Sm和U原子光电离截面的模型势计算

本文给出了使用四种不同形式的势对Sm基态光学电子所属壳层光电离截面计算的结果,同时给出了U原子三个激发态参量形式的极化修正模型势光电离截面的计算结果.我们的结果与其他作者使用相同形式的势计算的结果较好地符合.使用参数形式的极化模型势计算光电离截面是一种有效的方法.

I~N电子组态谱项结构的U群方法

多电子原子或离子的光谱理论中,一个很重要的问题就是确定由于电子间相互作用所形成的光谱项。通常采用轨道角动量耦合,自旋角动量耦合以及泡里原理来确定.当电子数N和轨道角动量量子数l大时,要经过冗长而仔细的运算才能确定下来,相当麻烦。本文利用U群方法,给出确定l~N电子组态光谱项的一般方法,大大简化了程序和工作量。首先把U_(2l+1)群的不可约表示的基直接和l~N电子组态的光谱结构联系起来,并引入了不可约表示的分解规则,及给出单列表示相应光谱项的计算方法。使计算程序标准化。

广义α_N指数及其应用——Ⅰ.广义α_N指数及其在中性磷萃取剂萃取Y、Ce、U和Th性能方面的应用

首先引进一般有机化合物的广义a_N指数,该指数能分辨有微小结构差别的有机化合物分子。在此基础上,计算了某些中性磷萃取剂的广义a_N指数。并将其与萃取性能进行相关分析,得到了满意的结果。

Element enrichment and U-series isotopic characteristics of the hydrothermal sulfides at Jade site in the Okinawa Trough

The geochemical and U-series isotopic characteristics of hydrothermal sulfide samples from the Jade site (127A degrees 04.5'E, 27A degrees 15'N, water depth 1300-1450 m) at Jade site in the Okinawa Trough were analyzed. In the hydrothermal sulfide samples bearing sulfate (samples HOK1 and HOK2), the LREEs are relatively enriched. All the hydrothermal sulfide samples except HOK1 belong to Zn-rich hydrothermal sulfide. In comparison with Zn-rich hydrothermal sulfides from other fields, the contents of Zn, Pb, Ag, Cd, Au and Hg are higher, the contents of Fe, Al, Cr, Co, Ni, Sr, Te, Cs, Ti and U lower, and the Pb-210 radioactivity ratios and Pb-210/Pb ratios very low. In the hydrothermal sulfide mainly composed of sphalerite, the correlations between rare elements Hf and U, and Hf and Mn as well as that between dispersive elements Ga and Zn, are strongly positive; also the contents of Au and Ag are related to Fe-sulfide, because the low temperature promotes enrichment of Au and Ag. Meanwhile, the positive correlations between Fe and Bi and between Zn and Cd are not affected by the change of mineral assemblage. Based on the Pb-210/Pb ratios of hydrothermal sulfide samples (3.99x10(-5)-5.42x10(-5)), their U isotopic composition (U-238 content 1.15-2.53 ppm, U-238 activity 1.07-1.87 dpm/g, U-234 activity 1.15-2.09 dpm/g and U-234/U-238 ratio 1.07-1.14) and their Th-232 and Th-230 contents are at base level, and the chronological age of hydrothermal sulfide at Jade site in the Okinawa Trough is between 200 and 2000 yr.

Genesis of Th-230 excess in basalts from mid-ocean ridges and ocean islands: Constraints from the global U-series isotope database and major and rare earth element geochemistry

Based on Th-230-U-238 disequilibrium and major element data from mid-ocean ridge basalts (MORBs) and ocean island basalts (OIBs), this study calculates mantle melting parameters, and thereby investigates the origin of Th-230 excess. (Th-230/U-238) in global MORBs shows a positive correlation with Fe-8, P (o), Na-8, and F-melt (Fe-8 and Na-8 are FeO and Na2O contents respectively after correction for crustal fractionation relative to MgO = 8 wt%, P (o)=pressure of initial melting and F (melt)=degree of melt), while Th-230 excess in OIBs has no obvious correlation with either initial mantle melting depth or the average degree of mantle melting. Furthermore, compared with the MORBs, higher (Th-230/U-238) in OIBs actually corresponds to a lower melting degree. This suggests that the Th-230 excess in MORBs is controlled by mantle melting conditions, while the Th-230 excess in OIBs is more likely related to the deep garnet control. The vast majority of calculated initial melting pressures of MORBs with excess Th-230 are between 1.0 and 2.5 GPa, which is consistent with the conclusion from experiments in recent years that D (U)> D (Th) for Al-clinopyroxene at pressures of > 1.0 GPa. The initial melting pressure of OIBs is 2.2-3.5 GPa (around the spinel-garnet transition zone), with their low excess Ra-226 compared to MORBs also suggesting a deeper mantle source. Accordingly, excess Th-230 in MORBs and OIBs may be formed respectively in the spinel and garnet stability field. In addition, there is no obvious correlation of K2O/TiO2 with (Th-230/U-238) and initial melting pressure (P (o)) of MORBs, so it is proposed that the melting depth producing excess Th-230 does not tap the spinel-garnet transition zone. OIBs and MORBs in both (Th-230/U-238) vs. K2O/TiO2 and (Th-230/U-238) vs. P (o) plots fall in two distinct areas, indicating that the mineral phases which dominate their excess Th-230 are different. Ce/Yb-Ce curves of fast and slow ridge MORBs are similar, while, in comparison, the Ce/Yb-Ce curve for OIBs shows more influence from garnet. The mechanisms generating excess Th-230 in MORBs and OIBs are significantly different, with formation of excess Th-230 in the garnet zone only being suitable for OIBs.

Generation and evolution of magma beneath the East Pacific Rise: Constraints from U-series disequilibrium and plagioclase-hosted melt inclusions

Mid-ocean ridge basalt (MORB) samples from the East Pacific Rise (EPR 12 degrees 50'N) were analyzed for U-series isotopes and compositions of plagioclase-hosted melt inclusions. The Ra-226 and Th-230 excesses are negatively correlated; the Ra-226 excess is positively correlated with Mg# and Sm/Nd, and is negatively correlated with La/Sm and Fe-8; the Th-230 excess is positively correlated with Fe-8 and La/Sm and is negatively correlated with Mg# and Sm/Nd. Interpretation of these correlations is critical for understanding the magmatic process. There are two models (the dynamic model and the "two-porosity" model) for interpreting these correlations, however, some crucial parameters used in these models are not ascertained. We propose instead a model to explain the U-series isotopic compositions based on the control of melt density variation. For melting either peridotite or the "marble-cake" mantle, the FeOt content, Th-230 excess and La/Sm ratio increases and Sm/Nd decreases with increasing pressure. A deep melt will evolve to a higher density and lower Mg# than a shallow melt, the former corresponds to a long residence time, which lowers the Ra-226 excess significantly. This model is supported by the existence of low Ra-226 excesses and high Th-230 excesses in MORBs having a high Fe-8 content and high density. The positive correlation of Ra-226 excess and magma liquidus temperature implies that the shallow melt is cooled less than the deep melt due to its low density and short residence time. The correlations among Fe-8, Ti-8 and Ca-8/Al-8 in plagioclase-hosted melt inclusions further prove that MORBs are formed from melts having a negative correlation in melting depths and degrees. The negative correlation of Ra-226 excess vs. chemical diversity index (standard deviation of Fe-8, Ti-8 and Ca-8/Al-8) of the melt inclusions is in accordance with the influence of a density-controlled magma residence time. We conclude that the magma density variation exerts significant control on residence time and U-series isotopic compositions. (c) 2010 Elsevier B.V. All rights reserved.

中国北方风成堆积的风化作用与环境变迁—U-Th、~(10)Be及元素地球化学的研究

The surface of the Earth is continuously undergoing changes as a result of weathering-erosion, plate tectonics and volcanic processes. Continental weathering-erosion with its complex rock-water interactions is the central process of global biochemical cycling of elements, and affects the long-term ocean atmosphere budget of carbon dioxide both through the consumption of carbonic acid during silicate weathering and through changes in the weathering and burial rates of organic carbon. Rates of the weathering-erosion depend on a variety of factors, in particular rock properties and chemical composition, climate (especially rainfall), structure, and elevation. They are quite variable on a regional scale. Thus, environmental changes in a region could be indicated by the history of weathering-erosion in the region. Recent attention has focused on increased silicate weathering of tectonically uplifted areas in the India-Asia collision zone as a possible cause for falling atmospheric CO_2 levels in the Cenozoic era. The wind blown dust deposits in the Loess Plateau is derived from the arid and semiarid regions in northwestern China, in turn, where the deposits have been derived from the Qinghai-Xizang Plateau and the high mountains around. Therefore, geochemistry of the wind blown loess-paleosol and red clay sequences may provide insight both to paleoenvironmental changes on the Loess Plateau, and to the uplift and weathering-erosion histories of the Qinghai-Xizang Plateau. In this paper, uranium-thorium series nuclides and cosmogenic ~(10)Be have been employed as tracers of weathering intensities and histories of the dust sediments in the Loess Plateau. Major elements, such as Na, Al, Fe etc., are also used to estimate degree of chemical alteration of the dust sediments and to rebuild the history of weathering on the Loess Plateau. First of all, using a low-level HPGe γ-ray detector, we measured U and Th series nuclides in 170 loess and paleosol samples from five sites in the Loess Plateau, going back 2.6 Ma. The results show that ~(238)U activities are disequilibrium with its daughter nuclide ~(230)Th in young loess-paleosol sequence, indicating that weathering was happened both in dust deposition site and in dust source regions. Using concentrations of ~(238)U and ~(232)Th in the samples, we estimated the amounts of ~(238)U leached out of from paleosols due to weathering. Further, based on analyses of ~(230)Th in paleosols deposited in the past ca. 140 ka, we determined when the paleosols weathered in the source regions. We conclude that most of the weathering in the dust-source regions may have occurred during the interglacials before dust deposition.

胶东昆嵛山复式花岗岩体的演化—岩石学和锆石U-Pb年代学研究

Kunyushan composite granite pluton is located in northeast part of the Sulu UHP collisional belt, Jiaodong peninsula, eastern China. It is regarded as the boundary of the Jiaodong block and the Sulu UHP collisional belt. The body is unique in the Dabieshan-Sulu UHP collisional orogen for its feature of multiple intrusions of diverse types granitoid rocks in a long span after UHP the collision between the North China and the Yangtze plates in late Triassic. It can be grouped into four series on the basis of petrology and petrochemistry. They are mid-K calc-alkaline granitoids, strongly peraluminous granites, high-K calc-alkaline granitoids and syenitic granite of shoshonitic series. In this thesis, the later three types of rocks are investigated geochronologically in detail. The grain zircon U-Pb isotope dilution dating technique has been employed in this study. Zircon morphology are presented and discussion on the chemical and physical conditions of the granite formation have been carried out in addtion. Strongly peraluminous granites comprises foliated monzogranite and garnet bearing leucogranite. They occupy more than half of the area of the Kunyushan composite body. Three zircon samples of foliated monzogranites have been analyzed, they yield lower intercept ages mainly in the range of 140-150 Ma. The formation of these rocks was likely to be at 700-600 ℃, implied by zircon morphology. Two zircon samples of the garnet bearing leucogranite yield lower intercept ages from 130 Ma to 140 Ma. Zircon morphology indicate that the liquidus temperature of the magma was about 750 °C. Syenitic granite of shoshonitic series occur in the north central part of the body, and the volume is quite small contrast to other types. One zircon sample was chosen from this rock, and yield lower intercept age of 121+1.8/-2.1 Ma. Zircon morphology indicate that the liquidus temperature of this rock is up to 900 °C, which is much higher than others'. High-K calc-alkaline granitoids can be divided into two types on the basis of rock texture and structure. One is Kf-porphyritic monzogranite. It's outcrop is quite small. Zircon ages of one sample constrain the emplacement of this rock at about 112 Ma. The other is medium-grain to coarse-grain monzogranite. Zircons from it yield lower intercept age of 100.5+2.9/-4.6 Ma. The variation of zircon morphology suggest that these two monzogranites were outcomes of a single magma at different stage. The former emplaced earlier than the latter. The liquidus temperature of the magma was about 800 ℃ Inherited zircon is ubiquitous in the Kunyushan composite body. Most of the samples yield upper intercept ages of late Proterozoic. It was considered that only the Yangtze plate underwent a crustal growth during late Proterozoic among the two plates which involved into the UHP collision. Inherited zircon of about 200 Ma can also be observed in strongly peraluminous and high-K calc-alkaline granitoids. Two samples out of eight yield upper intercept ages of Achaean.

滇东南发现新元古代岩浆岩：SHRIMP锆石U-Pb年代学和岩石地球化学证据

滇东南老君山地区出露了一套穹隆状变形-变质岩系,新近完成的1：5万都龙幅、麻栗坡县幅区域地质矿产调查报告,将其分解为晚志留纪南温河花岗岩、新元古界新寨岩组和古元古界猛硐岩群.首次对猛硐岩群的石英角闪斜长片麻岩进行了SHRIMP锆石U-Pb定年,结合阴极发光图像分析,获得两组岩浆锆石的结晶年龄分别为761±12Ma和829±10Ma,指示滇东南老君山地区存在新元古代岩浆活动,同时从同位素年代学上,表明猛硐岩群是一套前寒武纪的变质沉积-岩浆杂岩.此外,还获得一些年龄为≈1.83Ga的残留锆石,表明该区存在古元古代的结晶基底.石英角闪斜长片麻岩及共存的斜长角闪岩,它们的原岩具有大陆裂谷背景下玄武质-玄武安山质岩浆系列的地球化学特征,可能与新元古代Rodinia超大陆聚合-裂解过程中的岩浆活动有关,本区在新元古代可能位于南华裂谷与康滇裂谷的交汇部位。

都龙锡锌矿床锡石和锆石U-Pb年代学：滇东南白垩纪大规模花岗岩成岩-成矿事件

都龙锡锌矿床是我国最大的锡石硫化物矿床之一.由于缺少可靠的年代学数据,对该矿床的成因尚存在较大争议.本文报道了利用锡石和锆石U-Pb法,首次获得的都龙锡锌矿床及相关的燕山晚期老君山花岗岩的年龄.其中,锡石TIMS法^206Pb/^238U年龄加权平均值为79.8±3.2Ma（MSWD=3.16）,^238U/^204Pb-^206Pb/^204Pb等时线年龄为82.0±9.6Ma（MSWD=4.81）;隐伏花岗岩的锆石SHRIMP法^206Pb/^238U年龄加权平均值为92.9±1.9Ma（N=10,MSWD=0.71）,花岗斑岩的锆石SHRIMP法^206Pb/^238U年龄加权平均值为86.9±1.4Ma（N=9,MSWD=3.70）,表明锡（铜）矿化主要与晚白垩世岩浆热液活动有关.结合个旧、白牛厂两个超大型矿床和相关花岗岩体的年代学资料,指示滇东南地区于白垩纪存在以锡矿化为特色的大规模花岗岩成岩-成矿事件,可能与晚中生代以来华南地块岩石圈伸展有关.

四川盐边高家村镁铁-超镁铁质杂岩体的形成时代: 单颗粒锆石U-Pb和角闪石40Ar/39Ar年代学制约

四川盐边高家村镁铁-超镁铁质杂岩体是一个分异良好的似层状侵入体, 该岩体可以分为两个堆积旋回. 对高家村杂岩体主体岩相的角闪辉长岩进行系统的单颗粒锆石U-Pb定年以及单矿物角闪石40Ar/39Ar定年的研究, 表明高家村杂岩体的主体岩相形成年龄为840±5 Ma. 对“盐边蛇绿岩”的提法提出了质疑, 认为高家村杂岩体的形成很可能与Rodinia超级大陆下的一个超级地幔柱活动有关. 以上的研究成果有助于重新认识盐边地区新元古代构造演化特征.

滇西北普朗斑岩铜矿锆石离子探针U-Pb年龄：成矿时限及地质意义

应用高精度离子探针锆石U—Pb测年方法，获得普朗斑岩铜矿床中3件矿化石英二长斑岩的锆石年龄分别为228．4-3Ma、226．3±2．8Ma、226±3Ma。锆石形态和铀钍参数均属典型的岩浆锆石特征，年龄值在误差范围内近似一致，表明形成矿化斑岩的中酸性岩浆从岩浆房快速上升侵位。结合前人已发表的矿化斑岩的黑云母Ar—Ar坪年龄及辉钼矿Re-Os同位素年龄等数据，推测普朗斑岩铜矿的岩浆-热液系统从岩浆侵入至矿化阶段的持续时间可能长达lOMa以上，主成矿期约为216～214Ma。从岩浆房分异出的富含成矿物质和挥发份的岩浆流体在相对较晚阶段对普朗复式岩体发生了强烈的蚀变作用并可能进一步萃取了岩体中的成矿物质。

滇西北中旬松诺含矿斑岩的锆石SHRIMP U-Pb年龄及地质意义

位于义敦岛弧南端的中甸岛弧中广泛发育印支期斑岩及斑岩型和矽卡岩型铜矿床。松诺（或称松诺力赞）复式岩体位于东斑岩带中部，由石英闪长玢岩、黑云石英二长斑岩、闪长玢岩和含矿石英二长斑岩组成，其南部为普朗超大型斑岩铜矿床，北部为地苏嘎铜矿点。本文对含矿石英二长斑岩进行了岩相学和锆石SHRIMPU-Pb定年研究，结果表明所有锆石颗粒自形较好且均发育规则的韵律环带，Th含量为180-854μg／g，U含量为270-709μg／g，Th／U比值为0．77-1．24，为典型岩浆成因锆石。获得了含矿石英二长斑岩的侵位年龄为220．9±3．5Ma（n=9，MSWD=1．6），这与中甸岛弧洋壳俯冲造山作用的时限（210-235Ma）相吻合。

碳酸盐岩风化过程中的U－Th不平衡研究－以黔中、黔北为例

为了进一步获得贵州碳酸盐岩风化成土过程的信息，为测定风化成土速率的研究工作奠定基础，本次研究工作通过U－Th的地球化学特征与主量元素、微量元素、稀土元素的地球化学特征的对比研究以及U－Th不平衡来研究贵州两个碳酸盐岩风化剖面的风化成土过程，并得出以下总体认识： 贵州碳酸盐岩风化剖面中的238U－234U－230Th不平衡说明风化剖面中的U－Th不平衡与风化过程密切相关，与风化壳中矿物和铁壳的演化特征密切相关。风化剖面不仅被简单的持续积累或者滤失过程所控制，而且被每一个土层中的复杂的重组过程所影响。U－Th不平衡也说明风化系统的扰动可能与中更新世晚期的气候变化有关。风化剖面中的U－Th不平衡是由母岩碳酸盐岩的风化、风化流体的溶解作用、表土层中的有机质、铁质结核带中的氧化铁矿物以及伊利石、高岭石等粘土矿物对U、Th的吸附作用、α反冲作用以及微生物的还原作用等共同作用的结果。 具体结论如下： （1）两个风化剖面中的U、Th都在半风化层中相对基岩强烈富集，安顺白云岩风化剖面中U、Th在全风化层中下部富集；而遵义石灰岩风化剖面中的U在全风化层中部富集，Th在全风化层上部富集，然后向表土层逐渐减少。 （2）U、Th在半风化层中相对基岩强烈富集，是因为在半风化层中，基岩中的原生矿物发生溶解、蚀变，生成新的次生粘土矿物伊利石，而伊利石对U、Th具有强烈的吸附能力。风化剖面中U、Th的富集主要与地表水的淋滤作用以及铁壳在进一步的风化过程中溶解释放出其中所富集的U、Th，而U、Th向下重新迁移的过程有关。 （3）风化剖面中U、Th的分布特征说明U、Th的含量与风化过程密切相关，与风化壳中的矿物和铁壳的演化特征密切相关。遵义石灰岩风化剖面中U、Th的淋失程度比安顺白云岩风化剖面中U、Th的淋失程度弱也说明了遵义石灰岩风化剖面的风化程度要低于安顺白云岩风化剖面的风化程度。 （4）安顺白云岩风化剖面中，234U/238U在<1和＞1之间交替变化。除在剖面中部，230Th/238U≈1外，230Th/238U基本上都＞1。 （5）安顺白云岩风化剖面中的238U －234U－230Th不平衡表明：安顺白云岩风化剖面中的U－Th不平衡是母岩碳酸盐岩的风化、风化流体的溶解作用、表土层中的有机质、铁质结核带中的氧化铁矿物以及伊利石、高岭石等粘土矿物对234U、230Th的吸附作用、α反冲作用以及微生物的还原作用等共同作用的结果。 （6）遵义石灰岩风化剖面中234U/238U除少数几个点外，大多数采样点的234U/238U都＜1。除了少数几个点外，大部分230Th/238U＞1。 （7）遵义石灰岩风化剖面中的238U －234U－230Th不平衡表明：234U－238U不平衡主要是由地表水和入渗水的溶解作用以及α反冲作用为主要的控制机制。而风化剖面中230Th－238U不平衡主要是由表土层中的有机质、高岭石、氧化铁矿物以及伊利石对230Th吸附作用和α反冲作用共同作用的结果。 （8）将U的迁移模型应用于本研究中的两个碳酸盐岩风化剖面，说明这两个风化剖面都被U的近期积累或者滤失过程所影响，风化系统处于过渡的不稳定状态，并通过U在风化剖面中的重新迁移将系统带回稳定状态。 （9）由等时线定年法计算出的安顺白云岩风化剖面的年龄范围为：87.0±7.8－479.2±47.9ka；遵义石灰岩风化剖面的年龄范围为：62.3±8.7－353.3±31.8ka。 （10）由等时线定年法可知：两个风化系统将在～1.1Ma达到稳定状态。 （11）碳酸盐岩风化剖面应用U的迁移模型得出的U的迁移过程与风化剖面中主量元素和微量元素的迁移特征相吻合，说明模型的选择是正确的。 （12）整个风化剖面的238U－234U－230Th不平衡说明风化剖面中的U－Th不平衡与风化过程密切相关，与风化壳中矿物和铁壳的演化特征密切相关。风化系统的扰动可能与中更新世晚期的气候变化有关。碳酸盐岩风化剖面被U的近期迁移过程所影响，风化剖面中的每一个单元甚至每一个土样都具有复杂的历史。这些单元或者土样是古老的风化历史和近期的重新迁移过程的叠加。