Equipment and procedures for ON-SITE testing of PV plants and BIPV

Actual system performance of a PV system can differ from its expected behaviour.. This is the main reason why the performance of PV systems should be monitored, analyzed and, if needed, improved on. Some of the current testing procedures relating to the electrical behaviour of PV systems are appropriated for detecting electrical performance losses, but they are not well-suited to reveal hidden defects in the modules of PV plants and BIPV, which can lead to future losses. This paper reports on the tests and procedures used to evaluate the performance of PV systems, and especially on a novel procedure for quick on-site measurements and defect recognition caused by overheating in PV modules located in operating PV installations.

3D simulation of complex shading affecting PV systems taking benefit from the power of graphics cards developed for the video game industry

Shading reduces the power output of a photovoltaic (PV) system. The design engineering of PV systems requires modeling and evaluating shading losses. Some PV systems are affected by complex shading scenes whose resulting PV energy losses are very difficult to evaluate with current modeling tools. Several specialized PV design and simulation software include the possibility to evaluate shading losses. They generally possess a Graphical User Interface (GUI) through which the user can draw a 3D shading scene, and then evaluate its corresponding PV energy losses. The complexity of the objects that these tools can handle is relatively limited. We have created a software solution, 3DPV, which allows evaluating the energy losses induced by complex 3D scenes on PV generators. The 3D objects can be imported from specialized 3D modeling software or from a 3D object library. The shadows cast by this 3D scene on the PV generator are then directly evaluated from the Graphics Processing Unit (GPU). Thanks to the recent development of GPUs for the video game industry, the shadows can be evaluated with a very high spatial resolution that reaches well beyond the PV cell level, in very short calculation times. A PV simulation model then translates the geometrical shading into PV energy output losses. 3DPV has been implemented using WebGL, which allows it to run directly from a Web browser, without requiring any local installation from the user. This also allows taken full benefits from the information already available from Internet, such as the 3D object libraries. This contribution describes, step by step, the method that allows 3DPV to evaluate the PV energy losses caused by complex shading. We then illustrate the results of this methodology to several application cases that are encountered in the world of PV systems design. Keywords: 3D, modeling, simulation, GPU, shading, losses, shadow mapping, solar, photovoltaic, PV, WebGL

Electronic and optical properties of substitutional V, Cr and Ir impurities in Cu2ZnSnS4

The substitution of cation atoms by V, Cr and It in the natural and synthetic quaternary Cu2ZnSnS4 semiconductor is analyzed using first-principles methods. In most of the substitutions, the electronic structure of these modified CZTS is characterized for intermediate bands with different occupation and position within of the energy band gap. A study of the symmetry and composition of these intermediate bands is carried out for all substitutions. These bands permit additional photon absorption and emission channels depending on their occupation. The optical properties are obtained and analyzed. The absorption coefficients are split into contributions from the different absorption channels and from the inter- and intra-atomic components. The sub bandgap transitions are significant in many cases because the anion states contribute to the valence, conduction and intermediates bands. These properties could therefore be used for novel optoelectronic devices.

Characterisation of the operation & maintenance phase in PV rural electrification programmes

Con 1.300 millones de personas en el mundo sin acceso a la electricidad (la mayoría en entornos rurales de países empobrecidos), la energía solar fotovoltaica constituye una solución viable técnica y económicamente para electrificar las zonas más remotas del planeta donde las redes eléctricas convencionales no llegan. Casi todos los países en el mundo han desarrollado algún tipo de programa de electrificación fotovoltaica rural durante los últimos 40 años, principalmente los países más pobres, donde a través de diferentes modelos de financiación, se han instalado millones de sistemas solares domiciliarios (pequeños sistemas fotovoltaicos para uso doméstico). Durante este largo período, se han ido superando muchas barreras, como la mejora de la calidad de los sistemas fotovoltaicos, la reducción de costes, la optimización del diseño y del dimensionado de los sistemas, la disponibilidad financiera para implantar programas de electrificación rural, etc. Gracias a esto, la electrificación rural descentralizada ha experimentado recientemente un salto de escala caracterizada por la implantación de grandes programas con miles de sistemas solares domiciliarios e integrando largos períodos de mantenimiento. Muchos de estos grandes programas se están llevando a cabo con limitado éxito, ya que generalmente parten de supuestos e hipótesis poco contrastadas con la realidad, comprometiendo así un retorno económico que permita el desarrollo de esta actividad a largo plazo. En este escenario surge un nuevo reto: el de cómo garantizar la sostenibilidad de los grandes programas de electrificación rural fotovoltaica. Se argumenta que la principal causa de esta falta de rentabilidad es el imprevisto alto coste de la fase de operación y mantenimiento. Cuestiones clave tales como la estructura de costes de operación y mantenimiento o la fiabilidad de los componentes del sistema fotovoltaico no están bien caracterizados hoy en día. Esta situación limita la capacidad de diseñar estructuras de mantenimiento capaces de asegurar la sostenibilidad y la rentabilidad del servicio de operación y mantenimiento en estos programas. Esta tesis doctoral tiene como objetivo responder a estas cuestiones. Se ha realizado varios estudios sobre la base de un gran programa de electrificación rural fotovoltaica real llevado a cabo en Marruecos con más de 13.000 sistemas solares domiciliarios instalados. Sobre la base de este programa se ha hecho una evaluación en profundidad de la fiabilidad de los sistemas solares a partir de los datos de mantenimiento recogidos durante 5 años con más de 80.000 inputs. Los resultados han permitido establecer las funciones de fiabilidad de los equipos tal y como se comportan en condiciones reales de operación, las tasas de fallos y los tiempos medios hasta el fallo para los principales componentes del sistema, siendo este el primer caso de divulgación de resultados de este tipo en el campo de la electrificación rural fotovoltaica. Los dos principales componentes del sistema solar domiciliario, la batería y el módulo fotovoltaico, han sido analizados en campo a través de una muestra de 41 sistemas trabajando en condiciones reales pertenecientes al programa solar marroquí. Por un lado se ha estudiado la degradación de la capacidad de las baterías y por otro la degradación de potencia de los módulos fotovoltaicos. En el caso de las baterías, los resultados nos han permitido caracterizar la curva de degradación en capacidad llegando a obtener una propuesta de nueva definición del umbral de vida útil de las baterías en electrificación rural. También sobre la base del programa solar de Marruecos se ha llevado a cabo un estudio de caracterización de los costes reales de operación y mantenimiento a partir de la base de datos de contabilidad del programa registrados durante 5 años. Los resultados del estudio han permitido definir cuáles son costes que más incidencia tienen en el coste global. Se han obtenido los costes unitarios por sistema instalado y se han calculado los montantes de las cuotas de mantenimiento de los usuarios para garantizar la rentabilidad de la operación y mantenimiento. Finalmente, se propone un modelo de optimización matemática para diseñar estructuras de mantenimiento basado en los resultados de los estudios anteriores. La herramienta, elaborada mediante programación lineal entera mixta, se ha aplicado al programa marroquí con el fin de validar el modelo propuesto. ABSTRACT With 1,300 million people worldwide deprived of access to electricity (mostly in rural environments), photovoltaic solar energy has proven to be a cost‐effective solution and the only hope for electrifying the most remote inhabitants of the planet, where conventional electric grids do not reach because they are unaffordable. Almost all countries in the world have had some kind of rural photovoltaic electrification programme during the past 40 years, mainly the poorer countries, where through different organizational models, millions of solar home systems (small photovoltaic systems for domestic use) have been installed. During this long period, many barriers have been overcome, such as quality enhancement, cost reduction, the optimization of designing and sizing, financial availability, etc. Thanks to this, decentralized rural electrification has recently experienced a change of scale characterized by new programmes with thousands of solar home systems and long maintenance periods. Many of these large programmes are being developed with limited success, as they have generally been based on assumptions that do not correspond to reality, compromising the economic return that allows long term activity. In this scenario a new challenge emerges, which approaches the sustainability of large programmes. It is argued that the main cause of unprofitability is the unexpected high cost of the operation and maintenance of the solar systems. In fact, the lack of a paradigm in decentralized rural services has led to many private companies to carry out decentralized electrification programmes blindly. Issues such as the operation and maintenance cost structure or the reliability of the solar home system components have still not been characterized. This situation does not allow optimized maintenance structure to be designed to assure the sustainability and profitability of the operation and maintenance service. This PhD thesis aims to respond to these needs. Several studies have been carried out based on a real and large photovoltaic rural electrification programme carried out in Morocco with more than 13,000 solar home systems. An in‐depth reliability assessment has been made from a 5‐year maintenance database with more than 80,000 maintenance inputs. The results have allowed us to establish the real reliability functions, the failure rate and the main time to failure of the main components of the system, reporting these findings for the first time in the field of rural electrification. Both in‐field experiments on the capacity degradation of batteries and power degradation of photovoltaic modules have been carried out. During the experiments both samples of batteries and modules were operating under real conditions integrated into the solar home systems of the Moroccan programme. In the case of the batteries, the results have enabled us to obtain a proposal of definition of death of batteries in rural electrification. A cost assessment of the Moroccan experience based on a 5‐year accounting database has been carried out to characterize the cost structure of the programme. The results have allowed the major costs of the photovoltaic electrification to be defined. The overall cost ratio per installed system has been calculated together with the necessary fees that users would have to pay to make the operation and maintenance affordable. Finally, a mathematical optimization model has been proposed to design maintenance structures based on the previous study results. The tool has been applied to the Moroccan programme with the aim of validating the model.

Laser induced forward transfer of silver pastes for printing of fingers in c-si cells.

The main objective of this work is to adapt the Laser Induced Forward Techniques (LIFT), a well- known laser direct writing technique for material transfer, to define metallic contacts (fingers and busbars) onto c-Si cells. The silver paste (with viscosity around 30-50 kcPs) is applied over a glass substrate using a coater. The thickness of the paste can be control changing the deposit parameters. The glass with the silver paste is set at a controlled gap over the c-Si cell. A solid state pulsed laser (532 nm) is focused at the glass/silver interface producing a droplet of silver that it is transferred to the c-Si cell. A scanner is used to print lines. The process parameters (silver paste thickness, gap and laser parameters -spot size, pulse energy and overlapping of pulses) are modified and the morphology of the lines is studied using confocal microscopy. Long lines are printed and the uniformity (in thickness and height) is studied. Some examples of metallization of larger areas (up to 10 cm x 10 cm) are presented.

Antiguo Poblado de Algarrobito ubicado en el Valle del Elqui Chile, y su Patrón Urbano Bioclimático

La importancia de conocer bien el entorno para un proyecto arquitectónico es que podemos adaptarlo a nuestras necesidades fisiológicas de Confort Térmico. Podemos decir entonces que el edificio juega un papel fundamental como técnica de control de nuestro entorno. El edificio nos debería entregar un entorno controlado para que nos sintamos bien térmicamente, considerando además, que la arquitectura por sí misma puede lograr dicho confort la mayor parte de las veces. De no ser así, los usuarios tienden a colocar elementos mecánicos, para generar frío o calor artificialmente. Es fundamental entonces que nuestros edificios, tengan una correcta interacción con los recursos naturales del lugar para lograr dicho confort térmico. Pero lograr el Confort Térmico en todos los edificios de una ciudad como unidad, no logrará que la ciudad entera sea confortable térmicamente, ya que las complejas interacciones hacen que la problemática se deba enfrentar como algo sistémico. Esto quiere decir, que para que una ciudad o un conjunto logren la Confortabilidad Térmica deseada por sus habitantes debiera haber sido planificada conforme a variables urbanas que interactúen con el medio natural en forma eficiente. Con la observación de ciertos conjuntos habitacionales antiguos en el interior del Valle del Elqui, Chile y de sus relaciones entre variables urbanas y naturales, queda de manifiesto ciertas características que conllevan a pensar que existió una planificación ambiental en éstos que llevaron a lograr un conjunto con características bioclimáticas. Las evidencias de la existencia en primer lugar de un patrón urbanístico en dichos conjuntos habitacionales antiguos, hacen pensar que dicho patrón se trataría de un patrón bioclimático rural planificado, lo que hace que exista un gran interés por el estudio de estos conjuntos. Hasta ahora, en Chile, los pocos estudios de Confort Térmico que existen, están orientados a edificaciones aisladas, al Confort térmico interior de la edificación en el ámbito urbano, y en nada a Patrones Bioclimáticos de Conjuntos Habitacionales en una situación de ruralidad como a la referida en esta investigación. Además, los estudios referidos al clima urbano, difieren a los del clima rural, por lo que se necesitan mayores estudios aún para comprender mejor la problemática. Es por esto, que la mayoría de los casos mencionados en este estudio son contextualizados al ámbito urbano por carecer de otros estudios rurales. Es en este sentido que esta investigación cobra real importancia y pretende establecer la relación existente entre las variables morfológicas rurales y los recursos naturales del lugar y que generan un confort térmico ideal para sus habitantes, al mismo tiempo, se analiza la existencia de un Patrón Bioclimático en un poblado denominado Algarrobito ubicado en la cuenca del Valle del Elqui, Chile. Es en este sentido que el propósito principal de este trabajo es determinar la real existencia de un Patrón Bioclimático que relacione la morfología rural y edificada de los antiguos poblados pertenecientes a la cuenca del Valle de Elqui Chile con el microclima del lugar. La metodología empleada se basa en realizar primeramente el estudio del microclima del lugar a través de las Cartas Bioclimáticas. Para ello se obtuvo información de datos climatológicos de las estaciones meteorológicas ubicadas en la cuenca del Valle de Elqui, principalmente las más cercanas al lugar de estudio. Mediante una revisión exhaustiva de la información arquitectónica, así como de una labor de reconocimiento en terreno realizada en el poblado seleccionado y de la aplicación del Climograma local, se identificaron las diferentes zonas bioclimáticas del poblado antiguo y potenciales áreas de estudio en el conjunto. Esta actividad incluyó un estudio preliminar de la energía solar local, vientos, humedad, temperaturas y su interacción con el conjunto, permitiendo una primera aproximación a la problemática del espacio exterior y las viviendas. Esto permitió en base a las condicionantes del lugar, la arquitectura vernácula y los materiales descubrir un Patrón en el antiguo conjunto que permitía entregar confortabilidad térmica a sus habitantes y darse cuenta también, que el nuevo conjunto emplazado en el sector no seguía ese patrón con las disfuncionalidades que ello llevaba. Con esto quedó demostrado en primer lugar la existencia de un Patrón Bioclimático rural, los beneficios del patrón, la importancia de éste como causante de Confortabilidad Térmica del conjunto, y por ende de mejor eficiencia energética, así como también, que el nuevo conjunto no sigue para nada este Patrón, pero que existe también la posibilidad de rectificación y por supuesto, que los nuevos desarrollos residenciales del Valle del Elqui, puedan planificarse en base al patrón bioclimático descubierto. ABSTRACT Knowing the environment of an architectonic proyect is really important for adjusting it to our physiological needs of Thermal Comfort. So we can say that the building plays a key role as a technique of control of our environment. The building should give us a controlled environment to make us feel good thermally, and it usually can reach pleasurable temperatures by itself. If it isn't like that, people cooled or heated the ambience with mechanical elements. So a correct interaction between the buildings and natural resources is important to reach a thermal comfort. But achieving Thermal Comfort in all the buildings of a city as a unit will not achieve the whole city is thermally comfortable, because the complex interactions cause the problem needs to be solved as something systemic. This means that for a city or a set reach the Thermal Comfortability desired by its inhabitants, it should have been planned according to the urban variables that interact with the natural environment efficiently. Observing some old housing complexes in Elqui Valley, Chile, and the relationships between their natural and urban variables, some features lead to think that the environmental planning in these led to achieve a set with bioclimatic features. First, the evidences about the existence of an urban pattern in those old housing complexes, make thinking that the pattern would be a planned urban pattern, which generates interest in its study. In Chile, there have been few studies about Thermal Comfort, oriented to isolated buildings and indoor thermal comfort, but Bioclimatic Urban Patterns haven't been studied at all. In this sense, this investigation acquires a real importance and pretends to establish the relationship between urban variables and natural resources of the place that generates a good thermal comfort for its habitants. At the same time, the existence of a Bioclimatic Urban Pattern in Algarrobito, located in Elqui Valley basin, Chile, is analized. It is in this sense that the main purpose of this work is to determine the real existence of a Bioclimatic Urban Pattern, that links the urban and constructive form of the old villages of it with its microclimate. The methodology used is based on performing first the study of the microclimate of the place through the Bioclimatic Cards. To do this, weather stations, located in Elqui valley, near the place that was studied, were used to obtain information of climatological data. The different bioclimatic zones to the old town and potential areas of study in the set were identified, through an exhaustive review of the architectural information, a field reconnaissance work performed on the selected town and the application of the Local Climograph. This activity included a preliminary study of the local solar energy, the winds, the moisture, the temperatures, and their interaction with the set, allowing a first aproximation to troubles of outer space and housing. This allowed, based on the conditions of the place, vernacular architecture and materials, discovering an urban pattern in the old set, which allowed to give thermal comfort to its inhabitants and realize that the new set of the place did not follow this pattern, with the dysfunctions that it carried. These points demonstrated, in first place, the existence of a Bioclimatic Urban Pattern, the benefits of it, the importance of it as a cause of Thermal Comfortability, and therefore a better efficiency of energy, also that the new set doesn’t follow this Pattern at all, but that the posibility of rectification exists and, of course, that the new residencial development in Elqui Valley can be planned based on bioclimatic pattern discovered.

Development of a full hybrid lighting-CPV prototype and savings in a real case operation

A full Hybrid lighting-CPV prototype has been assembled. This new concept mixes a classical CPV module with the production of light for illumination without a double conversion (solar energy to electricity and electricity to light) allowing a higher efficiency to the whole system. The present prototype is based on a commercial CPV module that has been adapted in order to be hybrid, adjusting the receivers to pass the fibers into the module, inserting a holder to adjust x,y and z position of the fibers and changing the original parquet of lenses by a bifocal one composed most of the original lenses and the inclusion of other lenses in the position of the corners. Results show that with a minimal loss in the CPV part, a luminous flux is obtained that can be used to illuminate. Adding an additional electrical lamp and a light sensor that enables this lamp when no light from the sun is received, a 38% saving on lighting electricity is expected in Madrid during a year.

Extreme overirradiance events in Sao Paulo, Brazil

Phenomena of overirradiance have been pointed all over the World. This note presents the most extreme enhancement event reported in Brazil, which contains an irradiance reading of 1590 W/m2 measured in São Paulo (latitude 23°32′S) at relatively low altitude (760 m a.s.l.).

Efficient exchange of the primary quinone acceptor QA in isolated reaction centers of Rhodopseudomonas viridis

A key step in the conversion of solar energy into chemical energy by photosynthetic reaction centers (RCs) occurs at the level of the two quinones, QA and QB, where electron transfer couples to proton transfer. A great deal of our understanding of the mechanisms of these coupled reactions relies on the seminal work of Okamura et al. [Okamura, M. Y., Isaacson, R. A., & Feher, G. (1975) Proc. Natl. Acad. Sci. USA 88, 3491–3495], who were able to extract with detergents the firmly bound ubiquinone QA from the RC of Rhodobacter sphaeroides and reconstitute the site with extraneous quinones. Up to now a comparable protocol was lacking for the RC of Rhodopseudomonas viridis despite the fact that its QA site, which contains 2-methyl-3-nonaprenyl-1,4-naphthoquinone (menaquinone-9), has provided the best x-ray structure available. Fourier transform infrared difference spectroscopy, together with the use of isotopically labeled quinones, can probe the interaction of QA with the RC protein. We establish that a simple incubation procedure of isolated RCs of Rp. viridis with an excess of extraneous quinone allows the menaquinone-9 in the QA site to be almost quantitatively replaced either by vitamin K1, a close analogue of menaquinone-9, or by ubiquinone. To our knowledge, this is the first report of quinone exchange in bacterial photosynthesis. The Fourier transform infrared data on the quinone and semiquinone vibrations show a close similarity in the bonding interactions of vitamin K1 with the protein at the QA site of Rp. viridis and Rb. sphaeroides, whereas for ubiquinone these interactions are significantly different. The results are interpreted in terms of slightly inequivalent quinone–protein interactions by comparison with the crystallographic data available for the QA site of the two RCs.

The long-range supraorganization of the bacterial photosynthetic unit: A key role for PufX

Bacterial photosynthesis relies on the interplay between light harvesting and electron transfer complexes, all of which are located within the intracytoplasmic membrane. These complexes capture and transfer solar energy, which is used to generate a proton gradient. In this study, we identify one of the factors that determines the organization of these complexes. We undertook a comparison of the organization of the light-harvesting complex 1 (LH1)/reaction center (RC) cores in the LH2− mutant of Rhodobacter sphaeroides in the presence or absence of the PufX protein. From polarized absorption spectra on oriented membranes, we conclude that PufX induces a specific orientation of the reaction center in the LH1 ring, as well as the formation of a long-range regular array of LH1-RC cores in the photosynthetic membrane. From our data, we have constructed a precise model of how the RC is positioned within the LH1 ring relative to the long (orientation) axis of the photosynthetic membrane.

Biotechnology: Enhancing human nutrition in developing and developed worlds

While the last 50 years of agriculture have focused on meeting the food, feed, and fiber needs of humans, the challenges for the next 50 years go far beyond simply addressing the needs of an ever-growing global population. In addition to producing more food, agriculture will have to deal with declining resources like water and arable land, need to enhance nutrient density of crops, and achieve these and other goals in a way that does not degrade the environment. Biotechnology and other emerging life sciences technologies offer valuable tools to help meet these multidimensional challenges. This paper explores the possibilities afforded through biotechnology in providing improved agronomic “input” traits, differentiated crops that impart more desirable “output” traits, and using plants as green factories to fortify foods with valuable nutrients naturally rather than externally during food processing. The concept of leveraging agriculture as green factories is expected to have tremendous positive implications for harnessing solar energy to meet fiber and fuel needs as well. Widespread adaptation of biotech-derived products of agriculture should lay the foundation for transformation of our society from a production-driven system to a quality and utility-enhanced system.

Indium-cadmium-oxide films having exceptional electrical conductivity and optical transparency: Clues for optimizing transparent conductors

Materials with high electrical conductivity and optical transparency are needed for future flat panel display, solar energy, and other opto-electronic technologies. InxCd1-xO films having a simple cubic microstructure have been grown on amorphous glass substrates by a straightforward chemical vapor deposition process. The x = 0.05 film conductivity of 17,000 S/cm, carrier mobility of 70 cm2/Vs, and visible region optical transparency window considerably exceed the corresponding parameters for commercial indium-tin oxide. Ab initio electronic structure calculations reveal small conduction electron effective masses, a dramatic shift of the CdO band gap with doping, and a conduction band hybridization gap caused by extensive Cd 5s + In 5s mixing.

Excited-state dynamics in photosystem II: Insights from the x-ray crystal structure

The heart of oxygenic photosynthesis is photosystem II (PSII), a multisubunit protein complex that uses solar energy to drive the splitting of water and production of molecular oxygen. The effectiveness of the photochemical reaction center of PSII depends on the efficient transfer of excitation energy from the surrounding antenna chlorophylls. A kinetic model for PSII, based on the x-ray crystal structure coordinates of 37 antenna and reaction center pigment molecules, allows us to map the major energy transfer routes from the antenna chlorophylls to the reaction center chromophores. The model shows that energy transfer to the reaction center is slow compared with the rate of primary electron transport and depends on a few bridging chlorophyll molecules. This unexpected energetic isolation of the reaction center in PSII is similar to that found in the bacterial photosystem, conflicts with the established view of the photophysics of PSII, and may be a functional requirement for primary photochemistry in photosynthesis. In addition, the model predicts a value for the intrinsic photochemical rate constant that is 4 times that found in bacterial reaction centers.

Sequential purification and crystal growth for the production of low cost silicon substrates : quarterly technical progress report no. 1, September 15-December 31, 1979 /

"February 1980."

Sequential purification and crystal growth for the production of low cost silicon substrates : annual report, September 15, 1979-September 14, 1980 /

"Work Performed Under Contract No. AC02-77CH00178."