Analysis of biodiesel and frying vegetable oils by means of FTIR photoacoustic spectroscopy

Fourier Transform Infrared Photoacoustic Spectroscopy was used to determine the mid-infrared vibrational modes of biodiesel and vegetable oils. Our results indicate that this method can contribute significantly to the biodiesel wash process during the sample preparation. Besides, by analyzing the spectra of vegetable oils used to fry snacks we could to monitor the degradation in function of the fried time.

Correlações genéticas de características de tamanho corporal e condição corporal com características de eficiência produtiva de fêmeas da raça Canchim

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Biodegradability of diesel and biodiesel blends

The biodegradability of pure diesel and biodiesel and blends with different proportions of biodiesel (2% (commercial); 5% and 20%) was evaluated employing the respirometric method and the redox indicator 2,6-dichlorophenol indophenol (DCPIP) test. In the former, experiments simulating the contamination of natural environments (soil from a petrol station or water from a river) were carried out in Bartha biometer flasks (250 ml), and used to measure the microbial CO 2 production. With the DCPIP test, the capability of three inocula to biodegrade the blends was tested. Results show that although biodiesel is more easily and faster biodegraded than diesel oil, among the blends evaluated (2%, 5% and 20%), only the blend with higher concentration of biodiesel presented biodegradability significantly different from diesel and it was not verified an improvement on the biodegradation of the diesel by means of co-metabolism. © 2008 Academic Journals.

Desempenho dinâmico de um trator agrícola utilizando biodiesel destilado de óleo residual

The objective of this study was to evaluate the dynamic performance of an agricultural tractor utilizing distilled biodiesel (50% ethylic + 50% methylic) as a function of the proportion of biodiesel and diesel of petroleum (0 and 100%, 5 and 95%, 15 and 85%, 25 and 75%, 50 and 50%, 75 and 25% and 100 and 0%), respectively. This research was done in the area of the Department of Rural Engineering of the Paulista State University (UNESP), Jaboticabal Campus, SP, located in the latitude 21° 14′ 28″ S and longitude 48° 17′12″ W. A tractor 4 x 2 FWA was used, with a 73.6 kW (100 HP) motor and a ballast tractor. The biodiesel used was produced from spent oil from food frying. The experimental design was entirely randomized, with 7 treatments and 5 repetitions, totaling 35 observations. The results showed that the biodiesel and diesel blend significantly influenced the hourly volumetric consumption, hourly mass consumption, fuel consumption per worked area and specific fuel consumption variables. When the tractor operated with 100% of biodiesel (B100) the specific fuel consumption increased 18% on average in relation to diesel (B0).

Influence of vegetable oil in the viscosity of biodiesel-a review

Viscosity is a measure fluid resistance to flowing, affecting the fuel spray in the combustion chamber and, by this way, thus the formation of carbon deposits. The analysis of the influence of vegetable oil viscosity in biodiesel seems appropriate, because biodiesel viscosity is a function of vegetable oil. The increase of the fuel viscosity, promoted by biodiesel, has a major impact on the dynamics of jet fuel, increasing its speed and distance of penetration, obtaining therefore an increase in the amount of turbulent movement of the jet and thus an increase in the rate of preparation of the mixture, air-fuel, when adding biodiesel to diesel oil. The negative effect of this higher fuel viscosity is the increase of the wear of the train of gears, cam shaft, and valve push rod of all the injection pumps due to the higher pressure of injection. The viscosity of biodiesel is influenced by the size of its molecule and by the increase of molecule insaturations, is directly related with its origin vegetable oil or fat. This study is a review of the influence of vegetable oils in viscosity of biodiesel. Copyright © 2008 SAE International.

Panorama social da América Latina 2010: documento informativo

Incluye bibliobgrafía

Transformação produtiva com eqüidade: a tarefa prioritária do desenvolvimento da América Latina e do Caribe nos anos 1990

Incluye Bibliografía

A transformaçao produtiva após 20 anos: velhos problemas, novas oportunidades. Síntese

Incluye Bibliografía

Mapeamento institucional e de medidas de política com impacto sobre a inovação produtiva e a diversificação das exportações

Includes bibliography

Biochemical biomarkers in Nile tilapia (Oreochromis niloticus) after short-term exposure to diesel oil, pure biodiesel and biodiesel blends

Fossil fuels such as diesel are being gradually replaced by biodiesel, a renewable energy source, cheaper and less polluting. However, little is known about the toxic effects of this new energy source on aquatic organisms. Thus, we evaluated biochemical biomarkers related to oxidative stress in Nile tilapia (Oreochromis niloticus) after two and seven exposure days to diesel and pure biodiesel (B100) and blends B5 and B20 at concentrations of 0.01 and 0.1mLL -1. The hepatic ethoxyresorufin-O-deethylase activity was highly induced in all groups, except for those animals exposed to B100. There was an increase in lipid peroxidation in liver and gills in the group exposed to the higher concentration of B5. All treatments caused a significant increase in the levels of 1-hydroxypyrene excreted in the bile after 2 and 7d, except for those fish exposed to B100. The hepatic glutathione-S-transferase increased after 7d in animals exposed to the higher concentration of diesel and in the gill of fish exposed to the higher concentration of pure diesel and B5, but decreased for the two tested concentrations of B100. Superoxide dismutase, catalase and glutathione peroxidase also presented significant changes according to the treatments for all groups, including B100. Biodiesel B20 in the conditions tested had fewer adverse effects than diesel and B5 for the Nile tilapia, and can be suggested as a less harmful fuel in substitution to diesel. However, even B100 could activate biochemical responses in fish, at the experimental conditions tested, indicating that this fuel can also represent a risk to the aquatic biota. © 2011 Elsevier Ltd.

Resposta produtiva do feijoeiro comum a diferentes manejos de irrigação

The objective of this work was to analyze the most appropriate management to achieve higher productivity for carioca beans (phaseolus vulgaris) and pearll cultivar. The research was developed in the Demonstrative and Experimental Area of Irrigation (ADEI) of FCAV/UNESP, Campus of Jaboticabal, SP. Four treatments were used: T1- irrigation with base in ETo estimated by the method of Class A pan; T2- irrigations based on the readings of tensiometers installed at 0,20 m and 0,40 m of depth; T3- irrigations carried out with base in ETo estimated by the method of Penman-Monteith and T4- witness. The results were submitted to analysis of variance. To compare the averages the test Turkey was used at 5% of probability. The treatment T3 had smaller applied water depth than the treatments T1 and T2, and also smaller productivity. The conclusion is that the treatments irrigated with larger frequency showed higher production of grains.

Using the electrochemical impedance spectroscopy to characterize carbon steel in biodiesel medium

Electrochemical impedance spectroscopy measurements using two carbon steel electrodes in soybean biodiesel medium, produced by methylic route, were performed in an electrochemical cell that allows positioning the two electrodes face-to-face. To retain the biodiesel between the electrodes and prevent its leakage a porous membrane soaked in biodiesel was used. The amplitude of the AC potential and the area of the electrodes were varied. The linearity between disturbance and response signals was observed for tests when the amplitude of the AC potential was lower than 1500 mV (rms). The electrical resistance of biodiesel dominates the global response and carbon steel presents low corrosion, which is observed only at low frequency, and was confirmed by chemical tests performed in the membrane. In conclusion the electrical resistance of biodiesel can be estimated using electrochemical impedance spectroscopy with two electrodes set up. ©The Electrochemical Society.