Chemical and electrochemical investigations of cobalt cyanide and ruthenium ammine complexes

Part I.

The stoichiometry and kinetics of the reaction between Co(CN₅H^3- and HgX₂ (X = CN, OH) have been investigated. The products of the reaction are two new complexes, [(NC)₅Co-HgX]^3- and [(NC)₅Co-Hg-Co(CN)₅]^6-, whose spectra are reported. The kinetic measurements produced a value for the forward rate constant of the reaction Co(CN)₅H^3- + OH^- k₁/k_-1 Co(CN)₅^4- +H₂O, k1 = (9.7 ± 0.8) x 10^-2 M^-1 sec^-1 at 24°C, and an equilibrium constant for the reaction K = 10^-6 M^-1.

Part II.

Unusually large and sharp "adsorption waves" appear in cyclic voltammograms of Co(CN)₅^3- and several cobalt(III) pentacyano complexes at stationary mercury electrodes. The nature of the adsorbed species and the reasons for the absence of the adsorption waves in polarograms taken with a d.m.e. have been examined. The data are compatible with the adsorption, in all cases, of a coordinatively unsaturated cobalt(II) complex, Co(CN)₄^2-, by means of a cobalt-mercury bond. When the resulting adsorbed complex is reduced, a series of subsequent chemical and electrode reactions is initiated in which three faradays of charge are consumed for each mole of adsorbed complex. The adsorption of the anionic complex strongly retards the reduction of other negatively charged complexes.

Part III.

A number of formal redox potentials for Ru^III (NH₃)₅L + e = Ru^II (NH₃)₅L and Ru^III(NH₃)₄L₂ + e = Ru^II (NH₃)₄L₂ (where L is various ligands) has been measured by cyclic voltammetry, potentiometry, and polarography and are discussed in terms of the properties of the ligands, such as π-accepting capability. Reduction of coordinated pyrazine in the complexes, Ru(NH₃)₅ Pz²⁺, cis- and trans-Ru(NH₃)₄Pz₂²⁺, on a mercury electrode has been observed. The behavior of this reduction in various acidity of the solution as well as the reoxidation of the reduction products are discussed.

Report of the Inter-American Tropical Tuna Commission for the year 1992

ENGLISH: The Inter-American Tropical Tuna Commission operates under the authority and direction of a convention originally entered into by Costa Rica and the United States. The convention, which carne into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas in the eastern Pacific Ocean. Under this provision Panama adhered in 1953, Ecuador in 1961, Mexico in 1964, Canada in 1968, Japan in 1970, and France and Nicaragua in 1973. Ecuador withdrew from the Commission in 1968, Mexico in 1978, Costa Rica in 1979, and Canada in 1984. Costa Rica re-adhered to the convention in 1989, and Vanuatu and Venezuela joined the Commission in 1990 and 1992, respectively. The Commission held its 50th meeting in La Jolla, California, USA, on June 16-18, 1992. SPANISH: La Comisión Interamericana del Atún Tropical funciona bajo la autoridad y dirección de un convenio suscrito originalmente por Costa Rica y los Estados Unidos de América. El convenio, vigente desde 1950, está abierto a la afiliación de cualquier país cuyos ciudadanos pesquen atunes tropicales en el Océano Pacífico oriental. Bajo esta estipulación, la República de Panamá se afilió en 1953, Ecuador en 1961, México en 1964, Canadá en 1968, Japón en 1970, y Francia y Nicaragua en 1973. Ecuador se retiró de la Comisión en 1968, México en 1978, Costa Rica en 1979, y Canadá en 1984. Costa Rica se adhirió de nuevo al Convenio en 1989; y Vanuatu y Venezuela se hicieron miembros de la Comisión en 1990 y 1992, respectivamente. La Comisión celebró su quincuagésima reunión en La Jolla, California, EE.UU., del 16 al 18 de junio de 1992. (PDF contains 316 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1993

ENGLISH: The Inter-American Tropical Tuna Commission (IATTC) operates under the authority and direction of a convention originally entered into by Costa Rica and the United States. The convention, which carne into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas and tuna-like species in the eastern Pacific Ocean. Under this provision Panama adhered in 1953, Ecuador in 1961, Mexico in 1964, Canada in 1968, Japan in 1970, France and Nicaragua in 1973, Vanuatu in 1990, and Venezuela in 1992. Ecuador withdrew from the IATTC in 1968, Mexico in 1978, Costa Rica in 1979, and Canada in 1984. Costa Rica readhered to the convention in 1989. The Commission held its 51st meeting in Port Vila, Vanuatu, on June 8-10, 1993. SPANISH: La Comisión Interamericana del Atún Tropical (CIAT) funciona bajo la autoridad y dirección de un convenio suscrito originalmente por Costa Rica y los Estados Unidos de América. El convenio, vigente desde 1950, está abierto a la afiliación de cualquier país cuyos ciudadanos pesquen atunes tropicales y especies afines en el Océano Pacífico oriental. Bajo esta estipulación, la República de Panamá se afilió en 1953, Ecuador en 1961, México en 1964, Canadá en 1968, Japón en 1970, Francia y Nicaragua en 1973, Vanuatu en 1990, y Venezuela en 1992. Ecuador se retiró de la CIAT en 1968, México en 1978, Costa Rica en 1979, y Canadá en 1984. Costa Rica se adhirió de nuevo al Convenio en 1989. La Comisión celebró su 51ª reunión en Port Vila (Vanuatu) del 8 al 10 de junio de 1993. (PDF contains 316 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1994

ENGLISH: The Inter-American Tropical Tuna Commission (IATTC) operates under the authority and direction of a convention originally entered into by Costa Rica and the United States. The convention, which came into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas and tuna-like species in the eastern Pacific Ocean. Under this provision Panama adhered in 1953, Ecuador in 1961, Mexico in 1964, Canada in 1968, Japan in 1970, France and Nicaragua in 1973, Vanuatu in 1990, and Venezuela in 1992. Ecuador withdrew from the IATTC in 1968, Mexico in 1978, and Canada in 1984. The Commission held its 53rd meeting in Cumaná, Venezuela, on June 7-8, 1994. SPANISH: La Comisión Interamericana del Atún Tropical (CIAT) funciona bajo la autoridad ydirección de un convenio suscrito originalmente por Costa Rica y los Estados Unidos de América. El convenio, vigente desde 1950, está abierto a la afiliación de cualquier país cuyos ciudadanos pesquen atunes tropicales y especies afines en el Océano Pacífico oriental. Bajo esta estipulación, la República de Panamá seafilióen 1953, Ecuadoren 1961, México en 1964, Canadáen 1968,Japónen 1970, FranciayNicaragua en 1973, Vanuatu en 1990, y Venezuela en 1992. Ecuador se retiró de la CIAT en 1968, México en 1978, y Canadá en 1984. La Comisión celebró su 53a reunión en Cumaná (Venezuela) el 7 y 8 de junio de 1994. (PDF contains 296 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1995

ENGLISH: The Inter-American Tropical Tuna Commission (IATTC) operates under the authority and direction of a convention originally entered into by Costa Rica and the United States. The convention, which came into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas and tuna-like species in the eastern Pacific Ocean. Under this provision Panama adhered in 1953, Ecuador in 1961, Mexico in 1964, Canada in 1968, Japan in 1970, France and Nicaragua in 1973, Vanuatu in 1990, and Venezuela in 1992. Ecuador withdrew from the IATTC in 1968, Mexico in 1978, and Canada in 1984. The IATTC held its 55th meeting in La Jolla, California, USA, on June 13-15, 1995. SPANISH: La Comisión Interamericana del Atún Tropical (CIAT) funciona bajo la autoridad ydirección de un convenio suscrito originalmente por Costa Rica y los Estados Unidos de América. El convenio, vigente desde 1950, está abierto a la afiliación de cualquier país cuyos ciudadanos pesquen atunes tropicales y especies afines en el Océano Pacífico oriental. Bajo esta estipulación, la República de Panamá seafilióen 1953, Ecuadoren 1961, México en 1964, Canadáen 1968,Japónen 1970, FranciayNicaragua en 1973, Vanuatu en 1990, y Venezuela en 1992. Ecuador se retiró de la CIAT en 1968, México en 1978, y Canadá en 1984. La CIAT celebró su 55a reunión en La Jolla, California (EE.DU.) del 13 al15 de junio de 1995. (PDF contains 336 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1996

ENGLISH: The Inter-American Tropical Tuna Commission (IATTC) operates under the authority and direction of a convention originally entered into by Costa Rica and the United States. The convention, which came into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas and tuna-like species in the eastern Pacific Ocean. Under this provision Panama adhered in 1953, Ecuador in 1961, Mexico in 1964, Canada in 1968, Japan in 1970, France and Nicaragua in 1973, Vanuatu in 1990, and Venezuela in 1992. Ecuador withdrew from the IATTC in 1968, Mexico in 1978, and Canada in 1984. The IATTC held its 57th meeting in La Jolla, California, USA, on October 21-23, 1996. SPANISH: La Comisión Interamericana del Atún Tropical (CIAT) funciona bajo la autoridad y dirección de un convenio suscrito originalmente por Costa Rica y los Estados Unidos de América. El convenio, vigente desde 1950, está abierto a la afiliación de cualquier país cuyos ciudadanos pesquen atunes tropicales y especies afines en el Océano Pacífico oriental. Bajo esta estipulación, la República de Panamá seafilióen 1953, Ecuador en 1961, México en 1964, Canadá en 1968, Japón en 1970, Francia y Nicaragua en 1973, Vanuatu en 1990, y Venezuela en 1992. Ecuador se retiró de la CIAT en 1968, México en 1978, y Canadá en 1984. La CIAT celebró su 57a reunión en La Jolla, California (EE.DU.) del 21 a123 de octubre de 1996. (PDF contains 360 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1997

ENGLISH: The Inter-American Tropical Tuna Commission (IATTC) operates under the authority and direction of a convention originally entered into by Costa Rica and the United States. The convention, which came into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas and tuna-like species in the eastern Pacific Ocean (EPO). Under this provision Panama adhered in 1953, Ecuador in 1961, Mexico in 1964, Canada in 1968, Japan in 1970, France and Nicaragua in 1973, Vanuatu in 1990, Venezuela in 1992, and EI Salvador in 1997. Mexico withdrew from the IATTC in 1978 and Canada in 1984. The 58th meeting of the IATTC was held in San Jose, Costa Rica, on June 3-4, 1997. SPANISH: La Comisión Interamericana del Atún Tropical (CIAT) funciona bajo la autoridad y dirección de un convenio suscrito originalmente por Costa Rica y los Estados Unidos de América. El convenio, vigente desde 1950, está abierto ala afiliación de cualquier país cuyos ciudadanos pesquen atunes tropicales y especies afines en el Océano Pacifico oriental (OPO). Bajo esta estipulación, la República de Panamá seafilió en 1953, Ecuador en 1961, México en 1964, Canadá en 1968, Japón en 1970, Francia y Nicaragua en 1973, Vanuatu en 1990, Venezuela en 1992, y El Salvador en 1997. México se retiro de la CIAT en 1978, y Canadá en 1984. La CIAT celebró su 58' reunión en San Jose de Costa Rica el 3 y 4 de junio de 1997. (PDF contains 310 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1998

ENGLISH: The Inter-American Tropical Tuna Commission (IATTC) operates under the authority and direction of a convention originally entered into by Costa Rica and the United States. The convention, which came into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas and tuna-like species in the eastern Pacific Ocean (EPO). Under this provision Panama adhered in 1953, Ecuador in 1961, Mexico in 1964, Canada in 1968, Japan in 1970, France and Nicaragua in 1973, Vanuatu in 1990, Venezuela in 1992, and El Salvador in 1997. Canada withdrew from the IATTC in 1984. The 60th meeting of the IATTC was held in La Jolla, California, USA, on February 7, 1998. SPANISH: La Comisión Interamericana del Atún Tropical (CIAT) funciona bajo la autoridad y dirección de un convenio suscrito originalmente por Costa Rica y los Estados Unidos de América. El convenio, vigente desde 1950, está abierto ala afiliación de cualquier país cuyos ciudadanos pesquen atunes tropicales y especies afines en el Océano Pacifico oriental (OPO). Bajo esta estipulación, la República de Panamá seafilió en 1953, Ecuador en 1961, México en 1964, Canadá en 1968, Japón en 1970, Francia y Nicaragua en 1973, Vanuatu en 1990, Venezuela en 1992, y El Salvador en 1997. México se retiro de la CIAT en 1978, y Canadá en 1984. La 60a reunión de la CIAT tuvo lugar el 7 de febrero de 1998. (PDF contains 358 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1999

ENGLISH: The Inter-American Tropical Tuna Commission (IATTC) operates under the authority and direction of a convention originally entered into by Costa Rica and the United States. The convention, which came into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas and tuna-like species in the eastern Pacific Ocean (EPO). Under this provision Panama adhered in 1953, Ecuador in 1961, Mexico in 1964, Canada in 1968, Japan in 1970, France and Nicaragua in 1973, Vanuatu in 1990, Venezuela in 1992, and El Salvador in 1997. Canada withdrew from the IATTC in 1984. The 63rd meeting of the IATTC was held in Guayaquil, Ecuador, on June 8-10,1999. SPANISH: La Comisión Interamericana del Atún Tropical (CIAT) funciona bajo la autoridad y dirección de un convenio suscrito originalmente por Costa Rica y los Estados Unidos de América. El convenio, vigente desde 1950, está abierto ala afiliación de cualquier país cuyos ciudadanos pesquen atunes tropicales y especies afines en el Océano Pacifico oriental (OPO). Bajo esta estipulación, la República de Panamá seafilió en 1953, Ecuador en 1961, México en 1964, Canadá en 1968, Japón en 1970, Francia y Nicaragua en 1973, Vanuatu en 1990, Venezuela en 1992, y El Salvador en 1997. México se retiro de la CIAT en 1978, y Canadá en 1984. La 63a reunión de la CIAT tuvo lugar del 8 al 10 de junio de 1999 en Guayaquil (Ecuador). (PDF contains 184 pages.)

Optimisation of the first principle code Octopus for massive parallel architectures: application to light harvesting complexes

150 p.

Formas inter-comunicacionais em Pedro Nava: o signo verbal e o pictórico

Esta pesquisa, contribuindo para os estudos em Literatura Comparada, evidencia a correlação entre Literatura e Artes Plásticas, que tem sido vista desde a Antigüidade quando ícones da analogia entre o verbal e o pictórico deixaram suas marcas na correspondência entre as artes. Tal correlação atravessou vários períodos da História e continua presente em inúmeras pesquisas, na época contemporânea. Este trabalho examina a especificação teórica de vários escritores relacionados ao tema e enfoca principalmente as formas como Pedro Nava (1903-1984) utilizou os artifícios verbal e pictórico ao lidar com duas artes distintas

Systematic liquidity: commonality and inter-temporal variation in the Portuguese stock market

[EN] The aim of this paper is to study systematic liquidity at the Euronext Lisbon Stock Exchange. The motivation for this research is provided by the growing interest in financial literature about stock liquidity and the implications of commonality in liquidity for asset pricing since it could represent a source of non-diversifiable risk. Namely, it is analysed whether there exist common factors that drive the variation in individual stock liquidity and the causes of the inter-temporal variation of aggregate liquidity. Monthly data for the period between January 1988 and December 2011 is used to compute some of the most used proxies for liquidity: bid-ask spreads, turnover rate, trading volume, proportion of zero returns and the illiquidity ratio. Following Chordia et al. (2000) methodology, some evidence of commonality in liquidity is found in the Portuguese stock market when the proportion of zero returns is used as a measure of liquidity. In relation to the factors that drive the inter-temporal variation of the Portuguese stock market liquidity, the results obtained within a VAR framework suggest that changes in real economy activity, monetary policy (proxied by changes in monetary aggregate M1) and stock market returns play an important role as determinants of commonality in liquidity.

Synthesis of nickel(II) complexes of alpha-isoxazolylazo-beta-diketones and their absorption of spin-coating films and thermal properties for HD-DVD-R

Three kinds of new nickel(II) complexes of alpha-isoxazolylazo-beta-diketones with blue-violet light absorption were synthesized. Their structures were postulated based on elemental analysis, MS and FT-IR spectra. Smooth films on K9 glass substrates were prepared using the spin-coating method. The absorption properties and thermal stability of these complexes were discussed. The static optical recording test for high density digital versatile disc-recordable (HD-DVD-R) system was also studied. (c) 2005 Elsevier B.V. All rights reserved.

Rare earth doped beta-diketone complexes as promising high-density optical recording materials for blue optoelectronics

Some kinds of rare earth beta-diketone complexes with blue-violet light absorption edge were synthesized using the ligands of thenoyltrifluoroacctone (HTTA), 2, 2'-dipyridyl (BIPY) and different metal ions (Gd3+, Sm3+ and La3+). Their contents, structures and optoelectronic parameters were monitored by elemental analysis, MS, IR and UV spectra. The solubility of rare earth beta-diketone complexes in 2, 2, 3, 3-tetrafluoro-1-propanol (TFP) and absorption properties of their films in the region 300-800 nm were measured. The influence on the difference of absorption maximum from rare earth beta-diketone complexes to beta-diketone ligand by different metal ions was studied. In addition, the thermal stability of rare earth beta-diketone complexes was also reported. (C) 2005 Elsevier B.V. All rights reserved.