Magnetic field induced lattice effects in a quasi-two-dimensional organic conductor close to the Mott metal-insulator transition

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Direct and Simultaneous Determination of Cd Cu, and Se in Blood Samples by Graphite Furnace Atomic Absorption Spectrometry

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Internal standardization and least-squares background correction in high-resolution continuum source flame atomic absorption spectrometry to eliminate interferences on determination of Pb in phosphoric acid

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Estudo voltamétrico de redissolução catódica de cefaloglicina em meio aquoso sobre eletrodo de mercúrio

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Optical Fiber Relative Humidity Sensor Based on a FBG with a Di-Ureasil Coating

In this work we proposed a relative humidity (RH) sensor based on a Bragg grating written in an optical fiber, associated with a coating of organo-silica hybrid material prepared by the sol-gel method. The organo-silica-based coating has a strong adhesion to the optical fiber and its expansion is reversibly affected by the change in the RH values (15.0-95.0%) of the surrounding environment, allowing an increased sensitivity (22.2 pm/%RH) and durability due to the presence of a siliceous-based inorganic component. The developed sensor was tested in a real structure health monitoring essay, in which the RH inside two concrete blocks with different porosity values was measured over 1 year. The results demonstrated the potential of the proposed optical sensor in the monitoring of civil engineering structures.

Relative antioxidant activity of Brazilian medicinal plants for gastrointestinal diseases

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Crescimento de figueira sob diferentes condições de cultivo

A análise de crescimento de plantas pode ser considerada um bom indicativo para a avaliação das bases fisiológicas de produção e da influência exercida por variáveis ambientais, genéticas e agronômicas. Avaliou-se o crescimento da figueira 'Roxo de Valinhos', submetida a irrigação e cobertura morta (bagacilho de cana-de-açúcar triturado), em Botucatu (SP). O experimento utilizou blocos casualizados, em esquema fatorial 2x2 (cobertura morta x irrigação), com 4 repetições, sendo cada repetição constituída por 3 plantas, com caracterização dos seguintes tratamentos: T1 - sem irrigação e sem cobertura morta; T2 - sem irrigação e com cobertura morta; T3 - com irrigação e sem cobertura morta; T4 - com irrigação e cobertura morta. Foram realizadas análises destrutivas e não destrutivas, aos 7, 55, 76, 97, 114, 135, 156, 176, 198, 219, 240, 254 e 275 dias após o transplantio, com base nos seguintes parâmetros: diâmetro do ramo e do caule, comprimento do ramo, número de folhas, número de entrenós e número de frutos. Foram particionados os diferentes órgãos da planta, para obtenção da massa seca e fresca das partições isoladas. As medições da área foliar (cm²) foram realizadas com aparelho integrador fotoelétrico. O manejo da irrigação foi realizado com o auxílio da técnica de tensiometria, mantendo o potencial matricial do solo próximo a -30 kPa. O uso de cobertura morta e irrigação favoreceu o desenvolvimento das plantas (diâmetro do caule de 36,60 mm e comprimento do ramo de 1,28 m), e as taxas de crescimento, crescimento relativo e assimilatória líquida da cultura foram de 7 g m-2 dia-1, 0,015 g g-1 dia-1 e 17 g m-2 dia-1, respectivamente. As taxas indicaram que a cobertura morta ofereceu condições hídricas satisfatórias ao rápido estabelecimento das mudas.

Determination of a point sufficiently close to the asymptote in nonlinear growth functions

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Electrothermal AAS determination of Ni in soft drinks using Co as the internal standard

A method for the direct determination of Ni in soft drinks by graphite furnace atomic absorption spectrometry using a transversely heated graphite atomizer (THGA), Zeeman-effect background corrector, and Co as the internal standard (IS) is proposed. Magnesium nitrate was used to stabilize both Ni and Co. All diluted samples (1+1) in 0.2% (v/v) HNO3 and reference solutions [5.0-50 mu g L-1 Ni in 0.2% (v/v) HNO3] were spiked with 50 mu g L-1 Co. For a 20-mu L sample dispensed into the atomizer, correlations between the ratio of absorbance of Ni to absorbance of Co and the analyte concentration were close to 0.9996. The relative standard deviation of the measurements varied from 0.5 to 3.4% and 1.0 to 7.0% (n=12) with and without IS, respectively. Recoveries within 98-104% for Ni spikes were obtained using IS. The characteristic mass was calculated as 43 pg Ni and the limit of detection was 1.4 mu g L-1. The accuracy of the method was checked for the direct determination of Ni in soft drinks and the results obtained with IS were better than those without IS.

Debris perturbed by radiation pressure: relative velocities across circular orbits

In the present work we consider a dynamical system of mum size particles around the Earth subject to the effects of radiation pressure. Our main goal is to study the evolution of its relative velocity with respect to the co-planar circular orbits that it crosses. The particles were initially in a circular geostationary orbit, and the particles size were in the range between 1 and 100 mum. The radiation pressure produces variations in its eccentricity, resulting in a change in its orbital velocity. The results indicated the maximum linear momentum and kinetic energy increases as the particle size increases. For a particle of 1 mum the kinetic energy is approximately 1.56 x 10(-7) J and the momentum is 6.27 x 10(-11) kg m/s and for 100 mum the energy is approximately 1.82 x 10(-4) J and the momentum is 2.14 x 10(-6) kg m/s. (C) 2004 COSPAR. Published by Elsevier Ltd. All rights reserved.

POSITRON-HELIUM SCATTERING IN THE CLOSE-COUPLING APPROACH

We present results for low-energy elastic S-, P-, and D-wave phase shifts, capture and total cross sections of positron-helium scattering with different basis sets in the close coupling approach using realistic wave functions for He(1s1s), He(1s2(1)s), He(1s2(1)p) and positronium (1s) states. A resonance is found in the S-wave capture cross section at 84 eV.

Positronium-alkali-ion scattering in the close-coupling approximation

We present results for low- and medium-energy elastic and capture cross sections for positronium-atom-alkali-ion scattering using the coupled static close-coupling approximation.

Determination of Cd(II) and Cd-metallothioneins in biological extracts using baker's yeast and inductively coupled plasma optical emission spectrometry

The use of Saccharomyces cerevisiae as a sorbent material to separate Cd(II) and Cd-metallothionein complex (Cd-MT) has been explored. Solid-liquid phase extractions were carried out in batch mode and the main parameters of the process (pH, temperature, time of incubation, amount of biomass and analyte) were evaluated. Under optimized conditions, the yeast quantitatively retain (94 +/- 5%) the Cd(II) while 97 +/- 2% of the Cd-MT remain in the supernatant. on base of the findings of this study, a simple method is proposed to determine Cd(II) and Cd-MT in cytosols extracted from mouse kidney and crab hepatopancreas. Inductively coupled plasma optical emission spectrometry was used to quantify the analytes in solid and liquid phase. Determination of Cd in the solid phase was carried out by introducing a slurry of the yeast (0.0625 g/10 mL) directly to the inductively coupled plasma optical emission spectrometer. Mixed standards solutions, which also have been submitted to the extraction procedure, were used to quantify the analytes in the samples. Thus, matrix effects due to nebulization of the slurry were overcame. Limits of detection (3 sigma) for Cd(II) and Cd-MT were 1.5 and 1.2 mu g L-1, respectively. Relative standard deviations of signals were 4.2% for measurements in the slurry of solid phase and 2.1% for measurements in the liquid phase. Recoveries of the analytes in cytosol samples were between 76 and 114%. The concentrations of Cd(II) (2.4 +/- 0.5 mu g L-1) and Cd-MT (3.0 +/- 0.5 mu g L-1) found by using the proposed approach were close to those found by tangential-flow ultrafiltration technique (2.6 +/- 0.7 mu g L-1 for Cd(II) and 3.7 +/- 1.7 mu g L-1 for Cd-MT).

A RELATIVE COHOMOLOGICAL INVARIANT FOR GROUP PAIRS

We define a cohomological invariant E(G, S, M) where G is a group, S is a non empty family of (not necessarily distinct) subgroups of infinite index in G and M is a F2G-module (F2 is the field of two elements). In this paper we are interested in the special case where the family of subgroups consists of just one subgroup, and M is the F2G-module F2(G/S). The invariant E(G, {S}, F2(G/S)) will be denoted by E(G, S). We study the relations of this invariant with other ends e(G) , e(G, S) and e(G, S), and some results are obtained in the case where G and S have certain properties of duality.