Desenvolvimento de métodos analíticos para determinação de fósforo e selênio em amostras biológicas

A determinação de fósforo em amostras de rações e fezes de peixes por espectrometria no visível e de selênio em amostras vegetais de cultura orgânica por espectrometria de absorção atômica em forno de grafite (GFAAS) representa o foco principal do trabalho desenvolvido. O fósforo e o selênio são macro e micronutrientes importantes para a nutrição vegetal e animal, no entanto, se utilizados sem um controle adequado podem poluir o solo e os recursos hídricos, atingindo todo o meio ambiente. Dessa forma, foram desenvolvidos métodos para extração dos analitos que diminuíram significativamente os resíduos químicos produzidos nas determinações de rotina feitas na área de nutrição de plantas e de piscicultura. No caso do fósforo foram otimizados parâmetros físico-químicos para extração desse elemento por ultra-som e posterior quantificação por espectrofotometria no visível. No caso do selênio foram otimizados parâmetros físico-químicos para amostragem em suspensão (slurry) e determinação direta por GFAAS. Os principais parâmetros físico-químicos avaliados e otimizados foram: granulometria da amostra sólida, tempo e potência de sonificação, soluções extratoras, agentes surfactantes para estabilização do slurry; temperatura de pirólise e atomização, tipos de modificadores químicos e volume de amostragem nas determinações de selênio por GFAAS e tempo de reação e relação ao agente cromogênico/volume de amostra nas determinações espectrofotométricas de fósforo. O método de extração por ultra-som foi aplicado na determinação de fósforo biodisponível em amostras de rações de peixes e o método de amostragem em suspensão para a determinação de selênio em amostras de vegetais orgânicos

Diagnóstico ambiental das áreas de expansão urbana do município de Jaguariúna - SP

The spatial chaotic urban growth is an increasing and common problem in Brazilian cities, especially in the State of São Paulo. In order to assist the territorial expansion planning, the present study aimed to conduct the environmental diagnosis of urban expansion areas in the City of Jaguariúna – SP, bounded by the Municipal Plan. From the preparation and analysis of thematic maps, literature review and field analysis, data were collected for use and occupation, geology, geomorphology, pedology, vegetation, water resources and features surrounding the five urban sprawl existing areas. It was noted, in general, that these areas are suitable for urban occupation, since they show flat geomorphology characteristics, with flattened, medium to large hills, slightly undulated, with low slope, and soils that do not present risks to the deployment of buildings, once properly managed. It was also observed a few water bodies crossing these areas and a few areas with native vegetation beyond permanent protection areas along the rivers. By the analysis of these areas and their surroundings, it was possible to determine on which area the urbanization process can occur more quickly. Thus, the study allows the City of Jaguariúna to perform a more effective occupation planning in these areas, always aiming the sustainable development and, consequently, the improvement in population’s quality of life, as well as the maintenance of environmental quality.

Consumo e incorporação de água na produção de commodities brasileiras

Water is one of the main inputs in agribusiness and is traded indirectly through the sale of agricultural products such as orange (juice or fresh) and cane sugar (ethanol and refined sugar). This study aims to estimate the proportional mass of water present in the products exported in the form of agricultural commodities considering the amount of water incorporated into the product in its genesis by plant photosynthesis, reinforcing a reflection on virtual and real water export, as well to indicate subsidies to management, planning and taxing of water resources

Diagnóstico dos riscos e impactos ambientais da suinocultura no Ribeirão dos Pinheirinhos, município de Torrinha, (SP)

The porcine activity is characterized by its great pollution capacity, generally produce loads of waste that usually are released in superficial water or soil without concern for the consequences to the environment. With this in mind, this study aimed to adjust the porcine production to the protection of water resources, in particular, Ribeirão dos Pinheirinhos in the town of Torrinha (SP), through inventory and diagnosis of the environmental impacts already present and environmental hazards linked to the activity in question. To achieve the proposed objectives, the productions of porcine on the studied area were raised and georeferenced, viewed and analyzed according to the technical and scientific literature. The production visited showed to be at odds with the protection of water resources due to lack of technical criteria in the development of treatment systems and waste handling, indiscriminate use of effluent and waste in the fertilization of crops and the lack of knowledge of producers on the influence of porcine waste into the environment. Based on these results, were set guidelines for action in the environmental awareness of farmers, to stimulate voluntary and conscious initiatives of environmental conservation in the direction of settlement of the activity.

Planejamento ambiental da Bacia Hidrográfica do Córrego da Olga, UGRHI Pontal do Paranapanema – São Paulo: inventário e diagnóstico

This work, presented in order to obtain the environmental engeneer title, is to raise the current status of environmental conditions in the watershed of the stream of Olga and thus contribute to environmental planning for the recovery, conservation and preservation. To this end, we conducted literature surveys and survey of the characteristics of the watershed, analysis of water fron stream of Olga and making use of remote sensingand of the soil, environmental fragiityand spatialization of APPs in order to carry out further research on the environmental conditions of the basin, as well as inferences about possible causes of degradation of watershed.Most of the basin of the stream Olga had a high environmental fargility and the main problem was the lack of riparian vegetation is also considered the cause of environmental problems of the watershed.The results will be available to municipal governments in order to contribute to their planning and management of UGRHI the teh watershed pertence

Avaliação das ocorrências de nitrato e fluoreto nas águas subterrâneas do Estado de São Paulo

Concerns about the quality of groundwater have been continuously rising, considering its importance for the public water supply in the State of São Paulo, and even more due to the impact that anthropic action has been causing to the original quality of that natural resource. It is extremely relevant to identify the contamination focuses along the aquifers of the State of São Paulo. This report aims to evaluate nitrates and fluorides concentrations along the aquifers present in the state, in order to identify places where change in the quality of groundwater is observed, through the comparison between measured concentrations and reference values, such as: “Intervention Value” (maximum allowed value) and “Alert Value” (attention required value). To perform this research, a full compilation and organization has been done on chemical analysis data from the “Sistema de Informações de Águas Subterrâneas - SIDAS”, made available by the “Divisão de Procedimentos de Outorga – DPO” of the “Departamento de Água e Energia Elétrica – DAEE”. This work has made possible the build-up of a database composed by 6,860 wells, with analytical data ready to be interpreted, containing information about water pH, electrical conductivity, hardness and chloride, iron, fluoride, nitrogen, nitrates and total dissolved solids concentrations. This database shows concentration data for nitrates (6,157 wells) and fluoride (3,316 wells). From this information, maps for nitrates and fluorides concentration distributions have been made, by each aquifer and each “Unidade de Gerenciamento de Recursos Hídricos – UGRHI”, which has enabled the identification of wells where the concentrations of these chemical compounds exceeds the reference values. Concerning nitrates, these analysis indicated the existence of contamination sources from rural and urban zones, mostly present in the west region... (Complete abstract click electronic access below)

Análise da dinâmica do uso da terra e sua interferência em enchentes na área urbana do município de Americana (SP)

Due to an intense process of population growth and urban density in Americana (SP), mainly due to the development of the local textile industry after 1970, there was, concomitant to the occupation of the margin of rivers and streams, soil sealing that increased the level of superficial runoff, triggering frequent floods. Based on the analysis of these processes we investigate the conditions of one densely urbanized area of the county, the Córrego do Parque, in three time series, 1977, 1996 and 2008. Taking as the starting the characterization and spatial distribution of landscape physiography, we prepared thematic letters and synthetic maps digital scale 1:10,000 from photointerpretation of aeroframes. The thematic maps were produced by scanning with subsequent edition using the software Auto-Cad Map. Checking the data and of geographic coordinates with GPS (Global Positioning System). Regarding land use classes, we used the description of the Soil Conservation Service (1975) which allowed us to get the Curve Number parameter, which will be used in hydrologic modeling for verification of flooding (Tucci, 1989). For the process of hydrologic modeling, we used models based on Methodology Object Oriented Modeling Applied to Water Resource Systems, Viegas Filho (1999), using the computer program called IPHS1, which uses models of the Soil Conservation Service (SCS , 2004), for conversion of rainfall-runoff and the spread of excessive rain. The results indicate that increased waterproofing generated by the change in use and occupation over the past decades promoted the increased surface runoff and drainage system overload, increasing the intensity of floods

Planejamento ambiental da bacia do Balneário da Amizade – São Paulo

Esta monografia esta relacionado à pesquisa de iniciação científica inserida no Grupo de Pesquisa em Gestão Ambiental e Dinâmica Socioespacial (GADIS), da Faculdade de Ciências e Tecnologia, UNESP, campus de Presidente Prudente, e vincula-se a projetos mais amplos desenvolvidos com apoio da FAPESP, do CNPq e FEHIDRO. De modo geral, este trabalho possui o objetivo de contribuir para o planejamento ambiental da bacia do Balneário da Amizade, como também para o gerenciamento de seus recursos hídricos, aprofundando conhecimentos teórico-metodológicos sobre o tema. Os procedimentos metodológicos seguem a proposta de Rodriguez (1994) adaptada por Leal (1995), na qual incluem etapas de elaboração do Inventário, Diagnóstico Ambiental, Prognóstico e Propostas, de modo a identificar as características de uso e ocupação da bacia do Balneário da Amizade, mapear seus principais problemas ambientais e elaborar propostas visando sua recuperação ambiental e a preservação de seus recursos hídricos, além de analisar políticas públicas direcionadas para a bacia. A importância desta pesquisa se inicia com a escolha da área de estudo, já que a mesma é uma importante bacia hidrográfica para os municípios de Presidente Prudente e Álvares Machado... (Resumo completo, clicar acesso eletrônico abaixo)

Contribuição das águas subterrâneas para a vazão do Ribeirão Boa Vista ou Córrego do Lajeado

This paper aimed to give a contribution to improve water resources management, consists of the analysis of interaction among groundwater and streamflow, by through the analysis of the relationship between basic and total streamflow, based on measured hidrological data from Ribeirão Boa Vista or Córrego Lajeado. watershed. Comparisons among groundwaterflow in this basin with another one in Rio Corumbataí basin were made based on the specific basic flow, in order to verify the possibility of the utilization of measured hydrological data in other basins with similar geological characteristics and soil use and occupation. Based upon the comparisons that were made, specific basic flow does not represent a good tool for extrapolation of measured data, indicating that this comparison shall be weighted by others characteristics as permeability and thickness of geological formations. Finally, it was possible to conclude that basic flow may be considered as an additional parameter for analysis of hydrological and hydrogeological characteristics of a basin and to provide subsidies to release legal licenses for water resources uses. related to surface water as well as for groundwater and may also be used as a tool for consolidation of integrated management of water resources, that is considered as a necessary and essential practice to avoid conflicts between users of water resources in a river basin.

Estudo comparativo de modelos matemáticos de qualidade de águas superficiais

Surface water quality models have been developed since 1925, when Streeter e Phelps created first order equations that represent the balance between DO and BOD. Since then, and specially after the ‘60s, new computational technologies evolved, making it possible to create more complex models, which try to represent, through mathematics, natural phenomena like eutrophication and rivers self-depuration. As main objective of such models is the understanding of aquatic systems and the relationship between them and the environment, so that it can support decision makers in creating water manage plans and in elaborating environmental projects of such resources. Regarding to that, it is of crucial importance the understanding of the models structures, so that one can choose the most appropriate model for the river in question. While one-dimensional models like QUAL2K are more appropriate for long and narrow rivers, bi- or tridimensional models (CE-QUAL-W2, WASP and CEQUAL- ICM) are more commonly used in wide and slower rivers, with higher lateral and/or vertical mixes rates. Besides, the more complex is the river studied more complex the model should be, which demands more costs and time for the model to be applied

Indicação e avaliação de potenciais áreas para implementação de aterros sanitários municipais – Apuí/AM

About eighty percent of the Brazilian municipalities have their residues in environmentally unsuitable sites and socially insalubrious. In this context, in the year 2010, instituted the National Policy on Solid Residues, which aims to integrated management and management environmentally appropriate of solid residues in Brazil (JUCA, 2002).The problem of urban residues is related to its origin and production in the same way that the concept of inexhaustibility and reflexes of compromising the environment, especially the pollution of soil, air and water resources (LIMA, 1995). Seeking a better residues management in the municipality of Apuí / AM and continuing work already started, Plan Solid Residues Management of the Apuí / AM, this work came to propose a better environmental compliance in relation to solid residues compared to 12305/2010 law that established deadlines / timelines on some actions such as landfills and the consequent elimination of environmentally sound disposal of residues by 2014 and thus began a study of potential areas for the implementation of the landfill were evaluated taking into consideration technical aspects (soil, vegetation, climate, hydrography, etc), legislation and Google Earth imagery. The result of the work over the 6 areas proposed by the City Hall was the choice of AREA 4 as the most indicated for the implementation of the landfill for the city of Apuí, which has 18,325 inhabitants (IBGE, 2011); some considerations were made if a new area can be proposed by the city to implement the landfill

Avaliação da membrana P81 como agente ligante da técnica de difusão em filmes finos por gradiente de concentração (DGT) para determinação de mercúrio em sistemas aquáticos

Worldwide environmental degradation is an undesirable byproduct resulting from the increasing demand for natural resources. Water sources are suffering intense contamination since they usually receive a huge amount of domestic and industrial effluents - which are mostly wasted without proper treatment - inserting a large number of pollutants in the environment, heavy metals included. Mercury holds great toxicological importance because, under some physicochemical conditions in a water environment, Hg (II) ion turns into methylated compounds stemming from this element, such as methylmercury CH3Hg, which is highly toxic for the aquatic community in which bioaccumulation occurs. Nowadays passive sampling techniques are being developed to enable the analytical procedures which are applied in environmental monitoring. Diffusive gradients in thin-films technique (DGT) has been proven an interesting tool for the determination of labile metal species due to its in situ application. The DGT technique consists of a piston-like device on which the following series of agents is disposed: a binding agent (conventionally Chelex 100 resin), a diffusive agent, usually a polyacrylamide gel, and a membrane filter. Nevertheless, the agents conventinally used for this technique don't usually show satisfactory results in mercury sampling. The main goal of this study was to evaluate the phosphate-treated cellulose membrane (Whatman P 81), an alternative material, as binding agent in the DGT to determine labile mercury fractions in aquatic systems. In this context, we conducted a study of the behavior of this material in relation with system variables, pH and ionic strength. Afterwards we performed immersions of the DGT devices in real and enriched samples and in situ aiming the determination of mercury

Cádmio, chumbo, cromo, mercúrio e níquel nos rios do estado de São Paulo e em peixes do Rio Sorocaba (São Paulo, Brasil)

To verify the levels of concentration of some heavy metals in fishes from Sorocaba river (São Paulo, Brazil) and evaluate if this contamination offers health risks to the fishermen, 63 samples of fishes collected from four points along the river were studied for cadmium, lead, chromium, nickel and mercury, with emphasis in this last, since it is the most toxic and most probable as a fish contaminant. Analyzing muscle samples by cold vapor atomic absorption spectrometry it was shown that the fishes are not contaminated. None of the five metals studied were present in prohibitive level and the fishes could be judged secure for human consume. It was also analyzed data from four years of cadmium, lead, chromium, nickel and mercury monitoring made by CETESB, from 1997 to 2000, in water from the main rivers of the State of São Paulo. The study pointed out that the majority of the monitored rivers still present contamination by those metals in a level that requires an improvement of the pollution control actions.

Ações de educação ambiental para conservação e preservação do Córrego Bela Vista, Piacatu-SP

Pós-graduação em Geografia - FCT

Utilização do cavaco de madeira como combustível alternativo para a produção de vapor de água em uma caldeira aquatubular com grelha fixa do tipo PIN HOLE

The steady increase in the price of oil and its derivatives, carbon credits, the concern with the environment combined with the precipitation of rain water and lack of water resources that Brazil has suffered in 2014 caused a migration of participation sources of energy in the Brazilian energy matrix. The hydropower sector suffered big drop at 2013 and is suffering so far, contributing thus to the generation and cogeneration of thermal energy using renewable energy sources such as: sugarcane bagasse, wood chips, rice husks, among others. The selling price of the electricity market reached the level of R$ 807, 00 MWh in January 2014 (Source: ANEEL), heating the Brazilian thermoelectric sector. Although thermoelectric use in bulk water as vaporizing fluid to produce electricity and use in various processes, water reuse plans have become an important factor in these industries. The increased use of biomass has been the bagasse which is allied to the sugarcane sector, strong market in Brazil, and consists basically use the rest of sugar cane, sugarcane industries that would play out. The sugar and ethanol industry is very unstable and only lasts for 6-8 months a year, and the remaining time in the period known as between crop that corresponds to the planting and harvesting of sugarcane and then enter the period of vintage which is the constant cane harvesting and crushing it. This instability of the market and the thermoelectric idle period leads the thermoelectric industries to seek other sources of renewable energy, such as wood chips (pine, Eucalyptus, Orange), rice husk, sorghum among others, to not be dependent on alcohol sector. The present work aims to study the use of wood chips as an alternative biomass for burning a fuel that essentially uses bagasse, the thermoelectric in question consists of two boilers that produce together 350 t / h ... (Complete Abstract click electronic access below)