改进的SILAR法制备ZnO薄膜及其表征

A modified solution method, successive ionic layer adsorption and reaction(SILAR), was applied to prepare transparent zinc oxide(ZnO) film on glass substrate at (125±5) ℃ in mixed ion precursor solution. The surface morphology and crystallizations of films were analyzed by field emission scanning microscopy(FESEM) and X-ray diffraction(XRD), respectively. The optical properties of the films were studied by ultraviolet visible(UV-Vis)spectroscopy. The results show that the obtained samples are polycrystallin...中文文摘：采用一种改进的液相成膜技术——连续离子层吸附与反应(SILAR)法,用锌氨络离子[Zn(NH3)4]2+溶液作为独立的前驱体溶液,以载玻片为衬底,在(125±5)℃的温度下沉积出致密、透明的ZnO薄膜。分别用冷场发射型扫描电镜(FESEM)和X射线衍射(XRD)分析了薄膜样品的表面形貌和结晶状态,用紫外-可见分光光度计(UV-Vis spectroscopy)研究了薄膜样品的发光性能。结果表明:获得样品为六角纤锌矿结构的多晶薄膜材料沿[002]方向择优生长;样品表面均匀、致密,厚度约为550nm;在可见光波段具有高的透射率(>80%)。

高计数率下的四路反堆积放大电路

A quadruple rejected-pile up amplifier used for high counting rate up to 105/s of average counting rate was described in this paper.To meet the need of high counting rate,the baseline regulation fuction,rejected pile up fuction was designed in the amplifier and the mark of rejected pile up was given for treatment of successive circuits.The quadruple amplifier consisting of four same circuits was assembled in one single NIM modul.These circuits have the advantages of compact construction,small volume and sta...中文文摘：介绍一种在高计数率情况下的反堆积放大器,它允许通过的平均计数为105/s。该放大器为了适应高计数率的要求,设计了基线调节功能和反堆积功能,给出了堆积标志,以便后继电路的处理。该电路在一个单宽NIM插件中有完全相同的四路电路工作,结构紧凑,体积小,工作性能稳定。

Theoretical investigation on excitation, ionization and capture in H(1s, 2s)+H(1s, 2s) collisions

Cross sections of electron- loss in H( 1s)+ H( 1s) collisions and total collisional destruction of H( 2s) in H( 1s) + H( 2s) collisions are calculated by four- body classical- trajectory Monte Carlo ( CTMC) method and compared with previous theoretical and experimental data over the energy range of 4 - 100 keV. For the former a good agreement is obtained within di. erent four- body CTMC calculations, and for the incident energy Ep > 10 keV, comparison with the experimental data shows a better agreement than the results calculated by the impact parameter approximation. For the latter, our theory predicts the correct experimental behaviour, and the discrepancies between our results and experimental ones are less than 30%. Based on the successive comparison with experiments, the cross sections for excitation to H( 2p), single- and double- ionization and H- formation in H( 2s)+ H( 2s) collisions are calculated in the energy range of 4 - 100 keV for the. rst time, and compared with those in H( 1s)+ H( 1s) and H( 1s)+ H( 2s) collisions.

纳秒激光诱导C60分子碎裂中轻碎片离子C+n(n＜30)的产生机理研究

The time of flight mass spectrometric technique was used to determine the initial mean kinetic energy of small fragment ions C-n(+) (n <= 11) produced from C-60 excited by 532 nm nanosecond laser pulses. The measured kinetic energy shows little variation with the fragment mass and the laser fluence in a broad range. Based on the assumption that C-30(+) is produced predominantly by a single electron emission followed by successive C-2 evaporation from hot C-60 in the nanosecond laser field, the formation of small fragments is interpreted as the complete breakup of the unstable C-30(+) cage structure. The interpretation is consistent with the previously observed results.

Commissioning test of LAPECR2 source on the 320kV HV platform

The high charge state all permanent Electron Cyclotron Resonance Ion Source (ECRIS) LAPECR2 (Lanzhou All Permanent magnet ECR ion source No.2) has been successfully put on the 320kV HV platform at IMP and also has been connected with the successive LEBT system. This source is the largest and heaviest all permanent magnet ECRIS in the world. The maximum mirror field is 1.28T (without iron plug) and the effective plasma chamber volume is as large as circle divide 67mm x 255mm. It was designed to be operated at 14.5GHz and aimed to produce medium charge state and high charge state gaseous and also metallic ion beams. The source has already successfully delivered some intense gaseous ion beams to successive experimental terminals. This paper will give a brief overview of the basic features of this permanent magnet ECRIS. Then commissioning results of this source on the platform, the design of the extraction system together with the successive LEBT system will be presented.

Excitation and dissociation of tungsten hexacarbonyl W(CO)(6): Statistical and nonstatistical dissociation processes

We have studied the excitation and dissociation processes of the molecule W(CO)(6) in collisions with low kinetic energy (3 keV) protons, monocharged fluorine, and chlorine ions using double charge transfer spectroscopy. By analyzing the kinetic energy loss of the projectile anions, we measured the excitation energy distribution of the produced transient dications W(CO)(6)(2+). By coincidence measurements between the anions and the stable or fragments of W(CO)(6)(2+), we determined the energy distribution for each dissociation channel. Based on the experimental data, the emission of the first CO was tentatively attributed to a nonstatistical direct dissociation process and the emission of the second or more CO ligands was attributed to the statistical dissociation processes. The dissociation energies for the successive breaking of the W-CO bond were estimated using a cascade model. The ratio between charge separation and evaporation (by the loss of CO+ and CO, respectively) channels was estimated to be 6% in the case of Cl+ impact. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3523347]

Sn-modified Pt/SAPO-11 catalysts for selective hydroisomerization of n-paraffins

The hydroconversion of n-paraffins is a key reaction in hydrodewaxing of lubricating base oil. In this paper, we investigate the performance of Pt/SAPO-11 catalysts for isomerization of n-paraffins by the model compound of n-dodecane. Under this experimental condition, yields of feed isomers as well as cracking products are a function of the total n-dodecane conversion. Primary products are methylundecane while multi-brancheds and cracking products are formed in successive reactions. The result shows that the addition of Sn increases the selectivity for isomerization reaction. The most ideal experimental data for hydroconversion of n-dodecane is that the selectivity of isomerized products gets 90% when conversion of n-dodecane is 90% for the Sn-promoted Pt/SAPO-11 catalyst.

Effect of addition of Zn on the catalytic activity of a Co/HZSM-5 catalyst for the SCR of NOx with CH4

The selective catalytic reduction (SCR) of NOx by methane in the presence of excess oxygen was studied on a Zn-Co/HZSM-5 catalyst. It was found that the addition of Zn could improve effectively the selectivity of methane towards NOx reduction. When prepared by a coimpregnation method, the Zn-Co/HZSM-5 catalyst showed much higher catalytic activity than the two catalysts of a Zn/Co/HZSM-5 and Co/Zn/HZSM-5 prepared by the successive impregnation method. It is considered that there exists a cooperative effect among the Zn, Co and zeolite, which enhances the reduction of NO to NO2 reaction and the activation of methane. (C) 2002 Elsevier Science B.V. All rights reserved.

Migration of large-scale subaqueous bedforms measured with seagrasses(Cymudocea nodesa) as tracers

The vertical growth of seagrasses in response to burial by migration of bedforms is combined with dating techniques to provide precise and rapid estimates of the migration speed of subaqueous dunes over seagrass patches. Two methods to estimate the time interval between the passage of successive dunes and the motion of single dunes through seagrass patches are described. The second method is more precise. The application of these methods to vegetated (Cymodocea nodosa) subaqueous dunes in the Alfacs Bay (NW Mediterranean) showed that the dunes traveled at an average speed of $13.0 \pm 0.6 m yr^-1$ and demonstrated that the methods can resolve migration speeds from 0.15 to $980 m yr^-1$ with this particular seagrass species. In areas vegetated with different seagrass species, bedform migration can be estimated over different time scales. The strong coupling between seagrass and sediment dynamics resembles the coupling of vegetation and land dunes.

The effects of sediment transport on grain-size distributions

Changes in statistics (mean, sorting, and skewness) describing grain-size distributions have long been used to speculate on the direction of sediment transport. We present a simple model whereby the distributions of sediment in transport are related to their source by a sediment transfer function which defines the relative probability that a grain within each particular class interval will be eroded and transported. A variety of empirically derived transfer functions exhibit negatively skewed distributions (on a phi scale). Thus, when a sediment is being eroded, the probability of any grain going into transport increases with diminishing grain size throughout more than half of its size range. This causes the sediment in transport to be finer and more negatively skewed than its source, whereas the remaining sediment (a lag) must become relatively coarser and more positively skewed. Flume experiments show that the distributions of transfer functions change from having a highly negative skewness to being nearly symmetrical (although still negatively skewed) as the energy of the transporting process increases. We call the two extremes low-energy and high-energy transfer functions , respectively. In an expanded sediment-transport model, successive deposits in the direction of transport are related by a combination of two transfer functions. If energy is decreasing and the transfer functions have low-energy distributions, successive deposits will become finer and more negatively skewed. If, however, energy is decreasing, but the initial transfer function has a high-energy distribution, successive deposits will become coarser and more positively skewed. The variance of the distributions of lags, sediment in transport, and successive deposits in the down-current direction must eventually decrease (i.e., the sediments will become better sorted). We demonstrate that it is possible for variance first to increase, but suggest that, in reality, an increasing variance in the direction of transport will seldom be observed, particularly when grain-size distributions are described in phi units. This model describing changes in sediment distributions was tested in a variety of environments where the transport direction was known. The results indicate that the model has real-world validity and can provide a method to predict the directions of sediment transport

陕北黄土丘陵沟壑区城郊农村土地利用变化定量分析

以典型黄土丘陵沟壑区——延安市赵庄村为例,选取土地利用动态度、土地利用趋势状态指数、土地利用景观指数等指标,对村庄尺度上的土地利用变化进行了定量分析。结果表明,6 a来,研究区土地利用发生了较大的变化,主要以耕地的减少和未利用土地的增加等变化为主;未利用土地、居住及建设用地、林地、灌草地以不同程度增加,其动态度大小依次为43.92%,15.35%,0.33%,0.17%;而耕地、果园、水域则以不同程度减小,动态度大小依次为7.45%,3.79%,0.20%;耕地、果园、水域呈"落势"状态,而未利用土地、居住及建设用地、林地、灌草地呈"涨势",朝着规模增大的趋势发展;斑块数与斑块密度增加,优势度指数与偏离度指数减小,多样性指数、均匀度指数和破碎度指数都有不同程度的增大。

子午岭林区典型植被下土壤结构及稳定性指标分析

运用分形理论,研究了子午岭林区5种天然次生植被(以6 a天然恢复弃耕地为对照)下土壤结构特征,分析了土壤水稳性团聚体分维、孔隙分维、平均重量直径等3个指标在描述土壤结构稳定性方面的差异。研究表明,相对于弃耕地,各个植被群落均能明显改善土壤结构,降低土壤水稳性团聚体分形维数,提高孔隙分形维数,增强土壤结构的稳定性。土壤水稳性团聚体分维、孔隙分维与>0.25 mm水稳性团聚体含量、土壤有机碳、容重的相关系数均达到了极显著水平,均能作为评价土壤结构稳定性的指标;而团聚体平均重量直径与土壤有机碳含量、容重相关性不显著,只与>5 mm团聚体含量和>0.25 mm团聚体含量有极显著正相关关系,因此,仅可作为大团聚体含量的评价指标。

黄土丘陵区农业生态安全评价指标体系初探

以纸坊沟流域为例,构建了黄土丘陵区流域农业生态安全评价指标体系。依据该流域近70 a来的农业生态安全状况,将该流域生态经济系统演变过程划分为4个阶段。从这4个阶段入手分析影响农业生态安全的主要因子,得出了一系列评价指标。结合选取指标的科学性、动态性、实用性等基本原则,参考压力—状态—响应(PSR)模型和多位专家的建议,进一步筛选、分类和确定评价指标,从而建立了一套由生态环境、社会经济、综合功能3大类,20个具体指标构成的适宜于黄土丘陵区的农业生态安全评价指标体系。

黄土高原旱塬农田生态系统碳氮循环特征

以黄土高原南部长武试区的典型旱塬农田生态系统为研究对象,运用DNDC模型分析其麦田在4种处理下连续6年的碳(C)、氮(N)循环特征,经与已知试验结果和实测数据比较,验证了该模型的适用性,并提出了该区农业发展的主要措施。