加速器高频D电路Q值的计算与测量

介绍了回旋加速器高频单D型盒D电路Q值的计算与测量方法。重点对Q值的理论计算进行推导,并对计算原理进行说明。然后对计算结果和测量结果进行比较。得出的计算和测量结果基本吻合。误差产生的主要原因是计算过程中的近似和短路片接触电阻的取值,其中短路片接触电阻是一个重要因素,在设计腔体时应引起足够的重视。

Injection by hydrostatic pressure in conjunction with electrokinetic force on a microfluidic chip

A simple method was developed for injecting a sample on a cross-form microfluidic chip by means of hydrostatic pressure combined with electrokinetic forces. The hydrostatic pressure was generated simply by adjusting the liquid level in different reservoirs without any additional driven equipment such as a pump. Two dispensing strategies using a floating injection and a gated injection, coupled with hydrostatic pressure loading, were tested. The fluorescence observation verified the feasibility of hydrostatic pressure loading in the separation of a mixture of fluorescein sodium salt and fluorescein isothiocyanate. This method was proved to be effective in leading cells to a separation channel for single cell analysis.

额济纳天然绿洲景观演化驱动因子分析

额济纳天然绿洲位于我国西北干旱内陆河流域黑河流域下游 ,近年来 ,随着黑河中、上游地区下泄地表径流量的减少 ,额济纳天然绿洲景观退化严重。基于研究区近十几年来的景观演化总体特征 ,分别从气候因素、水文因素、人类干扰因素等几个主要的景观变化驱动因子入手 ,探讨其演化机制、揭示其演化规律。研究结果表明 :黑河流域中、上游下泄地表径流量的锐减而导致研究区地下水水位下降、地下水矿化度升高以及水质恶化是额济纳天然绿洲景观发生退化的根本原因 ,绿洲人类活动强度的增加、绿洲关键区域的超载和过牧以及蒸发度指数的升高、湿润系数的下降均加剧了研究区景观退化的程度。

塔叶苔属(SchiffneriaSteph.)(Hepaticae)的研究

塔叶苔属(Schiffneria Steph.)建立于1894年。作者在研究中国标本时,发现一新种———Schiffneria yunnanensis C.Gao& W.Li sp.nov.。塔叶苔属的配子体为叶状体,生殖枝具茎叶返祖现象,应置于叶苔亚纲的叶状体无组织分化类群———带叶苔目(Pallaviciniales)之中。

A versatile color tuning strategy for iridium(III) and platinum(II) electrophosphors by shifting the charge-transfer states with an electron-deficient core

By fusing an electron-deficient ring system with the phenyl ring of a 2-phenylpyridine (ppy)-type ligand, a new and synthetically versatile strategy for the phosphorescence color tuning of cyclometalated iridium(III) and platinum(II) metallophosphors has been established. Two robust red electrophosphors with enhanced electron-injection/electron-transporting features were prepared by using an electron-trapping fluoren-9-one chromophore in the ligand design. The thermal, photophysical, redox and electrophosphorescent properties of these complexes are reported. These exciting results can be attributed to a switch of the metal-to-ligand charge-transfer (MLCT) character of the transition from the pyridyl groups in the traditional Ir-III or Pt-II ppy-type complexes to the electron-deficient ring core, and the spectral assignments corroborate well with the electrochemical data as well as the timedependent density functional theory (TD-DFT) calculations. The electron-withdrawing character of the fused ring results in much more stable MLCT states, inducing a substantial red-shift of the triplet emission energy from yellow to red for the Ir-III complex and even green to red for the PtII counterpart.

THE SYNTHESES CHARACTERIZATION AND CRYSTAL-STRUCTURE OF RARE-EARTH COMPLEXES WITH L-PROLIN

The complexes of Ln(L-Pro)s(H2O)2(ClO4)3(Ln = Pr, Nd and Er. L-Pro = L-Proline) were synthesized and characterized by elemental analysis, IR. spectra and thermal analysis. The singal crystal Pr2(L-Pro)6(H2O)4(ClO4)6 Was also obtained. The crystal belongs to monoclinic, P2(1), a = 0.9879 (3) nm, b = 2.1883 (4) nm, c = 1.3393 (2)nm, beta = 91.23(2)-degrees, V = 2.895(1) nm3, Z = 2. R = 0.035 for 5032 observed reflections. The coordination polyhedron of Pr(III) ion comprises six oxygen atoms from L-Pro molecules and two water molecules. Each L-Pro molecule coordinates to two Pr(III) ions through its carboxyl group which serves as a bridging bidentate ligand to form onedimensional chain structure.