Synthesis of Hollow Nanotubes of Zn2SiO4 or SiO2: Mechanistic Understanding and Uranium Adsorption Behavior

We report a facile synthesis of Zn2SiO4 nanotubes using a two-step process consisting of a wet-chemical synthesis of core-shell ZnO@SiO2 nanorods followed by thermal annealing. While annealing in air leads to the formation of hollow Zn2SiO4, annealing under reducing atmosphere leads to the formation of SiO2 nanotubes. We rationalize the formation of the silicate phase at temperatures much lower than the temperatures reported in the literature based on the porous nature of the silica shell on the ZnO nanorods. We present results from in situ transmission electron microscopy experiments to clearly show void nucleation at the interface between ZnO and the silica shell and the growth of the silicate phase by the Kirkendall effect. The porous nature of the silica shell is also responsible for the etching of the ZnO leading to the formation of silica nanotubes under reducing conditions. Both the hollow silica and silicate nanotubes exhibit good uranium sorption at different ranges of pH making them possible candidates for nuclear waste management.

Efficient density matrix renormalization group algorithm to study Y junctions with integer and half-integer spin

An efficient density matrix renormalization group (DMRG) algorithm is presented and applied to Y junctions, systems with three arms of n sites that meet at a central site. The accuracy is comparable to DMRG of chains. As in chains, new sites are always bonded to the most recently added sites and the superblock Hamiltonian contains only new or once renormalized operators. Junctions of up to N = 3n + 1 approximate to 500 sites are studied with antiferromagnetic (AF) Heisenberg exchange J between nearest-neighbor spins S or electron transfer t between nearest neighbors in half-filled Hubbard models. Exchange or electron transfer is exclusively between sites in two sublattices with N-A not equal N-B. The ground state (GS) and spin densities rho(r) = < S-r(z)> at site r are quite different for junctions with S = 1/2, 1, 3/2, and 2. The GS has finite total spin S-G = 2S(S) for even (odd) N and for M-G = S-G in the S-G spin manifold, rho(r) > 0(< 0) at sites of the larger (smaller) sublattice. S = 1/2 junctions have delocalized states and decreasing spin densities with increasing N. S = 1 junctions have four localized S-z = 1/2 states at the end of each arm and centered on the junction, consistent with localized states in S = 1 chains with finite Haldane gap. The GS of S = 3/2 or 2 junctions of up to 500 spins is a spin density wave with increased amplitude at the ends of arms or near the junction. Quantum fluctuations completely suppress AF order in S = 1/2 or 1 junctions, as well as in half-filled Hubbard junctions, but reduce rather than suppress AF order in S = 3/2 or 2 junctions.

On the issues of resolving a low melting combination as a definite eutectic or an elusive cocrystal: A critical evaluation

Cocrystals and eutectics are different yet related crystalline multi-component adducts with diverse applications in pharmaceutical and materials fields. Recently, they were shown to be alternate products of cocrystallization experiments. Whereas a cocrystal shows distinct diffraction, spectroscopic and thermal signatures as compared to parent components, the hallmark of a eutectic is its low melting nature. However, in certain cases, there can be a problem when one resorts to design a cocrystal and assess its formation vis-A -vis a eutectic. In the absence of a gold standard method to make a cocrystal, it is often difficult to judge how exhaustive should the cocrystallization trials be to ensure the accomplishment of a desired/putative cocrystal. Further, a cocrystal can manifest with intermolecular interactions and/or crystal structure similar to that of its parent compounds such that the conventional diffraction and spectroscopic techniques will be of little help to conclusively infer the formation of cocrystal in the lack of single crystals. Such situations combined with low melting behavior of a combination brings the complication of resolving the combination as a cocrystal or eutectic since now both the adducts share common features. Based on the curious case of Caffeine-Benzoic acid combination, this study aims to unfold the intricate issues related to the design, formation and characterization of cocrystals and eutectics for a way forward. The utility of heteronuclear seeding methodology in establishing a given combination as a cocrystal-forming one or a eutectic-forming one in four known systems is appraised.

Lereis, o Tántale en “Diálogos de los muertos” 7.2, análisis y traducción

Resumen: En Diálogos de los muertos 7 Menipo de Gádara intenta convencer a Tántalo de que su castigo, el tener sed en el Hades y no poder beber, es una mera ficción. Esta postura del gadarense se manifiesta claramente mediante el empleo del verbo ληρέω para describir el comportamiento de Tántalo (Dmort. 7.2). Lo que intentamos elucidar en el presente trabajo es si, desde la perspectiva de Menipo, dicha ficción se debe a una mentira intencional de Tántalo o a una enfermedad psíquica. De la interpretación que hagamos a este respecto dependerá la traducción del verbo ληρeω como ‘’decir tonterías’’ o ‘’delirar’’.

PICES Press, Vol. 7, No. 2, July 1999

Improving PICES CO2 measurement quality The status of the Bering Sea: July - December 1998 The state of the eastern North Pacific since October 1998 The state of the western North Pacific in the second half of 1998 Paul Henry LeBlond Report on the ICES/SCOR Symposium on Ecosystem Effects of Fishing What is the carrying capacity of the North Pacific Ocean for salmonids? Southeast Bering Sea Carrying Capacity (SEBSCC) The Whole Earth System: The role of regional programs Sub-Arctic Gyre Experiment in the North Pacific Ocean (SAGE) The Alaska Predator Ecosystem Experiment (APEX): An integrated seabird and forage fish investigation sponsored by the Exxon Valdez Oil Spill Trustee Council ICES and GOOS: A progress report Report on GOOS Living Marine Resource Panel Meeting

PICES Press, Vol. 7, No. 1, January 1999

Taking stock and looking to the future - note from former PICES Chairman The state of the western North Pacific in the first half of 1998 The status of the Bering Sea in the first eight month of 1998 The state of the eastern North Pacific since February 1998 Highlights of PICES VII, review of SB activities and future workplan The second PICES Workshop on the Okhotsk Sea and ajacent area PICES-GLOBEC Climate Change and Carrying Capacity Program: A report from PICES VII Data management for the CCCC Program Report on GOOS Living Marine Resource Panel Meeting Photos from PICES VII Vjatcheslav Petrovich Shuntov GLOBEC Canada: Who we are, what we’ve been doing and where we’re headed The Ocean Carrying Capacity Research Program (OCC) at the Alaska Fisheries Science Center, Auke Bay Laboratory, Juneau, Alaska JAMSTEC research activities in the northern North Pacific People and events

"I'm on it 24/7 at the moment" : A qualitative examination of multi-screen viewing behaviours among UK 10-11 year olds

Background: Screen-viewing has been associated with increased body mass, increased risk of metabolic syndrome and lower psychological well-being among children and adolescents. There is a shortage of information about the nature of contemporary screen-viewing amongst children especially given the rapid advances in screen-viewing equipment technology and their widespread availability. Anecdotal evidence suggests that large numbers of children embrace the multi-functionality of current devices to engage in multiple forms of screen-viewing at the same time. In this paper we used qualitative methods to assess the nature and extent of multiple forms of screen-viewing in UK children. Methods: Focus groups were conducted with 10-11 year old children (n = 63) who were recruited from five primary schools in Bristol, UK. Topics included the types of screen-viewing in which the participants engaged; whether the participants ever engaged in more than one form of screen-viewing at any time and if so the nature of this multiple viewing; reasons for engaging in multi-screen-viewing; the room within the house where multi-screen-viewing took place and the reasons for selecting that room. All focus groups were transcribed verbatim, anonymised and thematically analysed. Results: Multi-screen viewing was a common behaviour. Although multi-screen viewing often involved watching TV, TV viewing was often the background behaviour with attention focussed towards a laptop, handheld device or smart-phone. There were three main reasons for engaging in multi-screen viewing: 1) tempering impatience that was associated with a programme loading; 2) multi-screen facilitated filtering out unwanted content such as advertisements; and 3) multi-screen viewing was perceived to be enjoyable. Multi-screen viewing occurred either in the child's bedroom or in the main living area of the home. There was considerable variability in the level and timing of viewing and this appeared to be a function of whether the participants attended after-school clubs. Conclusions: UK children regularly engage in two or more forms of screen-viewing at the same time. There are currently no means of assessing multi-screen viewing nor any interventions that specifically focus on reducing multi-screen viewing. To reduce children's overall screen-viewing we need to understand and then develop approaches to reduce multi-screen viewing among children.

Carmel River Lagoon Enhancement Project: Water Quality and Aquatic Wildlife Monitoring, 2006-7

This is a report to the California Department of Parks and Recreation. It describes water quality and aquatic invertebrate monitoring after the construction of the Carmel River Lagoon Enhancement Project. Included are data that have been collected for two years and preliminary assessment of the enhanced ecosystem. This report marks the completion of 3-years of monitoring water quality and aquatic habitat. The report adopts the same format and certain background text from previous years’ reporting by the same research group (e.g. Larson et al., 2005). (Document contains 100 pages)

A Preliminary Check-List of the Marine Algae of the Moss Landing Jetty: An Annotated Floristic Compilation. Annual Report, Part 7, 1973

(PDF contains 55 pages)

Modelling of the Subarctic North Pacific Circulation (Report of Working Group 7)

This review focuses on modelling ocean circulation and its variability in the subarctic North Pacific; it addresses issues specific to that region, and not the subject of ocean modelling in general. The performance of existing models is assessed in relation to observations in the upper ocean, intermediate waters and deep/abyssal waters. (PDF contains 87 pages)

Oceanographic results from the ONR cruise 1, Lateral Transport Study, 3-7 June 1985

(Document pdf contains 54 pages)