Effective atomic orbitals for fuzzy atoms

The method of extracting effective atomic orbitals and effective minimal basis sets from molecular wave function characterizing the state of an atom in a molecule is developed in the framework of the "fuzzy" atoms. In all cases studied, there were as many effective orbitals that have considerable occupation numbers as orbitals in the classical minimal basis. That is considered to be of high conceptual importance

Las cuevas prehistóricas de Serinyà (Pla de l’Estany, Girona)

The Reclau Caves, which form part of the Serinyà Prehistoric Caves Park (Pla de l’Estany, Girona), are shelters formed by waterfall travertines which have been in turn affected by karstification phenomena. Though relatively small, these cavities were big enough to held human occupation. Its evolution has seen the falling of blocks and infilling of terrigenous materials. Thus, the caves were completely filled and had most of their original roofs fallen. The first excavations of these caves were made in the mid 1940s and they continued, albeit with some interruptions, until present times. The caves were occupied by humans since the late Middle Pleistocene until the Holocene. Hence, the main occupation periods can be attributed to the Middle Paleolithic and Upper Paleolithic cultures. Given the existence of these sites, the project of an archeological park was started and its first phase opened to the public in the summer of 1997. The creation of this park has led to the protection of the three main caves of the site (Arbreda, Mollet and Reclau Viver Caves). The caves have also been adapted and singposted to open them to the public. Other facilities of the park include a reception building and an activity area. The caves can be visited in guided tours which include the projection of a film, the visit to the permanent exhibition room, the three main caves and the participation in some prehistoric-related activities

The re-urbanization of the city center of Manaus , Brazil - Facing the challenges of informal settlements

Illegal occupation of urban land in Brazil is a widespread phenomenon. Slum dwellers are excluded from the attributes of urban citizenship although they provide the labor force required by low productivity urban services needed by cities. Illegal settlements generate multiple problems for the rest of the city . Its solution is of key relevance to the city in general but also provide an opportunity for the social and economic advancement of slum dwellers. The programs required to attain these results are complex and difficult to implement underscoring the challenges countries will face to attain the Millennium Development Goals of reducing the population living in slums.

Formação continuada: seus impactos na prática docente: um olhar sobre o programa pró-letramento

RESUMO: A preocupação central desta pesquisa foi compreendermos qual o impacto da formação continuada Pró-Letramento na prática pedagógica do professor a partir das necessidades e desafios do cotidiano escolar. Buscamos conhecer o conceito que os sujeitos da pesquisa têm sobre formação continuada, abordando a mesma como elemento da prática docente, comparamos o cotidiano de sala de aula de professores que passaram pela formação Pró-Letramento com os que não tiveram acesso a essa formação. Com respeito à formação continuada a percebemos como um processo dinâmico, reflexivo, que combina uma variedade de possibilidades e modalidades de aprendizagens, em que o professor vai adequando a sua formação às exigências sociais, culturais, educacionais. A formação continuada se dá, por meio da reflexão sobre a própria prática profissional no processo de ação-reflexão-ação, adquirindo significado na medida em que desenvolve e promove os diversos saberes docentes. A pesquisa foi conduzida com 90 professores do Ensino Fundamental – Anos Iniciais -, com oito coordenadoras que acompanham pedagogicamente os professores sujeitos dessa pesquisa e a observação em sala de aula. Procedeu-se à aplicação de um questionário validado e adaptado aos professores e uma entrevista aos coordenadores. A análise dos dados quantitativos foi realizada por meio do programa SPSS; enquanto a análise dos dados qualitativos foi orientada pela análise de discurso. A pesquisa aponta para algumas conclusões no que se refere a importância da Formação Continuada Pró-Letramento, tendo em vista a mesma possibilitar mudanças na prática pedagógica e colaborara para formação de um professor reflexivo, ao mesmo tempo que abre espaço para novos questionamentos e novos estudos.ABSTRACT: The central concern of this research was to understand the impact of the continuing education pro-literacy teaching practice from the teacher‘s needs and challenges of every day school life. We tried to know the concept that the subjects have on continuing education, addressing it as part of teaching practice, we compared the daily classroom teachers who have gone through training with Pro-Literacy did not access to such training. With respect to continuing education perceive it as a dynamic, reflective, which combines a variety of possibilities and modalities oF learning, the teacher will tailoring the training requirements to social, cultural, educational. The continuing education takes place, through reflection on own practice in the process of action-reflection-action, acquiring significance in that it develops and promotes the various teacher‘s knowledge. The research was conducted with 90 elementary school teacher‘s – Early Years – with eight coordinators accompanying teacher‘s pedagogically subject of research and observation in the classroom. Proceeded to the application of a validated questionnaire and adapted to an interview with the teachers and coordinators. The quantitative data analysis was performed using SPSS, while the analysis of qualitative data was guided by discourse analysis. The research points to some conclusions regarding the importance of Continuing Education Pro- Literacy in order to enable the same changes in teaching practice and collaborated to form a reflective teacher at the same time it makes room for new questions and new studies.

O Lugar como Simbiose : Centro Histórico de Torres Vedras

A presente dissertação tem como principal objectivo a análise morfológica do centro histórico de Torres Vedras. Após um rigoroso estudo do seu plano estratégico de reabilitação urbana, verifica-se a ausência de um documento complementar que permita conhecer sua identidade. A informação existente é bastante planimétrica, pouco esclarecedora da qualidade espacial do Lugar. Devido à escassa cartografia existente, julgou-se essencial desenvolver a reconstituição urbanística da cidade, permitindo dissipar algumas memórias artificiais, fomentadas pelo ‘neo-romantismo’ do Estado Novo, mas que ainda hoje se fazem sentir na memória colectiva dos torrienses. O estudo da génese fundacional do Lugar e do seu enquadramento histórico é fundamental para o entendimento do valor patrimonial enquanto conceito subjacente às políticas de reabilitação dos centros históricos. O estudo da evolução urbana de Torrres Vedras desde a vila medieval, até à cidade do séc. XXI, dando a conhecer os pólos de atracção do crescimento periurbano, e a sua relação com o centro histórico, permitiu um conhecimento mais aprofundado sobre os elementos essenciais que caracterizam a sua Identidade. Verifica-se que a matriz urbana fundacional, ainda hoje perceptível, provém da ocupação romana, materializada pelos dois principais eixos reguladores: cardus e decumanus. A leitura do passado, alicerçada sobre a historiografia e arqueologia, pretende apenas mostrar que os núcleos urbanos antigos foram sempre elementos dinâmicos, capazes de se adaptarem às circunstâncias de cada época, garantindo a sua permanência e importância até ao início do séc. XX. A abordagem feita ao centro histórico pretende demonstrar a sua potencialidade para se tornar num elemento activo da cidade de Torres Vedras, capaz de se adaptar às necessidades da sociedade do séc. XXI, sem perder a sua identidade.

Recuentos de dos ciudades: Guayaquil en 1899 y Quito en 1906 (Estudios)

Estudio preliminar del desarrollo demográfico de Guayaquil y Quito a fines el siglo XIX e inicios del siglo XX, basado en los censos proto-estadísticos realizados en ambas ciudades en 1899 y 1906, respectivamente. Se estudian las condiciones en las que se realizaron ambos censos, la información cuantitativa que ofrecen y los vacíos que la historia demográfica aún mantiene. El artículo enfatiza en una perspectiva de análisis comparativo entre las dos principales ciudades del Ecuador. Se examina la composición poblacional en términos de grupos de edad, sexo, ocupación, matrimonio, natalidad, mortalidad y educación.

Ancient lakes of the Sahara

As a result of climate change over the past 5000 years the Sahara changed from savannah to a desert landscape. The beds of ancient lakes are home to snail shells and the petrified roots of trees and shrubs. Examples of human occupation can also be seen in the form of fireplaces and discarded tools. Examination of the geological history of these sites can give a clearer picture of how the climate changed and how humans coped with these changes.

The Palaeolithic Rivers of Southwest Britain

The Palaeolithic Rivers of Southwest Britain (PRoSWeB) project synthesises the archaeological evidence for the Lower and Middle Palaeolithic occupation of south-west Britain (c. 500,000 - 40,000 BP), with a principal focus upon the archaeological and geological potential of the region's Middle Pleistocene fluvial environments. South-west Britain was defined as the region west of the headwaters of the Rivers Frome and Piddle and south-west of the River Avon.

Terrestrial implications for the maritime geoarchaeological resource: A view from the Lower Palaeolithic

Stone tools and faunal remains have been recovered from the English Channel and the North Sea through trawling, dredging for aggregates, channel clearance, and coring. These finds highlight the potential for a maritime Lower Palaeolithic archaeological resource. It is proposed here that any Lower Palaeolithic artefacts, faunal remains, and sediments deposited in the maritime zone during dry, low-stand phases were once (and may still be) contextually similar to their counterparts in the terrestrial Lower Palaeolithic records of north-western Europe. Given these similarities, can interpretive models and analytical frameworks developed for terrestrial archaeology be profitably applied to an assessment of the potential value of any maritime resource? The terrestrial geoarchaeological resource for the Lower Palaeolithic is dominated by artefacts and ecofacts that have been fluvially reworked. The spatio-temporal resolution of these data varies from entire river valleys and marine isotope stages to river channel gravel bar surfaces and decadal timescales, thus supporting a variety of questions and approaches. However, the structure of the terrestrial resource also highlights two fundamental limitations in current maritime knowledge that can restrict the application of terrestrial approaches to any potential maritime resource: (i) how have the repetitive transgressions and regressions of the Middle and Late Pleistocene modified the terrace landforms and sediments associated with the river systems of the English Channel and southern North Sea basins?; and (ii) do the surviving submerged terrace landforms and fluvial sedimentary deposits support robust geochronological models, as is the case with the classical terrestrial terrace sequences? This paper highlights potential approaches to these questions, and concludes that the fluvial palaeogeography, Pleistocene fossils, and potential Lower Palaeolithic artefacts of the maritime geoarchaeological resource can be profitably investigated in future as derived, low-resolution data sets, facilitating questions of colonisation, occupation, demography, and material culture.

A record of Holocene climate change from lake geochemical analyses in southeastern Arabia

Lacustrine sediments from southeastern Arabia reveal variations in lake level corresponding to changes in the strength and duration of Indian Ocean Monsoon (IOM) summer rainfall and winter cyclonic rainfall. The late glacial/Holocene transition of the region was characterised by the development of mega-linear dunes. These dunes became stabilised and vegetated during the early Holocene and interdunal lakes formed in response to the incursion of the IOM at approximately 8500 cal yr BP with the development of C3 dominated savanna grasslands. The IOM weakened ca. 6000 cal yr BP with the onset of regional aridity, aeolian sedimentation and dune reactivation and accretion. Despite this reduction in precipitation, the take was maintained by winter dominated rainfall. There was a shift to drier adapted C4 grasslands across the dune field. Lake sediment geochemical analyses record precipitation minima at 8200, 5000 and 4200 cal yr BP that coincide with Bond events in the North Atlantic. A number of these events correspond with changes in cultural periods, suggesting that climate was a key mechanism affecting human occupation and exploitation of this region. (c) 2006 University of Washington. All rights reserved.

Ancient lakes of the Sahara

As a result of climate change over the past 5000 years the Sahara changed from savannah to a desert landscape. The beds of ancient lakes are home to snail shells and the petrified roots of trees and shrubs. Examples of human occupation can also be seen in the form of fireplaces and discarded tools. Examination of the geological history of these sites can give a clearer picture of how the climate changed and how humans coped with these changes.

Mediating between hearer's and speaker's views in the generation of adaptive explanations

In this article, we examine the case of a system that cooperates with a “direct” user to plan an activity that some “indirect” user, not interacting with the system, should perform. The specific application we consider is the prescription of drugs. In this case, the direct user is the prescriber and the indirect user is the person who is responsible for performing the therapy. Relevant characteristics of the two users are represented in two user models. Explanation strategies are represented in planning operators whose preconditions encode the cognitive state of the indirect user; this allows tailoring the message to the indirect user's characteristics. Expansion of optional subgoals and selection among candidate operators is made by applying decision criteria represented as metarules, that negotiate between direct and indirect users' views also taking into account the context where explanation is provided. After the message has been generated, the direct user may ask to add or remove some items, or change the message style. The system defends the indirect user's needs as far as possible by mentioning the rationale behind the generated message. If needed, the plan is repaired and the direct user model is revised accordingly, so that the system learns progressively to generate messages suited to the preferences of people with whom it interacts.

UK commercial property lease structures: Landlord and tenant mismatch

UK commercial property lease structures have come under considerable scrutiny during the past decade since the property crash of the early 1990s. In particular, tenants complained that the system was unfair and that it has blocked business change. Government is committed, through its 2001 election manifesto, to promote flexibility and choice in the commercial property lettings market and a new voluntary Commercial Leases Code of Practice was launched in April 2002. This paper investigates whether occupiers are being offered the leases they require or whether there is a mismatch between occupier requirements and actual leases in the market. It draws together the substantial data now available on the actual terms of leases in the UK and surveys of corporate occupiers' attitude to their occupation requirements. Although the data indicated that UK leases have become shorter and more diverse since 1990, this is still not sufficient to meet the current requirements of many corporate occupiers. It is clear that the inability to manage entry and exit strategies is a major concern to occupiers. Lease length is the primary concern of tenants and a number of respondents comment on the mismatch between lease length in the UK and business planning horizons. The right to break and other problems with alienation clauses also pose serious difficulties for occupiers, thus reinforcing the mismatch. Other issues include repairing and insuring clauses and the type of review clause. There are differences in opinion between types of occupier. In particular, international corporate occupiers are significantly more concerned about the length of lease and the incidence of break clauses than national occupiers and private-sector tenants are significantly more concerned about leasing in general than public-sector occupiers. Proposed solutions by tenants are predictable and include shorter leases, more frequent breaks and relaxation of restrictions concerning alienation and other clauses. A significant number specify that they would pay more for shorter leases and other improved terms. Short leases would make many of the other terms more acceptable and this is why they are the main concern of corporate occupiers. Overall, the evidence suggests that there continues to be a gap between occupiers' lease requirements and those currently offered by the market. There are underlying structural factors that act as an inertial force on landlords and inhibit the changes which occupiers appear to want. Nevertheless, the findings raise future research questions concerning whether UK lease structures are a constraining factor on UK competitiveness.

The Royal Army Education Corps in the Gulf Conflict of 1990-91

The official history of the Royal Army Education Corps' involvement in Operation 'Desert Storm', the liberation of Kuwait from Iraqi occupation in 1991, their roles including prisoner of war interrogation, psychological operations, IT services and acting as interpreters for senior officers.

Forces information and media services in Operation Granby 1990-91

The paper looks at the setting up of media services for British Army forces engaged in Operation Granby, the British participation in Operation Desert Storm, the liberation of Kuwait from Iraqi occupation in 1991. In particular, the piece focuses on the creation of a force newspaper and radio station.There is far more involved in the organisation of modern war than simply battles themselves One aspect is the importance of creating and maintaining morale, which can be achieved in a number of ways, especially by keeping troops informed of their progress, purpose and mission as operations unfold. This was specifically recognised by commanders in the Gulf War, who ensured the smooth transmission of information by the provision of media services for forces personnel throughout the War. Here S J Anglim concentrates on the difficulties inherent in setting up and running the Gulf Forces newspaper, The Sandy Times, a Radio service and producing video reviews, all of which played their part in ensunng high morale. He concludes that there are lessons to be learnt and implemented for the success of any future conflicts.