994 resultados para Organoclay (OC)


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Pós-graduação em Agronomia (Ciência do Solo) - FCAV

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Pós-graduação em Engenharia e Ciência de Alimentos - IBILCE

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Soils of the Brazilian Cerrado biome have been found to be deficient in copper (Cu) and zinc (Zn). In this area, an Oxisol was deeply excavated in 1962 during the construction of a hydroelectrical plant, and the exposed saprolite material was abandoned, without any reclamation measures. The abandoned land was a harsh environment for plant growth, and the secondary vegetation has not recovered. A field trial was established in 1992 to assess the effects of different grass species and lime amendments on soil reclamation at the degraded site. In 2011 soil samples were collected at three depths (0-10, 10-20, and 20-40cm) from vegetated and bare plots over tilled saprolite, from an untreated area of the saprolite, and from an Oxisol under native forest, used as external reference. Nineteen years after the reclamation effort was begun, the organic carbon (OC) content of the restored saprolite still was much lower than that of the Oxisol under natural vegetation. The undisturbed Oxisol was deficient in extractable Cu (0.16-0.10mgkg(-1)) and Zn (0.10-0.02mgkg(-1)) and exhibited rather low concentrations of extractable iron (Fe; 5.24-1.47mgkg(-1)) and manganese (Mn; 3.21-0.77mgkg(-1)). However, the saprolite under reclamation showed even lower levels of these elements compared to the native forest soil. In the natural soil, OC, N, extractable Fe, Mn, and Cu showed stratification, but this was not the case for extractable Zn. Although the reclaimed saprolite still was far from predisturbance conditions, the revegetation treatments promoted recovery of OC, N, Fe, Mn, and Cu at the surface layers, which resulted in incipient stratification. Extractable Fe, Mn, and Cu were correlated to OC, whereas no association between Zn and OC was detected. Our results also suggest that reclamation of the excavated saprolite may be constrained by micronutrient deficiencies and mostly by the extremely low levels of Zn and Cu.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Ultraviolet (UV) filters are widely used in the formulation of personal care products (PCPs) to prevent damage to the skin, lips, and hair caused by excessive UV radiation. Therefore, large amounts of these substances are released daily into the aquatic environment through either recreational activities or the release of domestic sewage. The concern regarding the presence of such substances in the environment and the exposure of aquatic organisms is based on their potential for bioaccumulation and their potential as endocrine disruptors. Although there are several reports regarding the occurrence and fate of UV filters in the aquatic environment, these compounds are still overlooked in tropical areas. In this study, we investigated the occurrence of the organic UV filters benzophenone-3 (BP-3), ethylhexyl salicylate (ES), ethylhexyl methoxycinnamate (EHMC), and octocrylene (OC) in six water treatment plants in various cities in Southeast Brazil over a period of 6 months to 1 year. All of the UV filters studied were detected at some time during the sampling period; however, only EHMC and BP-3 were found in quantifiable concentrations, ranging from 55 to 101 and 18 to 115 ng L(-1), respectively. Seasonal variation of BP-3 was most clearly noticed in the water treatment plant in Araraquara, São Paulo, where sampling was performed for 12 months. BP-3 was not quantifiable in winter but was quantifiable in summer. The levels of BP-3 were in the same range in raw, treated and chlorinated water, indicating that the compound was not removed by the water treatment process.