986 resultados para 366.225
Resumo:
The flexoelectric behaviour of a hypertwisted chiral nematic bimesogenic liquid crystal is presented. Through detailed electro-optic measurements, with particular emphasis on the switching properties, we demonstrate remarkably high optical axis tilt angles. The material studied possessed a room temperature nematic phase and aligned easily on cooling under the application of a moderate electric field. Switching times of the order of 500 μs and contrast ratios of 90:1 are readily achieved. The tilt angles, measured using the rotating analyser technique, were found to be practically temperature independent and linear with the applied field. Tilt angles of 22.5° were obtained with moderate applied fields of 9.4 V/μm whilst fields of 25 V/μm yielded tilt angles of 45°. We believe these are the highest tilt angles ever recorded for such fields. © 2001 OPA (Overseas Publishers Association) N.V. Published by license under the Gordon and Breach Science Publishers imprint, a member of the Taylor & Francis Group.
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The present study deals with the chemical, algal and faunal characteristics of the stream system at Horton Plains, the highest plains in Ceylon (altitude 2'225 m). The cultivation of seed potatoes and subsequent use of fertilizers have caused extensive silting and severe eutrophication of the stream systems. Since there are no indigenous fish, the trout Salmo gairdnerii has been introduced and it is the only fish found in these streams. The commonest fauna in the streams are crabs (Paratelphusa sp.), shrimps (Caridimr sp.), Simulium sp. and Chironomus sp. Their increase in number is probably correlated with increase in organic and detritus matter. The most important food items of the trout are the crabs living abundantly in the stream, insect larvae and terrestrial insects were also commonly found in the guts. Records of stocking and taking of trout in the Horton plains streams have shown that now less trout are taken relatively to the numbers stocked. This decrease may be possibly due to the eutrophication of the stream and also due to the possible use of pollutants in connection with the cultivation of seed potatoes.
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In order to develop materials that exhibit enhanced flexoelectric switching in the chiral nematic phase we have identified mesogenic units that display inherently strong flexoelectric coupling capabilities. Here we examine the oxycyanobiphenyl (OCB) moiety: homologues from the nOCB series exhibit significant electro-optic switching effects when doped with a highly chiral additive. Here we have examined lower dielectric anisotropy materials, since they allow the flexoelectric response to be extended to high field amplitudes. We show that dielectric coupling strength can be low in symmetric bimesogenic molecules. The flexoelectric response of such a molecular structure is tested by doping a homologue from the series CBOnOCB with a chiral additive: very significantly we find that the optic axis is rotated through 2φ=45° in <50 μs on reversing the polarity of the field (amplitude E=±6 V μm-1). Subsequently we have synthesized room temperature chiral nematic materials that exhibit 2φ≥90° at E≈10 V μm-1. © 2001 OPA (Overseas Publishers Association) N.V. Published by license under the Gordon and Breach Science Publishers imprint, a member of the Taylor & Francis Group.
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The photoisomerisation of a flexoelectric chiral nematic bimesogen system dyed with an azo dye has been investigated. The host material has a pitch and field dependent tilt angle that are temperature independent. Upon illumination by ultra violet, the azo dye molecules undergo a shape change from their trans to cis isomer. The effect of the shape change of the dye on the mixture is to decrease the I-N* transition temperatures, to increase the response times and to decrease the transmitted optical intensity. For the same reduced temperatures, the tilt angles, pitch and threshold voltages for the transition from focal conic to homeotropic textures are unchanged. The macroscopic parameters observed suggest that the orientational order parameter of the system is reduced by UV illumination. The cis isomers do not appear to separate from the host material or significantly change the flexoelectric coefficient. © 2001 OPA (Overseas Publishers Association) N.V. Published by license under the Gordon and Breach Science Publishers imprint, a member of the Taylor & Francis Group.
Resumo:
In a chiral nematic liquid crystal, the flexoelectric effect consists of a fast and linear coupling with an applied electric field. One difficulty to overcome is the unwinding of the helix that occurs at higher fields due to dielectric coupling. The use of bimesogens, which possess very low molecular dielectric anisotropy can improve flexoelectric characteristics. New bimesogen compounds have recently been synthesised that exhibit switching angles of 45° for applied fields of about 9 V.μm-1. In this paper, results from dielectric, electro-optic and dynamic light scattering measurements are reported for the new bimesogenic mixture. The dielectric anisotropy Δε changes sign with temperature and its values range between -0.2 and 0.3 for the temperature range studied. For Δε weakly positive, no electric field Freedericksz transition could be induced but Williams domains are observed instead. The large decrease in the bend elastic constant to viscosity coefficient ratio is attributed to a large increase in the bend viscosity coefficient. © 2001 OPA (Overseas Publishers Association) N.V. Published by license under the Gordon and Breach Science Publishers imprint, a member of the Taylor & Francis Group.
Resumo:
潮滩湿地处于海陆相互作用地带,是响应全球变化和人类活动较为敏感的生态系统 之一。潮滩湿地是海岸带一个非常重要的生态类型,作为陆地和海洋过渡区的重要组成 部分,承接来自陆地人类活动带来的大量含氮物质。潮滩湿地氮的生物循环特征不但影 响湿地系统自身的调节机制,而且其在环境介质中的特殊动力学过程也与一系列全球环 境问题息息相关。为了更深入的理解潮滩湿地氮的生物循环特征及其关键机制,论文以 黄河口滨岸潮滩翅碱蓬湿地为研究对象,通过野外样品采集、原位实验、微区试验,研 究了湿地土壤氮的时空分布与化学转化特征,探讨了湿地植物生物量与氮累积季节变化 特征以及湿地植物残体分解及分解过程氮动态特征,建立了湿地植物-土壤系统氮循环 分室模式,主要结论如下:(1)潮滩湿地土壤氮含量具有明显的水平变异和空间结构, TN、NO3 --N 和C/N 具有明显空间分布格局,其空间变异性均以向低潮滩延伸且受潮汐 涨落影响较大的方向最大;微地貌特征和潮汐微域物理扰动是导致空间异质性的两个重 要随机因素,水盐条件、土壤类型和潮汐物理扰动是三个重要结构因素;(2)潮滩湿地 土壤氮含量在不同时期的垂直分布均存在较高变异性,主要与有机质分布、潮汐影响、 水分条件以及陆源影响程度有关;潮滩湿地土壤的氮含量具有明显季节变化特征,主要 与水分状况及受潮汐影响的程度有关;(3)潮滩湿地土壤氮的净矿化/硝化速率均呈波动 变化,并受生物固持、反硝化、温度、水分、C/N 和pH 等因素影响;潮滩湿地0~15cm 土壤的净矿化量和净硝化量分别介于0.33~27.81kg·hm-2 和1.19~15.99kg·hm-2,高潮滩湿 地维持无机氮的能力明显强于中潮滩和低潮滩湿地;(4)两种表现型翅碱蓬的生物量 均具有明显季节变化和空间结构分形特征,二者的地上生物量具有自相似性,分别遵从 D=2.012 和2.366 的分形生长过程;(5)沉积强度显著影响翅碱蓬种子的出苗和幼苗存 活,适度沉积可刺激幼苗生长,重度沉积对幼苗生长则具有抑制作用;沉积可促使幼苗 被埋部分发育为根系,反映了其对潮滩较强沉积环境的特殊适应对策;(6)两种表现 型翅碱蓬根、茎和枯落物的TN 含量均呈递减变化,符合指数衰减模型,叶是二者重要 氮储库,分配比高达46.91±16.97%和55.21±9.79%;中潮滩植被的N/P 为9.87±3.47<14, 其生长受N 限制,低潮滩植被的N/P 为15.73±5.00<16,其生长同时受N、P 限制,但 更受P 限制;(7)潮滩湿地植物残体在水盐含量较高或沉积较强条件下的失重率和分解 速率一般较高,反之则较低;温度、水分、盐分和pH 是影响残体相对分解速率的重要 摘 要 II 因素;(8)当分解环境的养分状况不发生较大改变时,残体相对分解速率在很大程度上 取决于基质质量,当养分状况因潮汐养分交换、潮汐物理扰动、沉积物矿化等发生较大 改变时,残体相对分解速率在很大程度上取决于分解环境养分供给状况;(9)潮滩湿地 植物残体在不同水盐梯度和沉积强度下的氮含量、C/N 的变化模式整体较为一致,水盐 条件和沉积强度对残体氮绝对量的变化具有重要影响,C/N 对分解过程中氮养分的调控 作用更为重要;(
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Salinity, fresh water and sea level data from the Negombo Lagoon with respect to oceanic sea level and salinity data were considered. The open ocean spring tidal range was 0.57 m, whereas the neap tidal range was 0.10 m. In lagoon, the corresponding spring tidal range was 0.13 m and neap tidal range is 0.05 m. The lagoon tide was strongly choked because of the restricted inlet channel, through which only a limited water exchange could take place over a tidal cycle. Mean water exchange and the residence times for variable fresh water supplies were calculated. These calculations were based on fortnightly measurements of salinity and river discharges in 1993. During this year, salinity varied from 30-5‰ depending on the river inputs which were 20-225 m³ sˉ¹. Corresponding residence times varied from 11-2 days and the tide is dominated the exchange during low discharges of freshwater.
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Chicken type II procollagen (ccol2a1) has become as an important oral tolerance protein for effective treatment of rheumatoid arthritis. However, its molecular identity remains unclear. Here, we reported the full-length cDNA and nearly complete genomic DN
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We investigated the distribution of Y-chromosome haplotype using 19 Y-SNPs in Han Chinese populations from 22 provinces of China. Our data indicate distinctive patterns of Y chromosome between southern and northern Han Chinese populations. The southern po
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A mathematical model is developed to predict the energy consumption of a heavy vehicle. It includes the important factors of heavy-vehicle energy consumption, namely engine and drivetrain performances, losses due to accessories, aerodynamic drag, rolling resistance, road gradients, and driver behaviour. Novel low-cost testing methods were developed to determine engine and drivetrain characteristics. A simple drive cycle was used to validate the model. The model is able to predict the fuel use for a 371 tractor-semitrailer vehicle over a 4 km drive cycle within 1 per cent. This paper demonstrates that accurate and reliable vehicle benchmarking and model parameter measurement can be achieved without expensive equipment overheads, e.g. engine and chassis dynamometers.
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Turbomachinery flows are inherently unsteady. Until now during the design process, unsteadiness has been neglected, with resort merely to steady numerical simulations. Despite the assumption involved, the results obtained with steady simulations have been used with success. One of the questions arising in recent years is can unsteady simulations be used to improve the design of turbomachines? In this work the numerical simulation of a multi-stage axial compressor is carried out. Comparison of Reynolds averaged Navier-Stokes (RANS) and unsteady Reynolds averaged Navier-Stokes (URANS) calculation shows that the unsteadiness affects pressure losses and the prediction of stall limit. The unsteady inflow due to the wake passing mainly modifies the losses and whirl angle near the endwalls. The computational cost of the fully unsteady compared with a steady simulation is about four times in terms of mesh dimension and two orders of magnitude as number of iterations. A mixed RANS-URANS solution has been proposed to give the designer the possibility to simulate an unsteady stage embedded in a steady-state simulation. This method has been applied to the simulation of a four-stage axial compressor rig. The mixed RANS-URANS approach has been developed using sliding and mixing planes as interface conditions. The rotor-stator interaction has been captured physically while reducing the computational time and mesh size.
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This paper develops a path-following steering control strategy for an articulated heavy goods vehicle. The controller steers the axles of the semi-trailer so that its rear end follows the path of the fifth wheel coupling: for all paths and all speeds. This substantially improves low-speed manoeuvrability, off-tracking, and tyre scrubbing (wear). It also increases high-speed stability, reduces 'rearward amplification', and reduces the propensity to roll over in high-speed transient manoeuvres. The design of a novel experimental heavy goods vehicle with three independent hydraulically actuated steering axles is presented. The path-following controller is tested on the experimental vehicle, at low and high speeds. The field test results are compared with vehicle simulations and found to agree well. The benefits of this steering control approach are quantified. In a low-speed 'roundabout' manoeuvre, low-speed off-tracking was reduced by 73 per cent, from 4.25 m for a conventional vehicle to 1.15 m for the experimental vehicle; swept-path width was reduced by 2 m (28 per cent); peak scrubbing tyre forces were reduced by 83 per cent; and entry tail-swing was eliminated. In an 80 km/h lane-change manoeuvre, peak path error for the experimental vehicle was 33 per cent less than for the conventional vehicle, and rearward amplification of the trailer was 35 per cent less. Increasing the bandwidth of the steering actuators improved the high-speed dynamic performance of the vehicle, but at the expense of increased oil flow.