Compilation of d18O data, living planktic foraminifera

Most of the isotopic paleotemperature equations used for paleoceanographic reconstructions have been derived from culture experiments or inorganic precipitates of calcium carbonate. To test these equations in the modern ocean, we measured the oxygen isotope composition of planktonic foraminifera (Globigerinoides ruber, Globigerinoides sacculifer, Globigerina bulloides and Neogloboquadrina pachyderma) collected from Atlantic and Southern Ocean surface waters, and added published plankton tow data from the Pacific, Indian and Arctic Oceans. The resulting species-specific regression equations of the temperature:d18O relationships for G. ruber, G. sacculifer and G. bulloides are statistically indistinguishable. The equations derived for G. sacculifer and G. bulloides agree with relationships obtained from laboratory experiments, in which these species were cultured at pH values close to modern surface waters. The equation derived from N. pachyderma has a significantly lower slope and offset than the other three species but produces a regression equation that is nearly identical to the one for the epifaunal benthic foraminifer Cibicides sp. Our work on plankton tow and pumped samples indicates that culture-derived equations appear to be more appropriate for predicting the absolute d18O of the species examined compared to equations derived from inorganic precipitates. However, over the oceanic temperature range, the slopes of the equations we derive for living species agree with the slopes obtained from inorganic precipitates.

Analytical results from sediment core MD03-2698

It is well established that orbital scale sea-level changes generated larger transport of sediments into the deep-sea during the last glacial maximum than the Holocene. However, the response of sedimentary processes to abrupt millennial-scale climate variability is rather unknown. Frequency of distal turbidites and amounts of advected detrital carbonate are estimated off the Lisbon-Setúbal canyons, within a chronostratigraphy based on radiometric ages, oxygen isotopes and paleomagnetic key global anomalies. We found that: 1) Higher frequency of turbidites concurred with Northern Hemisphere coldest temperatures (Greenland Stadials [GS], including Heinrich [H] events). But more than that, an escalating frequency of turbidites starts with the onset of global sea-level rising (and warming in Antarctica) and culminates during H events, at the time when rising is still in its early-mid stage, and the Atlantic Meridional Overturning Circulation (AMOC) is re-starting. This short time span coincides with maximum gradients of ocean surface and bottom temperatures between GS and Antarctic warmings (Antarctic Isotope Maximum; AIM 17, 14, 12, 8, 4, 2) and rapid sea-level rises. 2) Trigger of turbidity currents is not the only sedimentary process responding to millennial variability; land-detrital carbonate (with a very negative bulk d18O signature) enters the deep-sea by density-driven slope lateral advection, accordingly during GS. 3) Possible mechanisms to create slope instability on the Portuguese continental margin are sea-level variations as small as 20 m, and slope friction by rapid deep and intermediate re-accommodation of water masses circulation. 4) Common forcing mechanisms appear to drive slope instability at both millennial and orbital scales.

Eolian records from sediment core RC27-61 in the Arabian Sea

The modern Indian Ocean summer monsoon is driven by differential heating between the Asian continent and the Indian Ocean to the south. This differential heating produces a strong pressure gradient which drives southwest monsoon winds during June, July, and August. Satellite and meteorological observations, aerosol measurements, sediment trap studies, and mineralogical studies indicate an atmospheric mode of transport for modern lithogenic sediments in the northwest Arabian Sea. Analyses of lithogenic grain size and mass accumulation rate (MAR) records from the Owen Ridge indicate that eolian transport has been the primary mode of transport for the past 370 kyr. Visual inspection shows that the MAR record is positively correlated with global ice volume as indicated by the marine delta18O record. In contrast, the grain-size record varies at a much higher frequency, showing little correlation to either the MAR or the delta18O records. Spectral analyses confirm these relationships, indicating that the lithogenic grain-size and MAR records are coherent only over the precession band whereby the grain size leads the MAR by 124° (~8 kyr). We conclude that an eolian transport mechanism is the only mechanism that allows for this phase difference and at the same time is supported by comparison of the grain size and MAR with independent eolian records. We use lithogenic grain size as a paleoclimatic indicator of summer monsoon wind strength and lithogenic MAR as a paleoclimatic indicator of source-area aridity. These interpretations are supported by comparison of the lithogenic records to independent indicators of wind strength (Globigerina bulloides upwelling record) and aridity (a loess record from central China). Such comparisons indicate high coherence and zero phase relationships. Our work supports the findings of previous studies which have documented the link between monsoon strength and the Earth's axial precession cycles. Both the lithogenic MAR and the grain-size records have high coherency with precessional insolation. Maximum lithogenic MAR (source-area aridity) is in phase with delta18O (global ice volume) and leads maximum precessional insolation by 88° (~6 kyr). We attribute this lead to the influence of glacial conditions on the aridity, and therefore the deflation potential, of the source areas. Maximum lithogenic grain size (summer monsoon wind strength) lags maximum precession by 148° (~9 kyr). We attribute this lag both to the influence of global and/or local ice volume and to the availability of latent heat from the southern hemisphere Indian Ocean, the two of which combine to determine the strength of the Indian Ocean monsoon.

Seawater carbonate chemistry, processes and elements during experiments with planktonic foraminifera Orbulina universa, 2004

We investigate the sensitivity of U/Ca, Mg/Ca, and Sr/Ca to changes in seawater [CO3[2-]] and temperature in calcite produced by the two planktonic foraminifera species, Orbulina universa and Globigerina bulloides, in laboratory culture experiments. Our results demonstrate that at constant temperature, U/Ca in O. universa decreases by 25 +/- 7% per 100 µmol [CO3[2-]] kg**-1, as seawater [CO3[2-]] increases from 110 to 470 µmol kg**-1. Results from G. bulloides suggest a similar relationship, but U/Ca is consistently offset by ~+40% at the same environmental [CO3[2-]]. In O. universa, U/Ca is insensitive to temperature between 15°C and 25°C. Applying the O. universa relationship to three U/Ca records from a related species, Globigerinoides sacculifer, we estimate that Caribbean and tropical Atlantic [CO3[2-]] was 110 +/- 70 µmol kg**-1 and 80 +/- 40 µmol kg**-1 higher, respectively, during the last glacial period relative to the Holocene. This result is consistent with estimates of the glacial-interglacial change in surface water [CO3[2-]] based on both modeling and on boron isotope pH estimates. In settings where the addition of U by diagenetic processes is not a factor, down-core records of foraminiferal U/Ca have potential to provide information about changes in the ocean's carbonate concentration.