Metallic Fluence Monitors and J-value standards

Utilizing the neutron-irradiation parameter J is one of the major uncertainties in 40Ar/39Ar dating. The associated error of the individual J-value for a sample of unknown age depends on the accuracy of the age of the geological standards, the fast-neutron fluence distribution in the reactor and the distances between standards and samples during irradiation. While it is generally assumed that rotating irradiation evens out radial neutron fluence gradients, we observed axial and radial variations of the J-values in sample irradiations in the rotating channels of two reactors. To quantify them, we included three-dimensionally distributed metallic fast- (Ni) and thermal- (Co) neutron fluence monitors in three irradiations and geological age standards in three more. Two irradiations were carried out under Cd-shielding in the FRG1 reactor in Geesthacht, Germany, and four without Cd-shielding in the LVR-15 reactor in Rez, Czech Republic. The 58Ni(nf,p)58Co activation reaction and ?-spectrometry of the 811 keV peak associated with the subsequent decay of 58Co to 58Fe allow to calculate the fast-neutron fluence. The fast-neutron fluences at known positions in the irradiation container correlate with the J-values determined by mass-spectrometric 40Ar/39Ar measurements of the geological age standards. Ra-dial neutron fluence gradients are up to 1.8 %/cm in FRG1 and up to 2.2 %/cm in LVR-15; the corre-sponding axial gradients are up to 5.9 and 2.1 %/cm. We conclude that sample rotation might not al-ways suffice to meet the needs of high-precision dating and gradient monitoring can be crucial.

Holomorphic Automorphisms of Danielewski Surfaces II: Structure of the Overshear Group

We apply Nevanlinna theory for algebraic varieties to Danielewski surfaces and investigate their group of holomorphic automorphisms. Our main result states that the overshear group, which is known to be dense in the identity component of the holomorphic automorphism group, is a free product.

Electric current of an electrified jet issuing from a long metallic tube.

This paper presents an analysis of the transport of electric current in a jet of an electrically conducting liquid discharging from a metallic tube into a gas or a vacuum, and subject to an electric field due to a high voltage applied between the tube and a far electrode. The flow, the surface charge and the electric field are computed in the current transfer region of the jet, where conduction current in the liquid becomes surface current due to the convection of electric charge accumulated at its surface. The electric current computed as a function of the flow rate of the liquid injected through the tube increases first as the square root of this flow rate, levels to a nearly constant value when the flow rate is increased and finally sets to a linear increase when the flow rate is further increased. The current increases linearly with the applied voltage at small and moderate values of this variable, and faster than linearly at high voltages. The characteristic length and structure of the current transfer region are determined. Order-of-magnitude estimates for jets which are only weakly stretched by the electric stresses are worked out that qualitatively account for some of the numerical results.

Low-injection behaviour of a solar cell with a metallic grating back-reflector

Recent studies have dealt with the possibility of increasing light absorption by using the so-called electric field enhancement taking place within the grooves of metallic gratings. In order to evaluate the potential improvements derived from the absorption increase, we employ a simplified model to analyze the low-injection behaviour of a solar cell with a metallic grating back-reflector.

Fast Correction of Tiled Display Systems on Planar Surfaces

A method for fast colour and geometric correction of a tiled display system is presented in this paper. Such kind of displays are a common choice for virtual reality applications and simulators, where a high resolution image is required. They are the cheapest and more flexible alternative for large image generation but they require a precise geometric and colour correction. The purpose of the proposed method is to correct the projection system as fast as possible so in case the system needs to be recalibrated it doesn’t interfere with the normal operation of the simulator or virtual reality application. This technique makes use of a single conventional webcam for both geometric and photometric correction. Some previous assumptions are made, like planar projection surface and negligibleintra-projector colour variation and black-offset levels. If these assumptions hold true, geometric and photometric seamlessness can be achievedfor this kind of display systems. The method described in this paper is scalable for an undefined number of projectors and completely automatic.

Estimation of the solubility parameters of model plant surfaces and agrochemicals: a valuable tool for understanding plant surface interactions

Background Most aerial plant parts are covered with a hydrophobic lipid-rich cuticle, which is the interface between the plant organs and the surrounding environment. Plant surfaces may have a high degree of hydrophobicity because of the combined effects of surface chemistry and roughness. The physical and chemical complexity of the plant cuticle limits the development of models that explain its internal structure and interactions with surface-applied agrochemicals. In this article we introduce a thermodynamic method for estimating the solubilities of model plant surface constituents and relating them to the effects of agrochemicals. Results Following the van Krevelen and Hoftyzer method, we calculated the solubility parameters of three model plant species and eight compounds that differ in hydrophobicity and polarity. In addition, intact tissues were examined by scanning electron microscopy and the surface free energy, polarity, solubility parameter and work of adhesion of each were calculated from contact angle measurements of three liquids with different polarities. By comparing the affinities between plant surface constituents and agrochemicals derived from (a) theoretical calculations and (b) contact angle measurements we were able to distinguish the physical effect of surface roughness from the effect of the chemical nature of the epicuticular waxes. A solubility parameter model for plant surfaces is proposed on the basis of an increasing gradient from the cuticular surface towards the underlying cell wall. Conclusions The procedure enabled us to predict the interactions among agrochemicals, plant surfaces, and cuticular and cell wall components, and promises to be a useful tool for improving our understanding of biological surface interactions.

Estimation of the solubility parameters of model plant surfaces and agrochemicals: a valuable tool for understanding plant surface interactions

Background Most aerial plant parts are covered with a hydrophobic lipid-rich cuticle, which is the interface between the plant organs and the surrounding environment. Plant surfaces may have a high degree of hydrophobicity because of the combined effects of surface chemistry and roughness. The physical and chemical complexity of the plant cuticle limits the development of models that explain its internal structure and interactions with surface-applied agrochemicals. In this article we introduce a thermodynamic method for estimating the solubilities of model plant surface constituents and relating them to the effects of agrochemicals. Results Following the van Krevelen and Hoftyzer method, we calculated the solubility parameters of three model plant species and eight compounds that differ in hydrophobicity and polarity. In addition, intact tissues were examined by scanning electron microscopy and the surface free energy, polarity, solubility parameter and work of adhesion of each were calculated from contact angle measurements of three liquids with different polarities. By comparing the affinities between plant surface constituents and agrochemicals derived from (a) theoretical calculations and (b) contact angle measurements we were able to distinguish the physical effect of surface roughness from the effect of the chemical nature of the epicuticular waxes. A solubility parameter model for plant surfaces is proposed on the basis of an increasing gradient from the cuticular surface towards the underlying cell wall. Conclusions The procedure enabled us to predict the interactions among agrochemicals, plant surfaces, and cuticular and cell wall components, and promises to be a useful tool for improving our understanding of biological surface interactions.

Estudio de la rotura en barras de acero : aspectos experimentales y numéricos

El acero es, junto con el hormigón, el material más ampliamente empleado en la construcción de obra civil y de edificación. Además de su elevada resistencia, su carácter dúctil resulta un aspecto de particular interés desde el punto de vista de la seguridad estructural, ya que permite redistribuir esfuerzos a elementos adyacentes y, por tanto, almacenar una mayor energía antes del colapso final de la estructura. No obstante, a pesar de su extendida utilización, todavía existen aspectos relacionados con su comportamiento en rotura que necesitan una mayor clarificación y que permitirían un mejor aprovechamiento de sus propiedades. Cuando un elemento de acero es ensayado a tracción y alcanza la carga máxima, sufre la aparición de un cuello de estricción que plantea dificultades para conocer el comportamiento del material desde dicho instante hasta la rotura. La norma ISO 6892-1, que define el método a emplear en un ensayo de tracción con materiales metálicos, establece procedimientos para determinar los parámetros relacionados con este tramo último de la curva F − E. No obstante, la definición de dichos parámetros resulta controvertida, ya que éstos presentan una baja reproducibilidad y una baja repetibilidad que resultan difíciles de explicar. En esta Tesis se busca profundizar en el conocimiento del último tramo de la curva F − E de los aceros de construcción. Para ello se ha realizado una amplia campaña experimental sobre dos aceros representativos en el campo de la construcción civil: el alambrón de partida empleado en la fabricación de alambres de pretensado y un acero empleado como refuerzo en hormigón armado. Los dos materiales analizados presentan formas de rotura diferentes: mientras el primero de ellos presenta una superficie de rotura plana con una región oscura claramente apreciable en su interior, el segundo rompe según la clásica superficie en forma de copa y cono. La rotura en forma de copa y cono ha sido ampliamente estudiada en el pasado y existen modelos de rotura que han logrado reproducirla con éxito, en especial el modelo de Gurson- Tvergaard-Needleman (GTN). En cuanto a la rotura exhibida por el primer material, en principio nada impide abordar su reproducción numérica con un modelo GTN, sin embargo, las diferencias observadas entre ambos materiales en los ensayos experimentales permiten pensar en otro criterio de rotura. En la presente Tesis se realiza una amplia campaña experimental con probetas cilíndricas fabricadas con dos aceros representativos de los empleados en construcción con comportamientos en rotura diferentes. Por un lado se analiza el alambrón de partida empleado en la fabricación de alambres de pretensado, cuyo frente de rotura es plano y perpendicular a la dirección de aplicación de la carga con una región oscura en su interior. Por otro lado, se estudian barras de acero empleadas como armadura pasiva tipo B 500 SD, cuyo frente de rotura presenta la clásica superficie en forma de copa y cono. Estos trabajos experimentales han permitido distinguir dos comportamientos en rotura claramente diferenciados entre ambos materiales y, en el caso del primer material, se ha identificado un comportamiento asemejable al exhibido por materiales frágiles. En este trabajo se plantea la hipótesis de que el primer material, cuya rotura provoca un frente de rotura plano y perpendicular a la dirección de aplicación de la carga, rompe de manera cuasifrágil como consecuencia de un proceso de decohesión, de manera que la región oscura que se observa en el centro del frente de rotura se asemeja a una entalla circular perpendicular a la dirección de aplicación de la carga. Para la reproducción numérica de la rotura exhibida por el primer material, se plantea un criterio de rotura basado en un modelo cohesivo que, como aspecto novedoso, se hace depender de la triaxialidad de tensiones, parámetro determinante en el fallo de este tipo de materiales. Este tipo de modelos presenta varias ventajas respecto a los modelos GTN habitualmente empleados. Mientras los modelos GTN precisan de numerosos parámetros para su calibración, los modelos cohesivos precisan fundamentalmente de dos parámetros para definir su curva de ablandamiento: la tensión de decohesión ft y la energía de fractura GF . Además, los parámetros de los modelos GTN no son medibles de manera experimental, mientras que GF sí lo es. En cuanto a ft, aunque no existe un método para su determinación experimental, sí resulta un parámetro más fácilmente interpretable que los empleados por los modelos GTN, que utilizan valores como el porcentaje de huecos presentes en el material para iniciar el fenómeno de coalescencia o el porcentaje de poros que provoca una pérdida total de la capacidad resistente. Para implementar este criterio de rotura se ha desarrollado un elemento de intercara cohesivo dependiente de la triaxialidad de tensiones. Se han reproducido con éxito los ensayos de tracción llevados a cabo en la campaña experimental empleando dicho elemento de intercara. Además, en estos modelos la rotura se produce fenomenológicamente de la misma manera observada en los ensayos experimentales: produciéndose una decohesión circular en torno al eje de la probeta. En definitiva, los trabajos desarrollados en esta Tesis, tanto experimentales como numéricos, contribuyen a clarificar el comportamiento de los aceros de construcción en el último tramo de la curva F − E y los mecanismos desencadenantes de la rotura final del material, aspecto que puede contribuir a un mejor aprovechamiento de las propiedades de estos aceros en el futuro y a mejorar la seguridad de las estructuras construidas con ellos. Steel is, together with concrete, the most widely used material in civil engineering works. Not only its high strength, but also its ductility is of special interest from the point of view of the structural safety, since it enables stress distribution with adjacent elements and, therefore, more energy can be stored before reaching the structural failure. However, despite of being extensively used, there are still some aspects related to its fracture behaviour that need to be clarified and that will allow for a better use of its properties. When a steel item is tested under tension and reaches the maximum load point, necking process begins, which makes difficult to define the material behaviour from that moment onward. The ISO standard 6892-1, which defines the tensile testing method for metallic materials, describes the procedures to obtain some parameters related to this last section of the F − E curve. Nevertheless, these parameters have proved to be controversial, since they have low reproducibility and repeatibility rates that are difficult to explain. This Thesis tries to deepen the knowledge of the last section of the F − E curve for construction steels. An extensive experimental campaign has been carried out with two representative steels used in civil engineering works: a steel rod used for manufacturing prestressing steel wires, before the cold-drawing process is applied, and steel bars used in reinforced concrete structures. Both materials have different fracture surfaces: while the first of them shows a flat fracture surface, perpendicular to the loading direction with a dark region in the centre of it, the second one shows the classical cup-cone fracture surface. The cup-cone fracture surface has been deeply studied in the past and different numerical models have been able to reproduce it with success, with a special mention to the Gurson-Tvergaard-Needleman model (GTN). Regarding the failure surface shown by the first material, in principle it can be numerically reproduced by a GTN model, but the differences observed between both materials in the experimental campaign suggest thinking of a different failure criterium. In the present Thesis, an extensive experimental campaign has been carried out using cylindrical specimens made of two representative construction steels with different fracture behaviours. On one hand, the initial eutectoid steel rod used for manufacturing prestressing steel wires is analysed, which presents a flat fracture surface, perpendicular to the loading direction, and with a dark region in the centre of it. On the other hand, B 500 SD steel bars, typically used in reinforced concrete structures and with the typical cup-cone fracture surface, are studied. These experimental works have allowed distinguishing two clearly different fracture behaviours between both materials and, in the case of the first one, a fragile-like behaviour has been identified. For the first material, which shows a flat fracture surface perpendicular to the loading direction, the following hypothesis is proposed in this study: a quasi-brittle fracture is developed as a consequence of a decohesion process, with the dark region acting as a circular crack perpendicular to the loading direction. To reproduce numerically the fracture behaviour shown by the first material, a failure criterium based on a cohesive model is proposed in this Thesis. As an innovative contribution, this failure criterium depends on the stress triaxiality state of the material, which is a key parameter when studying fracture in this kind of materials. This type of models have some advantages when compared to the widely used GTN models. While GTN models need a high number of parameters to be defined, cohesive models need basically two parameters to define the softening curve: the decohesion stress ft and the fracture energy GF . In addition to this, GTN models parameters cannot be measured experimentally, while GF is indeed. Regarding ft, although no experimental procedure is defined for its obtention, it has an easier interpretation than the parameters used by the GTN models like, for instance, the void volume needed for the coalescence process to start or the void volume that leads to a total loss of the bearing capacity. In order to implement this failure criterium, a triaxiality-dependent cohesive interface element has been developed. The experimental results obtained in the experimental campaign have been successfully reproduced by using this interface element. Furthermore, in these models the failure mechanism is developed in the same way as observed experimentally: with a circular decohesive process taking place around the longitudinal axis of the specimen. In summary, the works developed in this Thesis, both experimental and numerical, contribute to clarify the behaviour of construction steels in the last section of the F − E curve and the mechanisms responsible for the eventual material failure, an aspect that can lead to a better use of the properties of these steels in the future and a safety improvement in the structures built with them.

Analytic free-form lens design in 3D: coupling three ray sets using two lens surfaces

The two-dimensional analytic optics design method presented in a previous paper [Opt. Express 20, 5576–5585 (2012)] is extended in this work to the three-dimensional case, enabling the coupling of three ray sets with two free-form lens surfaces. Fermat’s principle is used to deduce additional sets of functional differential equations which make it possible to calculate the lens surfaces. Ray tracing simulations demonstrate the excellent imaging performance of the resulting free-form lenses described by more than 100 coefficients.

Diffuse illuminance availability on horizontal and vertical surfaces at Madrid, Spain

The overall objective of this work is to provide diffuse illuminance availability at Madrid (Spain) through a statistical analysis of illuminance values corresponding to a long-term data series. The illuminance values are obtained from irradiance measurements by means of different empirical models for luminous efficacy. The values of diffuse illuminance on a horizontal and on vertical surfaces facing the four cardinal points are estimated and the different aspects related to daylight availability in an area with specific climatic conditions are analyzed. The experimental data consist of global and diffuse irradiance measurements on a horizontal surface provided by the National Meteorological Agency in Spain (AEMET) for Madrid. These data consist of hourly values measured in the period of 1980–2005. The statistical results derived correspond to a daylight typical year for the five surfaces considered. This information will be useful to building experts to estimate natural illumination availability when daylighting techniques are applied in building design with the main aim of electric energy savings.

Freeform Optical Surfaces: Report from OSA's First Incubator Meeting

Just as business incubator programs are designed to support the development of fledgling companies, OSA?s new incubator meeting series is structured to encourage the growth of exciting new areas within optics. The first one was devoted to the topic of freeform optics-a field that is actively evolving due to recent technological advances.

In situ study of Ge(100) surfaces with tertiarybutylphosphine supply in vapor phase epitaxy ambient

GaInP nucleation on Ge(100) often starts by annealing of the Ge(100) substrates under supply of phosphorus precursors. However, the influence on the Ge surface is not well understood. Here, we studied vicinal Ge(100) surfaces annealed under tertiarybutylphosphine (TBP) supply in MOVPE by in situ reflection anisotropy spectroscopy (RAS), X-ray photoelectron spectroscopy (XPS), and low energy electron diffraction (LEED). While XPS reveals a P termination and the presence of carbon on the Ge surface, LEED patterns indicate a disordered surface probably due to by-products of the TBP pyrolysis. However, the TBP annealed Ge(100) surface exhibits a characteristic RA spectrum, which is related to the P termination. RAS allows us to in situ control phosphorus desorption dependent on temperature.