Analysis of Mn-deposits from Lake Eningi-Lampi

The processes of formation of iron-manganese nodules and crusts have been studied on an example of the Eningi-Lampi lake, Central Karelia, where the relationships between the source of the ore, sedimentary materials and areas of their accumulation prove relatively simple and apparent. Nodules and crusts are composed mostly by birnessite, amorphous hydrous ferric oxides and hydro-goethite. They occur, as a rule, on the surface of relatively coarse-grained sediments, at the ground-water interface. Considerably in a lesser extent are found the nodules in the upper part (0ó5 cm) of the red-brown flooded watery mud covering dark-green, black muds. The nucleus of nodules, or the basis of crusts of iron-manganese hydroxides are various, frequently altered, fragments of rocks, sometimes pieces of wood. Distribution of Mn and Fe in sediments and waters of the lake is considered. It is shown that the Mn/Fe ratio decreases considerably in waters, sediments and nodules of the lake while moving off a distance from the source. The main role in the process of formation of iron-manganese nodules belongs to the selective chemosorption interaction (with auto-catalytic oxidation) of component-bearing solutions with active surfaces.

Description of the fossil manganese nodules found in the Oligocene clay deposits of Moravia, Brno area, Czech Republic

In the green Oligocene clay of Krizanovice (former Krzyzanowicz) the author found numerous black nodules. In the 3-4 centimeter thick black crust of a particular specimen the concentration in MnO2 is evaluated at 46.6% MnO2. The determination was done using the Volhard's method (precipitation of Fe by ZnO and titration with KMnO4). Only the dissoleved part in HCL was analysed. The non soluble residue was essentially a silica precipitate in the form of many gray flakes. The specific gravity of the crust was evaluated at 3.8. In the internal yellow core the amount of manganese is about 2.39% MnO2. Due to the light color it is judged to probably be in the form of Mn2O3.

Observation of manganese deposits made during the 1936 transect of C/S Lord Kelvin through the Northern Atlantic Ocean

In May and June 1936 Dr. C. S. Piggot of the Geophysical Laboratory, Carnegie Institution of Washington, took a series of 11 deep-sea cores in the North Atlantic Ocean between the Newfoundland banks and the banks off the Irish coast. These cores were taken from the Western Union Telegraph Co.'s cable ship Lord Kelvin with the explosive type of sounding device which Dr. Piggot designed. All but two of these cores (Nos. 8 and 11) are more than 2.43 meters (8 feet) long, and all contain ample material for study. Of the two short cores, No. 8 was taken from the top of the Faraday Hills, as that part of the mid-Atlantic ridge is known, where the material is closely packed and more sandy and consequently more resistant; No. 11 came from a locality where the apparatus apparently landed on volcanic rock that may be part of a submarine lava flow.

Annotated record of the detailed examination of Mn deposits from CHINOOK Expedition stations

The cores described in this report were taken during the CHINOOK Expedition in July to August 1956 by the Scripps Institution of Oceanography from the R/V Spencer F. Baird. A total of 20 cores and dredges were recovered and are available at Scripps for sampling and study.

Annotated record of the detailed examination of Mn deposits from the H.M.S. Sealark Percy Sladen Trust Expedition in the Indian ocean

In 1905, the Percy Sladen Trust Expedition, under the supervision of Stanley Gardiner in H.M.S. 'Sealark' made an extensive cruise in the Indian Ocean. The author received 79 samples from Mr. Gardiner which were thoroughly examined.

Annotated record of the detailed examination of Mn deposits from the FANFARE Expedition stations

The cores described in this report were taken on the FANFARE Expedition in July 1959 by Scripps Institution of Oceanography from the R/V H. M. Smith and the R/V Spencer F. Baird. A total of 49 cores and dredges were recovered and are available at Scripps for sampling and study. The coring sites, all in the eastern tropical central Pacific.

Annotated record of the detailed examination of Mn deposits from the SO 79 (SEDIPERU - TUSCH) expedition from R/V Sonne

The research cruise SO79 with RV SONNE (April 18 to June 09 1992) aimed to assess the impact of a potential mining activity on the sensitive deep-sea ecosystem of the Peru Basin. Up to now only results of reconnaissance surveys of the extended manganese nodule field discovered in 1978 in the Peru Basin are available. The hydroacoustic, sedimentological, and geochemical studies on data and sample material of SO79 came to the following results: a small-scaled variation in thickness respectively type of surface sediments shown by the sediment echosounder respectively the side-scan-sonar is assumably due to variations in deposition or erosion. The composition of sediments is controlled by climatic cycles of different length which were caused by the variable influence of glaciation of the northern hemisphere. We think that during the quaternary a deep-water circulation reduced in intensity and O2-content may have produced a suboxic diagenetic environment which led to a remobilization and redeposition of Mn forming manganese nodules in the oxic surface sediments. Near the distinct redox boundary at about 10 cm depth the growth conditions for nodules are extremely favourable. Due to the great variability of sediments the impact of deep-sea mining will be highly variable and the disturbance of the seafloor will change the ecosystem considerably.

Annotated record of the detailed examination of Mn deposits from VEMA 15 Expedition stations

The cores and dredges described in this report were taken during the VEMA 15 Expedition from October 1958 until July 1959 by the Lamont Geological Observatory, Columbia University from the R/V Vema. A total of 410 cores and dredges were recovered and are available at Lamont-Doherty Earth Observatory for sampling and study.

(Table 8.2, Page 178) Annotated record of the detailed examination of Mn deposits from submarine photographs acquired by the R/V Vityaz in the Pacific Ocean

Prof. H. H. W. Menard has brought together nearly all that was known of the Pacific geology in the early 1960s. His book contains a particular chapter on manganese nodules giving a stimulating review of the features and processes known to govern their distribution and chemical composition.

Observation of ferromanganese deposits in the Baltic Sea

Baltic sediments have been studied by Behrens, Munthe, Küppers, Spethmann, Apstein, Sjöstedt, Pratje and the writer. The following types of sediments have been observed: varved and non-varved late-glacial clays, gray and black, post-glacial muds, and sands. The organic content of late-glacial clays ordinarily is less than 1.3 per cent, and of post-glacial muds more than 3 per cent. Sediments containing intermediate quantities are scarce. This can be explained as a result of the changed balance between organic and inorganic sedimentation when the glacial period ended; the abundance of fresh detritus then suddenly ceased and inorganic sedimentation became very much slower than before; consequently, the relative amount of organic detritus increased. As most of the material was not subjected to biological analysis, it has not been possible to distinguish different ages among post-glacial sediments.