyl-2,6-anthrylene) (PI) and five poly(9,10-bisarylethynyl-2,6-anthrylene)s(P2-P6) as soluble conjugated polymers have been synthesized and characterized. All polymers exhibit two-dimensional conjugated characteristics as indicated by absorption spectra comprising multi-bands in the range of 300-600 nm. Compared with P1, polymers P2-P5, which contain phenylethynyl substituents with the longer conjugation than alkynyl groups, exhibit a similar to 60 nm red shift of absorption edge. However, further increasing the conjugation length of the arylethynyl substituents (longer than phenylethynyl) has only a no effect on the conjugation of the polymer chains, while comparing the absorption spectra of P6 with those of P2-P5.