Aplicación de la técnica de espectrometría de fluorescencia de rayos-X en el estudio de la dispersión de metales en áreas mineras

One critical factor for success in characterizing metals polluting mining environments so as to be able to eliminate them and subsequently recover these areas depends upon a speedy and correct response in the analysis of samples. Rapid, simultaneous, multi-element analysis can be undertaken using X-ray fluorescence spectrometry, a versatile, non-destructive analytical technique commonly employed to identify both major and minor elements in samples related to environmental studies. An additional advantage of this technique is the possibility of conducting the analysis directly on solid samples, which is extremely convenient when dealing with environmental samples that are difficult to dissolve, such as soils, sediments and mining wastes. Moreover, in recent years the development of spectrometers equipped with digital-signal processors combined with enlarged X-ray production, using better designs for excitation-detection, has contributed to an improvement in instrumental sensitivity, thus allowing us to detect important polluting elements such as Cd and Pb at trace levels. In this paper the authors describe, on the basis of their own experience, some interesting applications of XRF spectrometry for the analysis of several types of environmental samples related to the study of the dispersion of metals within mining environments: (A) analysis of mining wastes, soils and sediments; (B) analysis of samples of vegetation used as bioindicators or related to phytoremediation studies; and (C) analysis of water samples related to mining operations

Innovar, renovar, avaluar

[eng] The new educational context in which we are involved and the facilities of the TIC (Communication Information Technologies) have led to the necessary modification of didactic approach that during years has been used for Pharmaceutical Technology teaching. However, changes/updating and innovation require a simultaneous reflection in order to avoid excessive dispersion of the approach and to channel adequately the pedagogic and didactic effort. On the other hand, it is necessary to evaluate the above initiatives to determinate if these one are on the right track. The Pharmaceutical Technology Teaching Innovation Group of the University of Barcelona has been formed and consolidated in this point of view. In this work, a review of studies carried on by the group, in the exposed purposes, from the beginning of their activities is presented. [spa] El nuevo contexto docente en el que estamos inmersos así como las posibilidades de las TIC (Tecnologías de la Información y de la Comunicación) han conllevado la necesaria modificación de los planteamientos didácticos que durante años han servido de base para las enseñanzas de la Tecnología Farmacéutica. Sin embargo, la renovación/actualización e innovación precisan de una simultánea reflexión a fin de evitar una excesiva dispersión del enfoque y para encauzar adecuadamente el esfuerzo pedagógico y didáctico. Por otra parte, es necesario evaluar dichas iniciativas para determinar si están bien encaminadas. El Grupo de Innovación Docente de Tecnología Farmacéutica de la Universidad de Barcelona se ha creado y consolidado desde esta óptica. En este trabajo se presentan un conjunto de estudios que el grupo ha llevado a cabo, con los fines expuestos, desde el comienzo de sus actividades.

Registro arqueobotánico de Cataluña occidental durante el II y I milenio a.n.e.

Se presenta una síntesis de los resultados obtenidos en los estudios de semillas y frutos realizados durante los últimos años en la Cataluña Occidental (especialmente en el llamado Llano Occidental Catalán) en yacimientos del II y I milenio a.n.e. Entre las plantas cultivadas destacan claramente los cereales, sobre todo la cebada vestida (Hordeum vulgare) y el trigo común/duro (Triticum aestivum/durum), con escasa presencia de leguminosas, siendo las más representadas la lenteja (Lens culinaris) y el guisante (Pisum sativum). Nuevos cultivos como los mijos (Panicum miliaceum y Setaria italica) o el lino (Linum usitatissimum) se detectan ya desde mediados del II milenio, mientras que otros como la avena (Avena sativa) se introducen en época ibérica. Se han recuperado también testimonios de recolección, como las bellotas (Quercus sp.) o la uva silvestre (Vitis vinifera ssp. sylvestris), así como de la vegetación arvense, principalmente el raygrás (Lolium sp.).

Las semillas y los frutos arqueológicos: aportación a la reconstrucción paleoambiental

La contribución de los análisis de semillas y frutos a la reconstrucción paleoambiental es más reducida que la de otras disciplinas paleobotánicas, aunque su aportación es fundamental ya que permite identificar a nivel de especie numerosas plantas. No obstante, los problemas en su interpretación son múltiples, lo que hace muy compleja su interpretación paleoecológica. La principal dificultad deriva del hecho de que la mayor parte de los restos provienen de yacimientos arqueológicos, a los cuales han llegado como resultado directo o indirecto de una actividad antrópica. Los de plantas silvestres -mejores indicadoras del entorno de las zonas de hábitat- se conservan principalmente en condiciones anaeróbicas, siendo, pues, los yacimientos de medio húmedo los idóneos para el estudio paleoambiental.

Innovar, renovar, avaluar

[eng] The new educational context in which we are involved and the facilities of the TIC (Communication Information Technologies) have led to the necessary modification of didactic approach that during years has been used for Pharmaceutical Technology teaching. However, changes/updating and innovation require a simultaneous reflection in order to avoid excessive dispersion of the approach and to channel adequately the pedagogic and didactic effort. On the other hand, it is necessary to evaluate the above initiatives to determinate if these one are on the right track. The Pharmaceutical Technology Teaching Innovation Group of the University of Barcelona has been formed and consolidated in this point of view. In this work, a review of studies carried on by the group, in the exposed purposes, from the beginning of their activities is presented. [spa] El nuevo contexto docente en el que estamos inmersos así como las posibilidades de las TIC (Tecnologías de la Información y de la Comunicación) han conllevado la necesaria modificación de los planteamientos didácticos que durante años han servido de base para las enseñanzas de la Tecnología Farmacéutica. Sin embargo, la renovación/actualización e innovación precisan de una simultánea reflexión a fin de evitar una excesiva dispersión del enfoque y para encauzar adecuadamente el esfuerzo pedagógico y didáctico. Por otra parte, es necesario evaluar dichas iniciativas para determinar si están bien encaminadas. El Grupo de Innovación Docente de Tecnología Farmacéutica de la Universidad de Barcelona se ha creado y consolidado desde esta óptica. En este trabajo se presentan un conjunto de estudios que el grupo ha llevado a cabo, con los fines expuestos, desde el comienzo de sus actividades.

A new approach to segmentation based on fusing circumscribed contours, region growing and clustering

One of the major problems in machine vision is the segmentation of images of natural scenes. This paper presents a new proposal for the image segmentation problem which has been based on the integration of edge and region information. The main contours of the scene are detected and used to guide the posterior region growing process. The algorithm places a number of seeds at both sides of a contour allowing stating a set of concurrent growing processes. A previous analysis of the seeds permits to adjust the homogeneity criterion to the regions's characteristics. A new homogeneity criterion based on clustering analysis and convex hull construction is proposed

Hajupäästöjen tutkiminen Saint-Gobain Rakennustuotteet Oy:n Hyvinkään lasivillatehtaalla

Hajupäästöillä tarkoitetaan tavallisesti teollisen toiminnan aiheuttamia hajuaineiden päästöjä ympäristöön. Suomessa ympäristölainsäädäntö ei varsinaisesti kiellä hajuaineiden päästöjä mutta edellyttää kuitenkin, ettei niistä aiheudu merkittävää viihtyvyyshaittaa. Tässä työssä tutkittiin hajupäästöjä Saint-Gobain Rakennustuotteet Oy:n Hyvinkään lasivillatehtaalla. Tavoitteena työssä oli selvittää, mikä on tehtaan aiheuttamien päästöjen hajuvaikutus, ja mitä hajuyhdisteitä valmistusprosessissa muodostuu. Lisäksi työssä selvitettiin miten hajupäästöjä pystyttäisiin vähentämään. Työn kokeellisten tutkimusten aikana kerättiin tietoa hajun esiintymisestä valitulta tarkasteluajanjaksolta sekä mitattiin mm. tehtaan savukaasujen hajupitoisuutta ja koostumusta. Mittauksissa kaasunäytteiden hajupitoisuudeksi saatiin 170 HY/m3, joka kuvaa suhteellisen mietoa hajua. Näytteistä analysoidut haihtuvat orgaaniset yhdisteet olivat suurelta osin peräisin lasivillan valmistuksessa käytetystä sideaineesta, jota lisätään tuotteen joukkoon kuidutusvaiheessa. Ympäristöstä otetuista näytteistä ei kuitenkaan havaittu piipun yhdisteitä, mikä viittaisi siihen, että mittausjaksonaikana tehtaan päästöjen leviäminen ympäristöön on tapahtunut melko pieninä pitoisuuksina. Lisäksi on mahdollista, että ulkoilmassa yhdisteissä tapahtuu kemiallista muutuntaa ja hajontaa, jonka seurauksena yhdisteet muuttuvat. Tehtaan hajuhaitat vaikuttaisivat tutkimustulosten mukaan johtuvan savupainumaksi kutsutusta ilmiöstä. Savupainumaan vaikuttavat kaasun lämpömäärä sekä ympäristön olosuhteet ja topografia. Hajuhaittojen poistamiseksi olisi muodostuvia hajuyhdisteitä pystyttävä vähentämään 95-100 %.

Genetic diversity and species richness patterns in Baetidae (Ephemeroptera) in the Montseny Mountain range (North-East Iberian Peninsula)

This study aimed to describe patterns of diversity of Baetidae (Ephemeroptera) at the ommunity and population levels within the Montseny Mountain range (North-East Iberian Peninsula). We studied both the distribution of 4 species of baetids in 20 sites among three catchments along the altitudinal gradient (350-1700 masl); and the genetic diversity of the mtDNA cytochrome c oxidase subunit I (cox1) gene of the two common species Baetis alpinus and Baetis rhodani. We found a gradual replacement of the dominant species along the altitudinal gradient. Baetis alpinus inhabited sites at high-altitudes, and this species was replaced by B. rhodani when the altitude decreased. Baetis melanonyx and Alainites muticus attained low abundance at all river sections, and no clear altitudinal trend appeared. Our hypothesis at the population level was that genetic structuring is associated with geographic distance and limited by drainage boundaries among the three studied catchments because of the short-time dispersion of adults. Unexpectedly, analyses of molecular variance (AMOVA) and isolation-bydistance (IBD) showed genetic diversity was unstructured by distance for both species, which may be explained by the relatively short spatial scale studied and small topographic barriers among the three catchments. The Generalized Mixed Yule-Coalescent (GMYC) model showed that B. rhodani had two differentiated genetic lineages that co-occurred in all sites. Overall, diversity of baetids was structured at the community level along the altitudinal gradient, whereas it was unstructured at the population level within the Montseny Mountain range.

Genetic diversity and species richness patterns in Baetidae (Ephemeroptera) in the Montseny Mountain range (North-East Iberian Peninsula)

This study aimed to describe patterns of diversity of Baetidae (Ephemeroptera) at the ommunity and population levels within the Montseny Mountain range (North-East Iberian Peninsula). We studied both the distribution of 4 species of baetids in 20 sites among three catchments along the altitudinal gradient (350-1700 masl); and the genetic diversity of the mtDNA cytochrome c oxidase subunit I (cox1) gene of the two common species Baetis alpinus and Baetis rhodani. We found a gradual replacement of the dominant species along the altitudinal gradient. Baetis alpinus inhabited sites at high-altitudes, and this species was replaced by B. rhodani when the altitude decreased. Baetis melanonyx and Alainites muticus attained low abundance at all river sections, and no clear altitudinal trend appeared. Our hypothesis at the population level was that genetic structuring is associated with geographic distance and limited by drainage boundaries among the three studied catchments because of the short-time dispersion of adults. Unexpectedly, analyses of molecular variance (AMOVA) and isolation-bydistance (IBD) showed genetic diversity was unstructured by distance for both species, which may be explained by the relatively short spatial scale studied and small topographic barriers among the three catchments. The Generalized Mixed Yule-Coalescent (GMYC) model showed that B. rhodani had two differentiated genetic lineages that co-occurred in all sites. Overall, diversity of baetids was structured at the community level along the altitudinal gradient, whereas it was unstructured at the population level within the Montseny Mountain range.

Aerossóis atmosféricos: perspectiva histórica, fontes, processos químicos de formação e composição orgânica

This work starts with a historical perspective of the social and scientific progress related to the understanding of the atmospheric aerosol. Its origin, physical, chemical and optical characteristics, as well as its environmental behaviour are described, retracing the evolution of the concepts related to this subject over the last centuries. The main sources that contribute to atmospheric particulate matter and the modern understanding of its formation processes and constitution, focusing on the chemical pathways leading to it and on its organic components are presented. This discussion is complemented with recent evaluations of the quantities emitted by primary, secondary, biogenic and anthropogenic sources and the effects due to accumulation or dispersion of aerosols, justifying the chemical and environmental interest they engender.

High-Performance-Tensile-Strength Alpha-Grass Reinforced Starch-Based Fully Biodegradable Composites

Though there has been a great deal of work concerning the development of natural fibers in reinforced starch-based composites, there is still more to be done. In general, cellulose fibers have lower strength than glass fibers; however, their specific strength is not far from that of fiberglass. In this work, alpha-fibers were obtained from alpha-grass through a mild cooking process. The fibers were used to reinforce a starch-based biopolymer. Composites including 5 to 35% (w/w) alpha-grass fibers in their formulation were prepared, tested, and subsequently compared with those of wood- and fiberglass-reinforced polypropylene (PP). The term “high-performance” refers to the tensile strength of the studied composites and is mainly due to a good interphase, a good dispersion of the fibers inside the matrix, and a good aspect ratio. The tensile strength of the composites showed a linear evolution for fiber contents up to 35% (w/w). The strain at break of the composites decreased with the fiber content and showed the stiffening effects of the reinforcement. The prepared composites showed high mechanical properties, even approaching those of glass fiber reinforced composites

Obtenção de filmes espessos de seleneto de cobre sobre carbono vítreo, ouro, titânio e cobre

Copper selenide (berzelianite) films were prepared on the title substrates using the chemical bath deposition technique (CBD). Film composition was determined by energy dispersion of x-rays. The kinetics of film growth is parabolic and film adherence limits the film thickness. On titanium, copper selenide forms islands that do not completely cover the surface, unless the substrate is prepared with a tin oxide layer; film composition also depends on the titanium oxide layer. On vitreous carbon, CBD and mechanical immobilization techniques lead to films with similar resistances for the electron transfer across the film/substrate interface. On gold, composition studies revealed that film composition is always the same if the pH is in the range from 8 to 12, in contrast to films prepared by an ion-ion combination route. On copper, a new procedure for obtaining copper selenide films as thick as 5 µm has been developed.

Desempenho de biomassas na adsorção de hidrocarbonetos leves em efluentes aquosos

Removal of hydrocarbons from aqueous effluents using biosorbents was investigated. The effluent was simulated by a dispersion of gasoline (simple hydrocarbons) in water. Corn-cob, wood powder, coconut mesocarp and sugar-cane bagasse were used as adsorbents and their performance verified by means of batch experiments performed in an agitated vessel. The influence of input variables such as hydrocarbon concentration, mass of biomass and agitation level on the adsorbents' capacity was studied by means of factorial design. The results indicated that, among the materials studied, coconut mesocarp and sugar-cane bagasse can be considered promising biomasses for treating aqueous effluents contaminated by hydrocarbons.

Influência de poluentes atmosféricos em Belo Jardim (PE) utilizando Cladonia verticillaris (líquen) como biomonitor

Cladonia verticillaris used in this study was collected in the cerrado vegetation of Saloá (PE, Brazil) and transplanted in plastic containers on soil from the collection place to Belo Jardim (PE) that possesses lead smelters and battery industries. The experiments were disposed at eleven different places for evaluating the dispersion of pollutants and their effects on the biomonitor. The exposed lichens were collected over eight months and submitted to thin layer and high performance liquid chromatographies, and scanning electron microscopy. C. verticillaris placed in the vicinity of the emission sources demonstrated alteration in its metabolism, decreasing the production of its major compound, fumarprotocetraric acid, and deterioration of its external and internal surfaces.

Utilização de modelagem numérica para o estudo da dispersão de poluentes emitidos pela usina termoelétrica Presidente Médici

The purpose of the present study is to evaluate the atmospheric behavior in the dispersion of the pollutants SO2, PM10 and NOx emitted by the President Medici power plant in Candiota, RS. The RAMS atmospheric model was applied and the simulations were conducted from april in 20 to 24, 2004. The concentrations of the pollutants simulated by RAMS were compared with the data measured at the air quality monitoring stations. The results showed significant influence of the emissions generated by the power plant on the concentration of the pollutants.