Spectroscopic investigation and thermal behavior of new carbonyl complexes [M(CO)(4)(N-N)(CuX)], (M = W, Mo; N-N=2,2 '-bipyridine, 1,10-phenanthroline; X = Cl, SCN)

M(CO)(4)(N-N)] reacts with CuCl to give new heterobimetallic metal carbonyls of the type [M(CO)(4)(N-N)(CuCl)], M = W, Mo; N-N = 2,2'-bipyridine (bipy), 1,10-phenanthroline (phen). Reactions of [M(CO)(4)(N-N)(CuCl)] with NaSCN produced the series of complexes of general formula [M(CO)(4)(N-N)(CuSCN)]. The i.r. spectral of all the bimetallic carbonyls exhibited the general four m ( CO) band patterns of the precursors. The u.v.-vis. spectral data for precursors and products showed bands associated with pi --> pi* (nitrogen ligands), d-->d (intrametal), as well as MLCT d-->pi* (nitrogen ligands) and MLCT d --> pi*(CO) transitions. The [M(CO)(4)(N-N)(CuX)] (X = Cl, SCN) emission spectra showed only one band associated with the MLCT transition. The t.g. curves revealed a stepwise loss of CO groups. The initial decomposition temperatures of the [M(CO)(4)(N-N)(CuX)] series suggest that the bimetallic compounds are indeed thermally less stable than their precursors, and the X- ray data showed the formation of MO3, CuMO4, Cu2O and CuO as final decomposition products, M = W, Mo. The spectroscopic data suggests that the heterobimetallic compounds are polymeric.

Improvement of the Mo/TiO2-Al2O3 catalyst by the control of the sol-gel synthesis

Traditional hydrotreating catalysts are constituted by molybdenum deposited on Al2O3 promoted by nickel and phosphorous. Several studies have shown that TiO2-Al2O3 mixed oxides are excellent supports for the active phases. Results concerning the preparation, characterization and testing of molybdenum catalyst supported on titania-alumina are presented. The support was prepared by sol-gel route using titanium and aluminum isopropoxides, the titanium one chelated with acetylacetone (acac) to promote similar hydrolysis ratio for both the alcoxides. The effect of nominal molar ratio [Ti]/[Ti+Al] on the microstructural features of nanometric particles was analyzed by X-Ray Diffraction, N-2 Adsorption Isotherms and Transmission Electron Microscopy. The catalytic activity of Mo impregnated supports was evaluated using the thiophene hydrodesulfurization at different temperatures and atmospheric pressure. The pores size distribution curve moves from the micropores to the mesopores by increasing the Ti contents, allowing the fine tuning of average size from 2.5 to 6 nm. Maximal (367 m(2).g(-1)) and minimal (127 m(2).g(-1)) surface area were found for support containing [Ti]/[Ti+Al] ratio equal to 0.1 and 1, respectively. The good mesopore texture of alumina-titania support with [Ti]/[Ti+Al] molar ratio between 0.3 and 0.5 was found particularly valuable for the preparation of well dispersed MoS2 active phase, leading to HDS catalyst with somewhat higher activity than that prepared using a commercial alumina support.

Development of Ti-Mo alloys for biomedical applications: Microstructure and electrochemical characterization

Ti-Mo alloys from 4 to 20 Mo wt.% were arc-melted. Their compositions and surfaces were analyzed by EDX, XRF and SEM. The Mo mapping shows a homogeneous distribution for all alloys. The XRD analysis showed that the crystal structure of the alloys is sensitive to the Mo concentration; a mixture of the hexagonal alpha' and orthorhombic alpha '' phases was observed for the Ti-4Mo alloy, and the alpha '' phase is observed almost exclusively when the concentration of Mo added to the Ti reaches 6%. A significant retention of the beta phase is observed for the alloy containing 10% Mo, while at higher Mo concentrations (15% and 20%), retention of phase beta is only verified. Preliminary electrochemical studies have indicated a valve-metal behavior and good corrosion resistance in aerated Ringer solution for all alloys. (c) 2006 Published by Elsevier B.V.

Estudio de la pasivacion de la aleacion Co-Cr-Mo en suero fisiologico

Results are presented on the mechanism of passivation of Co-Cr-Mo biological implant alloys in physiological serum using open circuit potentiometry, potentiodynamic curves, and electrochemical impedance spectroscopy. The potential dependence of impedance data and the analysis of the parameters obtained indicate a progressive diminution of the initial layer thickness and the simultaneous formation of a second higher resistive layer. In more severe conditions than the existent in human body, the metallographic examination of the alloy surface shows localized corrosion in interdendritric regions. Elemental analysis of the surface reveals the presence of higher chromium content in these regions. The presence of chlorine was not detected, which suggested that during preferential attack, soluble species are also formed.

Investigation of the metal/porcelain interface in LASER-welded Ni-Cr-Mo alloy

The interface formed between the metal and the porcelain of laser-welded Ni-Cr-Mo alloy was studied on a metallurgical basis. The characterization was carried out by using optical microscope, electron scan microscopy and X-ray dispersive spectroscopy techniques and mechanical three-point flexion tests, in the laser-welded region, with and without porcelain. The union of the porcelain with the alloy is possible only after the oxidation of the metallic surface and the subsequent application of a bonding agent known as opaque. The porcelain applied to the base metal and weld bead showed different behaviours - after the flexion test, the base metal showed cracks, while that in the weld bead broke away completely. It was noted that the region subjected to laser welding had lower adherence to the porcelain than the base metal region, due to microstructural refinement of the weld bead. These results can be shown by the X-ray dispersive spectroscopy carried out on the regions studied. The flexion tests demonstrated that the Ni-Cr-Mo alloy subject to laser welding had significant alterations in its mechanical properties after application of the porcelain.

Effect of molybdenum on the formation of Ti6Si2B in mechanically alloyed Ti-Mo-Si-B powders

This paper discusses on effect of molybdenum on the Ti6Si2B formation in mechanically alloyed and hot-pressed Ti-xMo-22Si-11B (x= 2, 5, 7 and 10 at%) alloys. High-energy ball milling and hot pressing were utilized to produce homogeneous and dense materials, which were characterized by scanning electron microscopy, X-ray diffraction, electron dispersive spectrometry, and Vickers hardness. The excessive agglomeration during milling was more pronounced in Moricher powders, which was minimized with the formation of brittle phases. Hot pressing of mechanically alloyed Ti-xMo-22Si-11B powders produced dense samples containing lower pore amounts than 1%. Ti6Si2B was formed in microstructure of the hot-pressed Ti-2Mo-22Si-11B alloy only. In Mo-richer quaternary alloys, the Ti3Si and Ti5Si3 phases were preferentially formed during hot pressing. Oppositely to the ternary phase, the Ti3Si phase dissolved a significant Mo amount. Vickers hardness values were reduced in hot-pressed Ti-xMo-22Si-11B alloys containing larger Mo amounts, which were dissolved preferentially in Ti solid solution. © (2012) Trans Tech Publications, Switzerland.

Biomedical Ti-Mo Alloys with Surface Machined and Modified by Laser Beam: Biomechanical, Histological, and Histometric Analysis in Rabbits

Purpose: In vivo bone response was assessed by removal torque, hystological and histometrical analysis on a recently developed biomedical Ti-15Mo alloy, after surface modification by laser beam irradiation, installed in the tibia of rabbits. Materials and Methods: A total of 32 wide cylindrical Ti-15Mo dental implants were obtained (10mm × 3.75mm). The implants were divided into two groups: 1) control samples (Machined surface - MS) and 2) implants with their surface modified by Laser beam-irradiation (Test samples - LS). Six implants of each surface were used for removal torque test and 10 of each surface for histological and histometrical analysis. The implants were placed in the tibial metaphyses of rabbits. Results: Average removal torque was 51.5Ncm to MS and >90Ncm to LS. Bone-to-implant-contact percentage was significantly higher for LS implants both in the cortical and marrow regions. Conclusions: The present study demonstrated that laser treated Ti-15Mo alloys are promising materials for biomedical application. © 2011 Wiley Periodicals, Inc.

Estudo da eletrocatálise da reação de oxidação de etanol sobre fases intermetálicas ordenadas Pt-M (M = Mn,Mo, Pb, Sb e Sn)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Estudo da eletrocatálise das reações de oxidação de ácido fórmico e metanol sobre fases intermetálicas ordenadas Pt-M(M = Mn, Mo, Pb, Sb e Sn)

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Análise do setor de celulose e papel na era da globalização: um olhar sobre sua produção e mão-de-obra

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Caracterização química e morfológica de implantes Ti-Mo com superfícies usinadas e modificadas por feixe de laser: análises biomecânica, histológica e histométrica em coelhos

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Aspectos morfológicos e biométricos da mão e densitométricos do metacarpo de ovinos da raça Santa Inês

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Avaliação da força de preensão palmar plena e pulpo-lateral: relação com a antropometria da mão e posições de trabalho

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)