Biogenic opal in Late Pleistocene sediments of ODP Leg 177 holes

Sediments in the southeast Atlantic sector of the Southern Ocean were cored during Ocean Drilling Program (ODP) Leg 177 to study the paleoceanographic history of the Antarctic region on short (millennial) to long (Cenozoic) timescales. Seven sites were drilled along a north-south transect across the Antarctic Circumpolar Current (ACC) from 41° to 53°S. The general goals of Leg 177 were twofold: (1) to document the biostratigraphic, biogeographic, and paleoceanographic history of the Paleogene and early Neogene, a period marked by the establishment of the Antarctic cryosphere and the ACC, and (2) to target expanded sections of late Neogene sediments, which can be used to resolve the timing of Southern Hemisphere climatic events on orbital and suborbital time scales (Gersonde, Hodell, Blum, et al., 1999, doi:10.2973/odp.proc.ir.177.1999). Closely spaced measurements of sedimentary physical properties were obtained from all cores recovered during Leg 177 using the ODP whole-round multisensor track. In addition, high-resolution diffuse color reflectance and resistivity measurements were collected on the Oregon State University Split Core Analysis Track. These whole-core and split-core measurements provide high-resolution proxy data sets for the estimation of biogenic and terrigenous mineralogy and mass flux. To assist investigators in calibrating these proxy data sets from sites located within the circum-Antarctic opal belt, samples from Sites 1093 (50°S) and 1094 (53°S) were analyzed for biogenic opal content.

Geochemistry of middle Eocene-lower Oligocene pelagic sediments of ODP Hole 105-647A

Geochemical analyses of the middle Eocene through lower Oligocene lithologic Unit IIIC (260-518 meters below seafloor [mbsf]) indicate a relatively constant geochemical composition of the detrital fraction throughout this depositional interval at Ocean Drilling Program (ODP) Site 647 in the southern Labrador Sea. The main variability occurs in redox-sensitive elements (e.g., iron, manganese, and phosphorus), which may be related to early diagenetic mobility in anaerobic pore waters during bacterial decomposition of organic matter. Initial preservation of organic matter was mediated by high sedimentation rates (36 m/m.y.). High iron (Fe) and manganese (Mn) contents are associated with carbonate concretions of siderite, manganosiderite, and rhodochrosite. These concretions probably formed in response to elevated pore-water alkalinity and total dissolved carbon dioxide (CO2) concentrations resulting from bacterial sulfate reduction, as indicated by nodule stable-isotope compositions and pore-water geochemistry. These nodules differ from those found in upper Cenozoic hemipelagic sequences in that they are not associated with methanogenesis. Phosphate minerals (carbonate-fluorapatite) precipitated in some intervals, probably as the result of desorption of phosphorus from iron and manganese during reduction. The bulk chemical composition of the sediments differs little from that of North Atlantic Quaternary abyssal red clays, but may contain a minor hydrothermal component. The silicon/ aluminum (Si/Al) ratio, however, is high and variable and probably reflects original variations in biogenic opal, much of which is now altered to smectite and/or opal CT. An increase in the sodium/potassium (Na/K) ratio in the upper Eocene corresponds to the beginning of coarsergrained feldspar flux to the site, possibly marking the onset of more vigorous deep currents. Although the Site 647 cores provide a nearly complete high-resolution, high-latitude Eocene-Oligocene record, the high sedimentation rate and somewhat unusual diagenetic conditions have led to variable alteration of benthic foraminifers and fine-fraction carbonate and have overprinted the original stable-isotope records. Planktonic foraminifers are less altered, but on the whole, there is little chance of sorting out the nature and timing of environmental change on the basis of our stable-isotope analyses.

Chemical and mineral compositions of bottom sediments and ferromanganese crusts and nodules near Iceland

Results of study of bottom sediments near Iceland and on the Jan Mayen Island are reported. It was found that in recent sediments chemical elements are mainly associated with pyro- and volcanoclastics. In some areas adjusted to deep-seated faults ancient iron-manganese crusts and sediments occur. They are rich in Ni, Co, V, Cu, Mo, Cd and other elements associated with endogenic matter.