924 resultados para Waste from iron mining


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A set of 43 sediment cores from around the Canary Islands is used to characterise this region, which intersects meridional climatic regimes and zonal productivity gradients in a high spatial resolution. Using rapid and nondestructive core logging techniques we carried out Fe intensity and magnetic susceptibility (MS) measurements and created a stack on the basis of five stratigraphic reference cores, for which a stratigraphic age model was available from d18O and 14C analyses on planktonic foraminifera. By correlation of the stack with the Fe and MS records of the other cores, we were able to develop age depth models at all investigated sites of the region. We present the bulk sediment accumulation rates (AR) of the Canary Islands region as an indicator of shifts in the upwelling-influenced areas for the Holocene (0-12 ky), the deglaciation (12-18 ky) and the last glacial (18-40 ky). General observations are an enhanced productivity during glacial times with highest values during the deglaciation. The main differences between the analysed time intervals we interpret as result of the sea-level effects, changes in the extent of high productivity areas, and current intensity.

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Fe-Mn-concretions of a spheroidal type were found according to electron probe determinations to consist of alternating iron- and manganese-rich layers. This pattern was ascribed to seasonal variations in the physico-chemical conditions governing the precipitation of the hydrous oxides of iron and manganese. Calculations based on the rhythmic growth of the concretions investigated gave a mean accumulation rate of 0.15-0.20 mm/yr. The rather high phosphorus content (average 3.5 % P2O5) of the concretions was found to be concentrated in the iron-rich layers, probably as a result of the scavenging effect of ferric hydroxide.

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We examined sediments from Neogene and Quaternary sections of the Benguela and Oman upwelling systems (DSDP Site 532, ODP Sites 723 and 722) to determine environmental and geochemical factors which control and limit pyrite formation in organic-carbon-rich marine sediments. Those samples from the upwelling sites, which contained low to moderate concentrations of total organic carbon (0.7%-3%), had C/S ratios typical of normal marine sediments, i.e., around 2.8. In these sediments, TOC availability probably limited pyrite formation. Results that do not conform with accepted models were found for the sediments high in TOC (3^0-12.4%). The organic matter was of marine origin and contained considerable pyrolytic hydrocarbons, a fact that we take as a sign of low degradation, yet significant concentrations of dissolved sulfate coexisted with it (> 5 mmol/L in the case of Sites 532 and 723). Detrital iron was probably not limiting in either case, because the degree of pyritization was always less than 0.65. Therefore, controls on sulfate reduction and pyrite formation in the organic matter-rich sediments do not appear to conform simply to generally accepted diagenetic models. The data from these thermally immature, old, and organic-rich marine sediments imply that (1) the total reduced sulfur content of organic-rich marine upwelling sediments rarely exceeds an approximate boundary of 1.5% by weight, (2) the C/S ratio of these sediments is not constant and usually much higher than the empirical values proposed for marine sediments. We conclude that sedimentary pyrite formation in upwelling sediments is limited by an as yet unknown factor, and that caution is advised in using C/S ratios and C vs. S diagrams in paleoenvironmental reconstructions for organic-rich sediments.

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Issued July 1978.

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"January 1981"--Cover.

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Mode of access: Internet.

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Mode of access: Internet.

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Publisher location came from U.S. EPA About EPA, Mailing addresses and phone numbers webpage.

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Bibliography: p. 30-31.

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Vita.

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"Contract No. AT(40-1)-2077."