Chemistry of bulk-rocks and minerals of ODP Hole 120-748C

Five hundred meters of a unique Upper Cretaceous Cr-rich glauconitic sequence (Unit III) that overlies a 3-m-thick alkali-basalt flow with underlying epiclastic volcanogenic sediments was drilled at ODP Leg 120 Site 748. The Cr-rich glauconitic sequence is lithostratigraphically and biostratigraphically divided into three subunits (IIIA, IIIB, IIIC) that can also be recognized by the Cr concentration of the bulk sediment, which is low (<200 ppm) in Subunits IIIC and IIIA and high (400-800 ppm) in Subunit IIIB. The Cr enrichment is caused by Cr-spinel, which is the only significant heavy mineral component beside Fe-Ti ores. Other Cr-bearing components are glauconite pellets and possibly some other clay minerals. The glauconitic sequence of Subunit IIIB was formed by reworking of glauconite and volcanogenic components that were transported restricted distances and redeposited downslope by mass-transportation processes. The site of formation was a nearshore, shallow inner shelf environment, and final deposition may have been on the outer part of a narrow shelf, at the slope toward the restricted, probably synsedimentary, faulted Raggatt Basin. The volcanic edifices uncovered on land were tholeiitic basalts (T-MORB), alkali-basaltic (OIB) and (?)silicic volcanic complexes, and ultramafic rocks. The latter were the ultimate source for the Cr-spinel contribution. Terrestrial aqueous solutions carried Fe, K, Cr, Si, and probably Al into the marine environment, where, depending on the redox conditions of microenvironments in the sediment, green (Fe- and K-rich) or brown (Al-rich) glauconite pellets formed. The Upper Cretaceous glauconitic sequence at Site 748 on the Southern Kerguelen Plateau constitutes the transition in space and time from terrestrial to marine, from magmatically active subaerial to magmatically passive submarine conditions, and from a tranquil platform to active rifting conditions.

Sedimentation processes in the Mar del Plata Canyon (Southwest Atlantic) reconstructed from three sediment cores (GeoB13832-2, GeoB13833-2, GeoB13862-1)

The Mar del Plata Canyon is located at the continental margin off northern Argentina in a key intermediate and deep-water oceanographic setting. In this region, strong contour currents shape the continental margin by eroding, transporting and depositing sediments. These currents generate various depositional and erosive features which together are described as a Contourite Depositional System (CDS). The Mar del Plata Canyon intersects the CDS, and does not have any obvious connection to the shelf or to an onshore sediment source. Here we present the sedimentary processes that act in the canyon and show that continuous Holocene sedimentation is related to intermediate-water current activity. The Holocene deposits in the canyon are strongly bioturbated and consist mainly of the terrigenous "sortable silt" fraction (10-63 µm) without primary structures, similarly to drift deposits. We propose that the Mar del Plata Canyon interacts with an intermediate-depth nepheloid layer generated by the northward-flowing Antarctic Intermediate Water (AAIW). This interaction results in rapid and continuous deposition of coarse silt sediments inside the canyon with an average sedimentation rate of 160 cm/kyr during the Holocene. We conclude that the presence of the Mar del Plata Canyon decreases the transport capacity of AAIW, in particular of its deepest portion that is associated with the nepheloid layer, which in turn generates a change in the contourite deposition pattern around the canyon. Since sedimentation processes in the Mar del Plata Canyon indicate a response to changes of AAIW contour-current strength related to Late Glacial/Holocene variability, the sediments deposited within the canyon are a great climate archive for paleoceanographic reconstructions. Moreover, an additional involvement of (hemi) pelagic sediments indicates episodic productivity events in response to changes in upper ocean circulation possibly associated with Holocene changes in intensity of El Niño/Southern Oscillation.

Composition and age of igneous rocks from the Vityaz Ridge

Results of geological research carried out by V.I. Il'ichev Pacific Oceanological Institute (Far East Division of the Russian Academy of Sciences) and P.P. Shirshov Institute of Oceanology (Russian Academy of Sciences) on the submarine Vityaz Ridge during Cruise 37 of R/V Akademik Lavrentyev in 2005 are discussed. Various rocks composing the basement and the sedimentary cover of the ridge were dredged in three areas. Based on isotope geochronology, petrogeochemical, petrographic, and paleontological data and comparison with similar rocks available from the adjacent land and the Sea of Okhotsk, they are subdivided into several age complexes. Late Cretaceous, Eocene, Late Oligocene, Miocene, and Pliocene-Pleistocene complexes are defined among igneous rocks, while volcanogenic-sedimentary rocks are united into Late Cretaceous - Early Paleocene (Late Campanian - Danian), undivided Paleogene (Paleocene-Eocene?), Oligocene - Early Miocene, and Pliocene-Pleistocene complexes. Obtained data on age and formation settings of the defined complexes allowed to reconstruct geological evolution of the central Pacific slope of the Kurile Island arc.

Magnetobiostratigraphy and stable isotope record of Paleocene sediments from ODP Hole 122-761B in the subtropical Indian Ocean

Surface and deep water circulation patterns in the eastern Indian Ocean during the Paleocene Epoch are inferred based on an integrated magnetobiostratigraphic and stable isotope investigation of Ocean Drilling Program Hole 761B, drilled on the Wombat Plateau. A combination of magnetostratigraphy, biostratigraphy and isotope stratigraphy demonstrates that numerous deep sea sites that have been considered to show continuous, or nearly continuous sedimentation through the Paleocene are punctuated by a series of hiatuses, some of which exceeding a duration of 1 Myr. Therefore, our study is based on a detailed temporal interpretation of the stratigraphic successions we used for paleoceanographic reconstructions. We compare detailed planktonic and benthic foraminiferal carbon and oxygen isotope records from Hole 761B with several temporally correlative records published from different oceanic provinces in order to distinguish between local and global patterns within the eastern Indian Ocean. Although Site 761 was situated at low latitudes during the Paleocene, its surface waters were predominantly influenced by circulation originating from the Southern Ocean as indicated by inferred cool sea surface temperatures and reduced surface to deep water temperature gradients. We suggest that deep waters in the eastern Indian Ocean were not directly fed by the Southern or Tethys Oceans. Rather, the more negative delta13C composition of the bottom waters recorded by benthic foraminifera implies the presence and/or active contribution of aged deep waters from the Pacific during this time, at least prior to ~60.2 Ma and subsequent to ~59.0 Ma. The Indian continent, Ninetyeast Ridge, Kerguelen Plateau and Broken Ridge may have played a significant role as submarine barriers to deep water circulation during the Paleocene.

(Table 2) Taxonomic composition of diatoms in dredged samples from the island-side slope of the Kuril-Kamchatka Trench

Studies of diatoms from dredge samples collected on the island slope of the Kuril-Kamchatka Trench have allowed to recognize well-preserved marine diatom assemblages corresponding to assemblages of the followed Oligocene zones: Rhizosolenia oligocaenica (subzone ''a'', 33.6-31 Ma), Cavitatus rectus (29.6-28.2 Ma), and Rocella gelida (28.2-24.0 Ma) as identified in the North Pacific zonal scale. Description of these assemblages and their complete taxonomic composition are presented. Diversity of species together with abundance and degree of preservation of diatoms and accompanying siliceous microorganisms suggests their autochtonous origin and favorable conditions of their development. Assemblages of the Early Oligocene zones Rhizosolenia oligocaenica and Cavitatus rectus recognized in sediments of the outer zone of the Lesser Kuril Ridge (submarine slope of the Shikotan Island) and on the Vityaz' submarine ridge were most probably formed under conditions of a vast shelf, while assemblage of the Late Oligocene zone Rocella gelida encountered only in the region of the Lesser Kuril Ridge formed under more deep-water conditions, presumably, over an island slope. Deepening of the basin in the region of the outer zone of the Lesser Kuril Ridge in Late Oligocene probably reflects one of stages of evolution of the Kuril-Kamchatka Trench.

(Table 3) Stable isotope record of Cretaceous foraminifera from DSDP Hole 44-392A

Mid-Cretaceous (Barremian-Turonian) plankton preserved in deep-sea marl, organic-rich shale, and pelagic carbonate hold an important record of how the marine biosphere responded to short- and long-term changes in the ocean-climate system. Oceanic anoxic events (OAEs) were short-lived episodes of organic carbon burial that are distinguished by their widespread distribution as discrete beds of black shale and/or pronounced carbon isotopic excursions. OAE1a in the early Aptian (~120.5 Ma) and OAE2 at the Cenomanian/Turonian boundary (~93.5 Ma) were global in their distribution and associated with heightened marine productivity. OAE1b spans the Aptian/Albian boundary (~113-109 Ma) and represents a protracted interval of dysoxia with multiple discrete black shales across parts of Tethys (including Mexico), while OAE1d developed across eastern and western Tethys and in other locales during the latest Albian (~99.5 Ma). Mineralized plankton experienced accelerated rates of speciation and extinction at or near the major Cretaceous OAEs, and strontium isotopic evidence suggests a possible link to times of rapid oceanic plateau formation and/or increased rates of ridge crest volcanism. Elevated levels of trace metals in OAE1a and OAE2 strata suggest that marine productivity may have been facilitated by increased availability of dissolved iron. The association of plankton turnover and carbon isotopic excursions with each of the major OAEs, despite the variable geographic distribution of black shale accumulation, points to widespread changes in the ocean-climate system. Ocean crust production and hydrothermal activity increased in the late Aptian. Faster spreading rates [and/or increased ridge length] drove a long-term (Albian-early Turonian) rise in sea level and CO2-induced global warming. Changes in ocean circulation, water column stratification, and nutrient partitioning lead to a reorganization of plankton community structure and widespread carbonate (chalk) deposition during the Late Cretaceous. We conclude that there were important linkages between submarine volcanism, plankton evolution, and the cycling of carbon through the marine biosphere.

Oxygen isotope concentrations of minerals from the upper kilometer of the ocean crust, DSDP Hole 504B

DSDP Hole 504B is the deepest basement hole in the oceanic crust, penetrating through a 571.5 m pillow section, a 209 m lithologic transition zone, and 295 m into a sheeted dike complex. An oxygen isotopic profile through the upper crust at Site 504 is similar to that in many ophiolite complexes, where the extrusive section is enriched in 18O relative to unaltered basalts, and the dike section is variably depleted and enriched. Basalts in the pillow section at Site 504 have delta 18O values generally ranging from +6.1 to +8.5? SMOW (mean= +7.0?), although minor zeolite-rich samples range up to 12.7?. Rocks depleted in 18O appear abruptly at 624 m sub-basement in the lithologic transition from 100% pillows to 100% dikes, coinciding with the appearance of greenschist facies minerals in the rocks. Whole-rock values range to as low as +3.6?, but the mean values for the lithologic transition zone and dike section are +5.8 and +5.4?, respectively. Oxygen and carbon isotopic data for secondary vein minerals combined with the whole rock data provide evidence for the former presence of two distinct circulation systems separated by a relatively sharp boundary at the top of the lithologic transition zone. The pillow section reacted with seawater at low temperatures (near 0°C up to a maximum of around 150°C) and relatively high water/rock mass ratios (10-100); water/rock ratios were greater and conditions were more oxidizing during submarine weathering of the uppermost 320 m than deeper in the pillow section. The transition zone and dikes were altered at much higher temperatures (up to about 350°C) and generally low water/rock mass ratios (~1), and hydrothermal fluids probably contained mantle-derived CO2. Mixing of axial hydrothermal fluids upwelling through the dike section with cooler seawater circulating in the overlying pillow section resulted in a steep temperature gradient (~2.5°C/m) across a 70 m interval at the top of the lithologic transition zone. Progressive reaction during axial hydrothermal metamorphism and later off-axis alteration led to the formation of albite- and Ca-zeolite-rich alteration halos around fractures. This enhanced the effects of cooling and 18O enrichment of fluids, resulting in local increases in delta 18O of rocks which had been previously depleted in 18O during prior axial metamorphism.

Geochemistry of hydrothermal solutions, ores, and biota from hydrothermal fields at the East Pacific Rise axis near 9°50'N

Hydrothermal solutions were examined in a circulation system that started to develop after the 1991 volcanic eruption in the axial segment of the EPR between 9°45'N and 9°52'N. Within twelve years after this eruption, diffusion outflow of hot fluid from fractures in basaltic lavas gave way to focused seeps of hot solutions through channels of hydrothermal sulfide edifices. An example of the field Q demonstrates that from 1991 to 2003 H2S concentrations decreased from 86 to 1 mM/kg, and the Fe/H2S ratio simultaneously increased by factor 1.7. This fact can explain disappearance of microbial mats that were widespread within the fields before 1991. S isotopic composition of H2S does not depend on H2S concentration. This fact testifies rapid evolution of the hydrothermal system in the early years of its evolution. Carbon in CH4 from hot fluid sampled in 2003 is richer in 12C isotope than carbon in fluid from the hydrothermal field at 21°N EPR. It suggests that methane comes to the Q field from more than one source. Composition of particulate matter in hydrothermal solutions indicates that it was contributed by biological material. Experimental solutions with labeled substrates (t<70°C) show evidence of active processes of methane oxidation and sulfate reduction. Our results indicate that, during 12-year evolution of the hydrothermal system, composition of its solutions evolved and approached compositions of solutions in mature hydrothermal systems of the EPR.

Corrected ICESat altimetry data, surface mass balance, and firn elevation change on Antarctic ice shelves

Accurate prediction of global sea-level rise requires that we understand the cause of recent, widespread and intensifying glacier acceleration along Antarctic ice-sheet coastal margins. Floating ice shelves buttress the flow of grounded tributary glaciers and their thickness and extent are particularly susceptible to changes in both climate and ocean forcing. Recent ice-shelf collapse led to retreat and acceleration of several glaciers on the Antarctic Peninsula. However, the extent and magnitude of ice-shelf thickness change, its causes and its link to glacier flow rate are so poorly understood that its influence on the future of the ice sheets cannot yet be predicted. Here we use satellite laser altimetry and modelling of the surface firn layer to reveal for the first time the circum-Antarctic pattern of ice-shelf thinning through increased basal melt. We deduce that this increased melt is the primary driver of Antarctic ice-sheet loss, through a reduction in buttressing of the adjacent ice sheet that has led to accelerated glacier flow. The highest thinning rates (~7 m/a) occur where warm water at depth can access thick ice shelves via submarine troughs crossing the continental shelf. Wind forcing could explain the dominant patterns of both basal melting and the surface melting and collapse of Antarctic ice shelves, through ocean upwelling in the Amundsen and Bellingshausen Seas and atmospheric warming on the Antarctic Peninsula. This implies that climate forcing through changing winds influences Antarctic Ice Sheet mass balance, and hence global sea-level, on annual to decadal timescales.

Chemical composition and description of a ferromanganese crust, sample 89D, obtained during R/V Capricorne cruise ARCANTE 1

A manganese oxide encrustation (2.5 kg) was dredged, in an island arc setting, downslope of Bertrand bank, a seamount culminating at 70-m depth and located NNE of Grande-Terre, Guadeloupe, and SE of Antigua, West Indies. A thorough texturai analysis indicated a rhythmic precipitation and growth polarity as well as mineralogical ( 10 A tektomanganate) and geochemical (low concentrations of Ni, Cu, Co, Zn, Pb and REE) criteria, point to a submarine hydrothermal origin for most of the sample. The crust was coated with a fine ferromanganese oxide cortex deposited iii a "normal" oceanic environment; it also included micritic fillings, a main pyroclastic zone near the top of the crust, and a Mg-Al sulphate deposit. Planktonic foraminifera coeval with the precipitation of the manganese oxide indicate an age of ca. 3 m. y. (upper Pliocene); i.e., more than 20 m. y. after the cessation of the volcanic activity of the Lesser Antilles outer arc that was responsible for the buildup of the Bertrand seamount. Furthermore, the genesis of the crust is not linked to the activity of the contemporaneous inner arc (Miocene to Present), particularly of its nearmost segment (Basse Terre, Guadeloupe-Montserrat) located about 50 km to the West. The authors suggest that the manganese oxide is the result of convective circulation of sea water through a faulted system occurring in an area of intense seismic activity. The remobilization of chemical elements (Mn, S, etc.) within the seamount volcanic core bas probably affected a substratum that was still hydrothermally altered during the previous volcanic activity of the outer arc. The authors insist on the interest in using texturai analysis for Fe/Mn oxide investigations.

Hydrate abundances at the high-flux Batumi seep area in the southeastern Black Sea

Submarine gas hydrates are a major global reservoir of the potent greenhouse gas methane. Since current assessments of worldwide hydrate-bound carbon vary by one order of magnitude, new technical efforts are required for improved and accurate hydrate quantifications. Here we present hydrate abundances determined for surface sediments at the high-flux Batumi seep area in the southeastern Black Sea at 840 m water depth using state-of-the art autoclave technology. Pressure sediment cores of up to 2.65 m in length were recovered with an autoclave piston corer backed by conventional gravity cores. Quantitative core degassing yielded volumetric gas/bulk sediment ratios of up to 20.3 proving hydrate presence. The cores represented late glacial to Holocene hemipelagic sediments with the shallowest hydrates found at 90 cmbsf. Calculated methane concentrations in the different cores surpassed methane equilibrium concentrations in the two lowermost lithological Black Sea units sampled. The results indicated hydrate fractions of 5.2% of pore volume in the sapropelic Unit 2 and mean values of 21% pore volume in the lacustrine Unit 3. We calculate that the studied area of ~ 0.5 km**2 currently contains about 11.3 kt of methane bound in shallow hydrates. Episodic detachment and rafting of such hydrates is suggested by a rugged seafloor topography along with variable thicknesses in lithologies. We propose that sealing by hydrate precipitation in coarse-grained deposits and gas accumulation beneath induces detachment of hydrate/sediment chunks. Floating hydrates will rapidly transport methane into shallower waters and potentially to the sea-atmosphere boundary. In contrast, persistent in situ dissociation of shallow hydrates appears unlikely in the near future as deep water warming by about 1.6 °C and/or decrease in hydrostatic pressure corresponding to a sea level drop of about 130 m would be required. Because hydrate detachment should be primarily controlled by internal factors in this area and in similar hydrated settings, it serves as source of methane in shallow waters and the atmosphere which is mainly decoupled from external forcing.

Active methane seepage in the Southern Ocean, off the sub-Antarctic island of South Georgia

An extensive submarine cold-seep area was discovered on the northern shelf of South Georgia during R/V Polarstern cruise ANT-XXIX/4 in spring 2013. Hydroacoustic surveys documented the presence of 133 gas bubble emissions, which were restricted to glacially-formed fjords and troughs. Video-based sea floor observations confirmed the sea floor origin of the gas emissions and spatially related microbial mats. Effective methane transport from these emissions into the hydrosphere was proven by relative enrichments of dissolved methane in near-bottom waters. Stable carbon isotopic signatures pointed to a predominant microbial methane formation, presumably based on high organic matter sedimentation in this region. Although known from many continental margins in the world's oceans, this is the first report of an active area of methane seepage in the Southern Ocean. Our finding of substantial methane emission related to a trough and fjord system, a topographical setting that exists commonly in glacially-affected areas, opens up the possibility that methane seepage is a more widespread phenomenon in polar and sub-polar regions than previously thought.