967 resultados para Electrolytic manganese dioxides


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At head of title: Imperial mineral resources bureau.

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"This report ... is the work of Mr. J.A. Jones."--Pref.

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Text reproduced from type-written copy on one side of leaf only.

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Translation of Neue Verfahrungsweisen zur Prüfung der Pottasche und Soda, der Aschen, der Säuren, insbesondere des Essigs so wie Braunsteins auf ihren wahren Gehalt und Handelswerth.

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Mode of access: Internet.

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Chemical composition of manganese nodules and crust collected from the Hakurei Maru Cruise GH74-5, September-October, 1974, in the Eastern Central Pacific Basin by the Geological Survey of Japan according to: Analyses and sample manganese deposits data from Cruise GH74-5 (private communication) (unpublished), Scripps Institution of Oceanography. http://www.ngdc.noaa.gov/mgg_mmbib/showref.jsp?mmbib=MIZUAA7702.

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Manganese nodules occurring within marine sediments of presumably Upper Miocene-Lower Pliocene age from cores obtained by the Argentine oceanographic vessel ARA Islas Orcadas in 1977 on the Malvinas (Falkland) Plateau and neighbouring Scotia Sea were studied with the aim of comparing them with other fossil nodules found on the mainland of Argentina that were also ascribed to the marine environment. After optical mineralogical, chemical, X-ray and trace element analysis, the studied "nodules" proved to be actually wacke clasts cemented by manganese oxides with a high Fe/Mn ratio corresponding to a continental environment. The studied "nodules" thus differ from the Argentine mainland nodules and are supposed to have been transported from continental environments and then deposited in the marine realms. The wacke clasts became then nuclei for the deposition of the marine manganese oxides of the coatings. The proportion of trace elements, which is high, suggests the growth of the nodules in the marine environment.

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The cores and dredges described in this report were taken on the GH74-5 Expedition in September-October, 1974 by the Geological Survey of Japan from the R/V Hakurei Maru. A total of 36 cores, dredges and submarine camera sites have been visited. The survey conducted an investigation of the manganese deposits in the Eastern Pacific Basin and the East of the Okinawa islands

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Liquidus isotherms and phase equilibria have been determined experimentally for a pseudo-ternary section of the form MnO-(CaO+MgO)-(SiO2+Al2O3) with a fixed Al-2,O-3,/SiO2, weight ratio of 0.17 and MgO/CaO weight ratio of 0.17 for temperatures in the range 1473-1673 K. The primary phase fields present for the section investigated include manganosite (Mn,Mg,Ca)O; dicalcium silicate alpha-2(Ca,Mg,Mn)O (.) SiO2; merwinite 3CaO(.) ((Mg,Mn)O.2SiO(2); wollastonite [(Ca,Mg,Mn)(OSiO2)-Si-.]; ;tephroite [2(Mn,Mg)O.SiO2]; rhodonite [(Mn,Mg)O. diopside [(CaO,MgO,MnO,Al2O3)(SiO2)-Si-.]; tridymite (SiO2), SiO2] and melilite [2CaO (.) (MgO,MnO,Al2O3).2(SiO2,Al2O3)]. The liquidus temperatures relevant to ferro-manganese and silico-manganese smelting slags have been determined. The liquiclus temperature is shown to be principally dependent on the modified basicity weight ratio (CaO+Mgo)/(SiO2+Al2O3) at low MnO concentrations, and dependent on the mole ratio (CaO+ MgO+MnO)/(SiO2+Al2O3) at higher MnO concentrations.

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The effect of manganese on gain refinement of a commercial AZ31 alloy has been investigated using an Al-60%Mn master alloy splatter as an alloying additive at 730 degrees C in aluminium titanite crucibles. It is shown that grain refinement by manganese is readily achievable in AZ31. Electron microprobe analyses reveal that prior to the addition of extra manganese the majority of the intermetallic particles found in AZ31 are of the AL(8)Mn(5) type. However, after the addition of extra manganese in the range from 0.1% to 0.8%, the predominant group of intermetallic particles changes to the metastable AlMn type. This leads to a hypothesis that the metastable AlMn intermetallic particles are more effective than Al8Mn5 as nucleation sites for magnesium grains. The hypothesis is supported by the observation that a long period of holding at 730 degrees C leads to an increase in grain size, due probably to the transformation of the metastable AlMn to the stable Al8Mn5. The hypothesis has also been used to understand the mechanism of grain refinement by superheating.

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Manganese is a grain refiner for high purity Mg-3%Al, Mg-6%Al, Mg-9%Al, and commercial AZ31 (Mg-3%Al-1%Zn) alloys when introduced in the form of an Al-60%Mn master alloy splatter but the use of pure Mn flakes and ALTAB (TM) Mn75 tablets shows no grain refinement. Long time holding of the melt at 730 degrees C leads to an increase in grain size. The mechanism is attributed to the presence of all epsilon-AlMn phase (hexagonal close-packed) in the master alloy splatter. (c) 2006 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.