Optimization of Off-Null Ellipsometry for Optical Biosensor Applications

The optimization of off-null ellipsometry is described with emphasis on the improvement of resolution for visualizing biomolecule layers. For optical biosensor with layer thickness below 6.5 nm, a numerical simulation for the dependence of resolution on the azimuth settings of polarizer and analyzer is presented first. For comparison, three different resolutions are given at three azimuth settings which are near null and far away from null condition, respectively. Furthermore, the square or linear approximation relationship between the intensity and the layer thickness are also given at these settings. The difference among their accuracy is up to 100 times or so. Experimental results of the biosensor sample verify the optimization.

De La navigation de l'Amazone : reponse a un memoire de M. Maury, officier de la marine des Etats-Unis

Pedro de Ângelis, militar e político italiano, nasceu em Nápolis, em 1784, e morreu em Buenos Aires, em 1854. Acompanhou o Rei Murat no exílio, após sua queda, e o preceptor de seus filhos. Retornou à Itália no regime constitucionalista, exilando-se novamente com o estabelecimento do absolutismo. A convite de Rivadavia, fixou-se em Buenos Aires, participando com destaque da política da República do Prata, contrária aos direitos do Brasil. Tornou-se, todavia, profundo conhecedor da história e da política da história e da política da América do Sul. De la navigation de l’Amazone, publicação em francês, editada em Montevidéu, segundo Borba de Moraes, “foi escrita a pedido do Governo brasileiro”, que foi o financiador da obra, em resposta aos planos de Maury para colonizar o Vale do Amazonas com afro-norte-americanos. “Apesar da sua parcialidade, a obra pode ser considerada valiosa contribuição para o conhecimento do Brasil”, como afirma Palau. Foi, também, publicada em espanhol, francês e português.

Preparation and optical properties of CdTe/CdO center dot nH(2)O core/shell nano-composites in aqueous solution

The deposition of CdO center dot nH(2)O On CdTe nanoparticles was studied in an aqueous phase. The CdTe nanocrystals (NCs) were prepared in aqueous solution through the reaction between Cd2+ and NaHTe in the presence of thioglycolic acid as a stabilizer. The molar ratio of the Cd2+ to Te2- in the precursory solution played an important role in the photoluminescence of the ultimate CdTe NCs. The strongest photoluminescence was obtained under 4.0 of [Cd2+]/[Te2-] at pH similar to 8.2. With the optimum dosage of Cd(II) hydrous oxide deposited on the CdTe NCs, the photoluminescence was enhanced greatly. The photoluminescence of these nanocomposites was kept constant in the pH range of 8.0-10.0, but dramatically decreased with an obvious blue-shifted peak while the pH was below 8.0. In addition, the photochemical oxidation of CdTe NCs with cadmium hydrous oxide deposition was markedly inhibited.