Chemical speciation and mobilization of copper and zinc in naturally contaminated mine soils with citric and tartaric acids

A one-step extraction procedure and a leaching column experiment were performed to assess the effects of citric and tartaric acids on Cu and Zn mobilization in naturally contaminated mine soils to facilitate assisted phytoextraction. A speciation modeling of the soil solution and the metal fractionation of soils were performed to elucidate the chemical processes that affected metal desorption by organic acids. Different extracting solutions were prepared, all of which contained 0.01 M KNO3 and different concentrations of organic acids: control without organic acids, 0.5 mM citric, 0.5 mM tartaric, 10 mM citric, 10 mM tartaric, and 5 mM citric +5 mM tartaric. The results of the extraction procedure showed that higher concentrations of organic acids increased metal desorption, and citric acid was more effective at facilitating metal desorption than tartaric acid. Metal desorption was mainly influenced by the decreasing pH and the dissolution of Fe and Mn oxides, not by the formation of soluble metal–organic complexes as was predicted by the speciation modeling. The results of the column study reported that low concentrations of organic acids did not significantly increase metal mobilization and that higher doses were also not able to mobilize Zn. However, 5–10 mM citric acid significantly promoted Cu mobilization (from 1 mg kg−1 in the control to 42 mg kg−1 with 10 mM citric acid) and reduced the exchangeable (from 21 to 3 mg kg−1) and the Fe and Mn oxides (from 443 to 277 mg kg−1) fractions. Citric acid could efficiently facilitate assisted phytoextraction techniques.

Emission factors from road dust resuspension in a Mediterranean freeway

Particulate matter emissions from paved roads are currently one of the main challenges for a sustainable transport in Europe. Emissions are scarcely estimated due to the lack of knowledge about the resuspension process severely hampering a reliable simulation of PM and heavy metals concentrations in large cities and evaluation of population exposure. In this study the Emission Factors from road dust resuspension on a Mediterranean freeway were estimated per single vehicle category and PM component (OC, EC, mineral dust and metals) by means of the deployment of vertical profiles of passive samplers and terminal concentration estimate. The estimated PM10 emission factors varied from 12 to 47 mg VKT?1 (VKT: Vehicle Kilometer Traveled) with an average value of 22.7 ? 14.2 mg VKT?1. Emission Factors for heavy and light duty vehicles, passenger cars and motorbikes were estimated, based on average fleet composition and EPA ratios, in 187e733 mg VKT?1, 33e131 VKT?1, 9.4e36.9 VKT?1 and 0.8e3.3 VKT?1, respectively. These range of values are lower than previous estimates in Mediterranean urban roads, probably due to the lower dust reservoir on freeways. PM emitted material was dominated by mineral dust (9e10 mg VKT?1), but also OC and EC were found to be major components and approximately 14 e25% and 2e9% of average PM exhaust emissions from diesel passenger cars on highways respectively.

Detección óptica de harinosidad en manzana mediante una nueva técnica láser.

Mealiness, a textural disorder that produces quality loss, combines softness and absence of juiciness. The only one (destructive) test to measure it, combines information from a mechanical test on fruit probes to classify the samples according to instrumental mealiness. Time-domain laser reflectance spectroscopy (TDRS) is able to assess simultaneously and independently the absorption of the light inside the irradiated body (µa coefficient) and the scattering of the photons across the tissues (µS, transport scattering coeff.) measured at each wavelength. Using VIS&NIR lasers as light sources, TDRS was applied to Golden Delicious and Cox apples (n=90), conforming batches of untreated samples and storage-treated (20°C&95%RH) to induce mealiness development. The collected database was clustered into different groups according to their instrumental mealiness. Optical variables were used to build discriminant functions, achieving classification scores 75-89% of correctly identified mealy apples.

Dopamine receptor 4 promoter polymorphism modulates memory and neuronal responses to salience

Animal models and human functional imaging data implicate the dopamine system in mediating enhanced encoding of novel stimuli into human memory. A separate line of investigation suggests an association between a functional polymorphism in the promoter region for the human dopamine 4 receptor gene (DRD4) and sensitivity to novelty. We demonstrate, in two independent samples, that the -521Cmayor queT DRD4 promoter polymorphism determines the magnitude of human memory enhancement for contextually novel, perceptual oddball stimuli in an allele dose-dependent manner. The genotype-dependent memory enhancement conferred by the C allele is associated with increased neuronal responses during successful encoding of perceptual oddballs in the ventral striatum, an effect which is again allele dose-dependent. Furthermore, with repeated presentations of oddball stimuli, this memory advantage decreases, an effect mirrored by adaptation of activation in the hippocampus and substantia nigra/ventral tegmental area in C carriers only. Thus, a dynamic modulation of human memory enhancement for perceptually salient stimuli is associated with activation of a dopaminergic-hippocampal system, which is critically dependent on a functional polymorphism in the DRD4 promoter region.

Valor documental de los herbarios históricos: aportación de la exsiccata Flora Forestal Española al conocimiento de las cubiertas forestales de las provincias de Huelva y Sevilla (España)

Los herbarios, además de información botánica, pueden contener datos históricos de valor científico para el estudio de los montes y de su historia, como los recogidos en las colecciones de material que fue recolectado para la descripción y cartografía de las cubiertas forestales españolas. En este trabajo se sintetizan los datos obtenidos de la exsiccata Flora Forestal Española creada por investigadores del Instituto Forestal de Investigaciones y Experiencias- IFIE que, junto con información obtenida de documentos inéditos, evidencian la vinculación de esta colección a la realización de los mapas forestales y estudios de flora y vegetación provinciales; en particular a los de las provincias de Huelva y Sevilla, que quedaron inéditos, permitiendo precisar mejor su datación y aportando datos botánicos relevantes e información sobre el paisaje forestal anterior a las grandes repoblaciones con pinos y eucaliptos realizadas en el suroeste peninsular.