833 resultados para Precursor solutions


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A new class of accelerating, exact, explicit and simple solutions of relativistic hydrodynamics is presented. Since these new solutions yield a finite rapidity distribution, they lead to an advanced estimate of the initial energy density and life-time of high energy heavy ion collisions. Accelerating solutions are also given for spherical expansions in arbitrary number of spatial dimensions.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Magnetic properties of two spinel oxides solid solutions, Cul+xMn2-xO4 and Ni1+xMn2-xO4 are reported. These series are characterized by two magnetic transitions: the upper one, of ferrimagnetic type, occurs at about 85 K (for copper-based) and at 105-110 K (for nickel-based spinels), independently of the x-content: the lower transition may be related to a Neel-type collinear ordering and takes place at 30 and 45 K, respectively. Application of moderate fields (H > 250 Oe) make both transitions to merge into one broad maximum in the magnetization, which takes place at lower temperature when applying larger fields. Magnetization cycles with temperature (ZFC/FC) or field (loops) allowed us to well characterize the ordered state. The effective moment follows the expected behavior when manganese ions are being substituted by ions of lower magnetic moment (Ni(2+)andCU(2+)). (c) 2007 Elsevier Ltd. All rights reserved.

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LiNbO3 thin films were grown on (0001) sapphire substrates by a chemical route, using the polymeric precursor method. The overall process consists of preparing a coating solution from the Pechini process, based on metallic citrate polymerization, the precursor films, deposited by dip coating, are then heat treated to eliminate the organic material and to synthesize the phase. In this work, we studied the influence of the heat treatment on the structural and optical properties of single-layered films. Two routes were also investigated to increase the film thickness: increasing the viscosity of the coating solution and/or increasing the number of successively deposited layers. The x-ray diffraction theta -2 theta scans revealed the c-axis orientation of the single- and multilayered films and showed that efficient crystallization can be obtained at temperatures as low as 400 degreesC, the phi-scan diffraction evidenced the epitaxial growth with two in-plane variants, A microstructural study revealed that the films were crack free, homogeneous, and relatively dense. Finally, the investigation of the optical properties (optical transmittance and refractive index) confirmed the good quality of the films. These results indicate that the polymeric precursor method is a promising process to develop lithium niobate waveguides.

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Nanocrystalline ZrO2-12 mol % CeO2 powders were synthesized using a polymeric precursor method based on the Pechini process. X-ray diffraction (XRD) patterns showed that the method was effective to synthesize tetragonal zirconia single-phase. The mean crystallite size attained ranges from 6 to 15 nm. The BET surface areas were relatively high reaching 97 m(2)/g. Studies by nitrogen adsorption/desorption on powders, dilatometry of the compacts, and transmission electron microscopy (TEM) of the powders, were also developed to verify the particles agglomeration state. Both citric acid : ethylene glycol ratio and calcination temperature affected the powder morphology, which influenced the sinterability and microstructure of the sintered material, as showed by scanning electron microscopy (SEM). (C) 2001 Kluwer Academic Publishers.

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(1-x)PbF2-(x)CdF2 solid solutions (with 0.1 less than or equal to x less than or equal to 0.5) were obtained by hyper-quenching the melt. Structural characteristics have been studied by X-ray diffraction (XRD) and extended X-ray absorption fine structure (EXAFS). A cubic solid solution was obtained in which the lattice parameter decreases with increasing CdF2 content. High anionic disorder was evidenced from EXAFS investigations, whereas cations remain in the FCC arrangement. Pb L-3-edge EXAFS results illustrate clearly the occurrence of CdxPb1-xF2 mixed crystals by the introduction of Cd atoms in the second Pb coordination shell. (C) 2002 Elsevier B.V. B.V. All rights reserved.

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In this paper 4.5SiO(2)-3Al(2)O(3-x)Nb(2)O(5)-2CaO powders have been synthesized using a chemical process the Polymeric Precursor Method. The process of glass formation has been investigated by XRD and DTA, the results confirm that the prepared powders are glasses. Experimental data show that amount of Nb2O5 had a considerable effect on the T-g values. The structures of glasses prepared. have been determined by Si-29 and Al-27 MAS NMR and the results indicated that the network is formed by SiO4 and AlO4 tetrahedral linked and probably Si-O-Nb bonds are present in the vitreous network. (C) 2005 Elsevier B.V. All rights reserved.