991 resultados para Solà-Morales, Manuel de, 1939-2012
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Mode of access: Internet.
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Mode of access: Internet.
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Mode of access: Internet.
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Mode of access: Internet.
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Mode of access: Internet.
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Representada en el teatro del Príncipe la noche del ll de Agosto de 1854."
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Bone is the second most widely transplanted tissue after blood. Synthetic alternatives are needed that can reduce the need for transplants and regenerate bone by acting as active temporary templates for bone growth. Bioactive glasses are one of the most promising bone replacement/regeneration materials because they bond to existing bone, are degradable and stimulate new bone growth by the action of their dissolution products on cells. Sol-gel-derived bioactive glasses can be foamed to produce interconnected macropores suitable for tissue ingrowth, particularly cell migration and vascularization and cell penetration. The scaffolds fulfil many of the criteria of an ideal synthetic bone graft, but are not suitable for all bone defect sites because they are brittle. One strategy for improving toughness of the scaffolds without losing their other beneficial properties is to synthesize inorganic/organic hybrids. These hybrids have polymers introduced into the sol-gel process so that the organic and inorganic components interact at the molecular level, providing control over mechanical properties and degradation rates. However, a full understanding of how each feature or property of the glass and hybrid scaffolds affects cellular response is needed to optimize the materials and ensure long-term success and clinical products. This review focuses on the techniques that have been developed for characterizing the hierarchical structures of sol-gel glasses and hybrids, from atomicscale amorphous networks, through the covalent bonding between components in hybrids and nanoporosity, to quantifying open macroporous networks of the scaffolds. Methods for non-destructive in situ monitoring of degradation and bioactivity mechanisms of the materials are also included. © 2012 The Royal Society.
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The aim was to determine the most effective calcium precursor for synthesis of sol-gel hybrids and for improving homogeneity of sol-gel bioactive glasses. Sol-gel derived bioactive calcium silicate glasses are one of the most promising materials for bone regeneration. Inorganic/organic hybrid materials, which are synthesized by incorporating a polymer into the sol-gel process, have also recently been produced to improve toughness. Calcium nitrate is conventionally used as the calcium source, but it has several disadvantages. Calcium nitrate causes inhomogeneity by forming calcium-rich regions, and it requires high temperature treatment (>400 C) for calcium to be incorporated into the silicate network. Nitrates are also toxic and need to be burnt off. Calcium nitrate therefore cannot be used in the synthesis of hybrids as the highest temperature used in the process is typically 40-60 C. Therefore, a different precursor is needed that can incorporate calcium into the silica network and enhance the homogeneity of the glasses at low (room) temperature. In this work, calcium methoxyethoxide (CME) was used to synthesize sol-gel bioactive glasses with a range of final processing temperatures from 60 to 800 C. Comparison is made between the use of CME and calcium chloride and calcium nitrate. Using advanced probe techniques, the temperature at which Ca is incorporated into the network was identified for 70S30C (70 mol % SiO, 30 mol % CaO) for each of the calcium precursors. When CaCl was used, the Ca did not seem to enter the network at any of the temperatures used. In contrast, Ca from CME entered the silica network at room temperature, as confirmed by X-ray diffraction, Si magic angle spinning nuclear magnetic resonance spectroscopy, and dissolution studies. CME should be used in preference to calcium salts for hybrid synthesis and may improve homogeneity of sol-gel glasses.
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World War II profoundly impacted Florida. The military geography of the State is essential to an understanding the war. The geostrategic concerns of place and space determined that Florida would become a statewide military base. Florida's attributes of place such as climate and topography determined its use as a military academy hosting over two million soldiers, nearly 15 percent of the GI Army, the largest force the US ever raised. One-in-eight Floridians went into uniform. Equally, Florida's space on the planet made it central for both defensive and offensive strategies. The Second World War was a war of movement, and Florida was a major jump off point for US force projection world-wide, especially of air power. Florida's demography facilitated its use as a base camp for the assembly and engagement of this military power. In 1940, less than two percent of the US population lived in Florida, a quiet, barely populated backwater of the United States. But owing to its critical place and space, over the next few years it became a 65,000 square mile training ground, supply dump, and embarkation site vital to the US war effort. Because of its place astride some of the most important sea lanes in the Atlantic World, Florida was the scene of one of the few Western Hemisphere battles of the war. The militarization of Florida began long before Pearl Harbor. The pre-war buildup conformed to the US strategy of the war. The strategy of theUS was then (and remains today) one of forward defense: harden the frontier, then take the battle to the enemy, rather than fight them in North America. The policy of "Europe First," focused the main US war effort on the defeat of Hitler's Germany, evaluated to be the most dangerous enemy. In Florida were established the military forces requiring the longest time to develop, and most needed to defeat the Axis. Those were a naval aviation force for sea-borne hostilities, a heavy bombing force for reducing enemy industrial states, and an aerial logistics train for overseas supply of expeditionary campaigns. The unique Florida coastline made possible the seaborne invasion training demanded for US victory. The civilian population was employed assembling mass-produced first-generation container ships, while Floridahosted casualties, Prisoners-of-War, and transient personnel moving between the Atlantic and Pacific. By the end of hostilities and the lifting of Unlimited Emergency, officially on December 31, 1946, Floridahad become a transportation nexus. Florida accommodated a return of demobilized soldiers, a migration of displaced persons, and evolved into a modern veterans' colonia. It was instrumental in fashioning the modern US military, while remaining a center of the active National Defense establishment. Those are the themes of this work.
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Natal has come through major changes in the last 150 years, since the actions of city beautification, in the 19th century, until the present day, when such transformations start to have the objective of including the city in the competition for the attraction of the capital flows and consumption, domestically and in a foreign sense. It is thought that the first initiatives aimed at increasing tourism in Natal occurred in the 1960s, however, it became apparent that only from the 1980s was there a significant increase in tourist activities in Natal and the Metropolitan Region, especially on the east coast of the state of Rio Grande do Norte, leading to an expansion of the labour market, the significant increase of foreign investment, territorial changes of great impact and the production of buildings primarily intended for the hotel industry and second residence for European tourists. Since then, the incentives for tourist activity in the state have been maintained and even increased, based on tourism aimed at natural beauties, local cuisine and events, which transformed the tourist activity in one of the main sources of foreign exchange for the city of Natal. In the early 21st century, the construction of high-rise condominiums, monuments (including the designer ones), such as the Parque da Cidade, designed by Oscar Niemeyer, were already established. Also, shopping centers and, in order to host the World Cup, the new football stadium, the Arena das Dunas, among others, which were aimed at local and foreign consumers, especially European, stood out in the city. It is understood that these new buildings, monuments and also renovations and restorations that were deployed in the city of Natal aimed at constructing a new identity for the city, within the process of capitalist development and urban spectacle. It is considered that the monuments and the iconic buildings are attributes of the cities aimed at selling locations as goods, establishing a new urban environment, a new role as cities, which aimed at seeking greater autonomy from the nation-state. In this research, it was sought to analyze the architectural object, that is, buildings and monuments built or restored in Natal and its relevance to the city marketing promoted by the city itself. It was found that, indeed, such buildings and monuments are inserted in contemporary architectural production as a basis for increasing the competitive nature of Natal. In addition, they reveal a capitalist mode of production, supported by public resources, operating in the production of urban space with a view to repeating the hegemonic model of a competitive city
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Desde mediados del siglo XX se manifiestan en el universo artístico propuestas caracterizadas por la falta de reflexión y la ausencia de compromiso con el entorno social y político. Prevalece en los artistas una actitud individualista y el desprendimiento de un interés por lo social, lo que ha significado un ejercicio de construcción estética desde su propio universo subjetivo. De otro lado, el conjunto de relaciones que determinan y gobiernan las prácticas artísticas configuran una institucionalidad fuertemente cimentada, desde donde se imponen modos de producción y circulación del arte que favorecen la persistencia de un distanciamiento entre el artista y su acontecer. Mayoritariamente la formalización de la obra artística transita de forma obligada hacia la mera circulación y exhibición en espacios institucionales, es destinada a un espectador recogido y silencioso. La obra en estos casos busca sustraer al espectador de su entorno habitual para contactarlo pasivamente con las obras presentadas. Sin embargo, contrarias a estos planteamientos, asoman actitudes en cierta comunidad artística que defiende la necesidad de socializar sus prácticas y de alimentar un intercambio directo con el conglomerado social, principalmente con comunidades urbanas, llegando incluso a proponer la promoción de las cualidades sociales en los individuos...
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El trabajo presenta un análisis cualitativo-cuantitativo del uso variable del perfecto simple y perfecto compuesto en los discursos presidenciales de Evo Morales, de acuerdo con la perspectiva Etnopragmática desarrollada por García 1990, 1995; Martínez 1995, 2000; Mauder 2000. Se considera la singularidad de una variedad en situación de contacto lingüístico: la del español en contacto con el aymara y el quechua, y se indaga sobre las transformaciones que pueden producirse cuando diferentes lenguas -diferentes visiones de mundo- entran en contacto. En relación con esto, veremos que la presencia, tanto en la lengua quechua como en la lengua aymara, de un sistema evidencial gramaticalizado podría influir en la variación del perfecto simple y compuesto en los discursos de Morales, en particular, que la presencia de la forma del perfecto compuesto podría funcionar como una marca de evidencia directa y su uso contribuiría a la estrategia discursiva del orador de mostrar ciertos hechos de la historia de Bolivia como cercanos a su vivencia y experiencia personales, marcando un mayor grado compromiso con respecto a la veracidad de lo que enuncia. De esta manera, el orador consigue aunar su voz con la de los pueblos originarios, formar parte de los grupos discriminados y excluidos de la historia de su país y así, contar con su apoyo y acompañamiento durante su mandato.
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A lo largo de los últimos años, la expresión "memoria histórica" resulta omnipresente en el discurso político, social y cultural europeo. Cuando, en el caso de España, se menciona la "memoria histórica" los acontecimientos a que se refiere en la mayoría de los casos son la Guerra Civil (1936-1939) y el Franquismo (1939-1975), acontecimientos cuya memoria nunca pierde su actualidad y necesidad. A partir del año 2000 se inició la apertura pública al pasado oculto y reprimido que lleva consigo la liberación de los recuerdos que habían permanecido marginados e ignorados hasta ahora. La obra del autor gallego Manuel Rivas forma parte de este proceso de recuperación de la memoria histórica y pone su enfoque, precisamente, en ese pasado incómodo que tantos años ha permanecido oculto para contribuir a la reivindicación de la memoria de las víctimas de la represión franquista. En Os libros arden mal (2006), Manuel Rivas ofrece un panorama complejo y diverso del pasado traumático. A través de la confrontación de diferentes comunidades de memoria -en muchos casos antagonistas- elabora la historia vivida por los ciudadanos coruñeses. Con referencia a los conceptos correspondientes a la memoria colectiva desarrollada en las Ciencias Sociales y Culturales, este artículo tiene la intención de estudiar la memoria de la Guerra Civil y el Franquismo a partir del análisis de una de las familias retratadas en la novela.
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El trabajo presenta un análisis cualitativo-cuantitativo del uso variable del perfecto simple y perfecto compuesto en los discursos presidenciales de Evo Morales, de acuerdo con la perspectiva Etnopragmática desarrollada por García 1990, 1995; Martínez 1995, 2000; Mauder 2000. Se considera la singularidad de una variedad en situación de contacto lingüístico: la del español en contacto con el aymara y el quechua, y se indaga sobre las transformaciones que pueden producirse cuando diferentes lenguas -diferentes visiones de mundo- entran en contacto. En relación con esto, veremos que la presencia, tanto en la lengua quechua como en la lengua aymara, de un sistema evidencial gramaticalizado podría influir en la variación del perfecto simple y compuesto en los discursos de Morales, en particular, que la presencia de la forma del perfecto compuesto podría funcionar como una marca de evidencia directa y su uso contribuiría a la estrategia discursiva del orador de mostrar ciertos hechos de la historia de Bolivia como cercanos a su vivencia y experiencia personales, marcando un mayor grado compromiso con respecto a la veracidad de lo que enuncia. De esta manera, el orador consigue aunar su voz con la de los pueblos originarios, formar parte de los grupos discriminados y excluidos de la historia de su país y así, contar con su apoyo y acompañamiento durante su mandato.