Structure characterization of molecular complexes for non-linear optical materials. II. 1 : 1 complexes of 4-methyl-morpholine-N-oxide (1) and 3-picoline-N-oxide (2) with 2,4,6-trinitrophenol, studied by X-ray, AM1 and DFT calculations

(1) C6H2N3O7- center dot C5H12NO2+, Mr = 346.26, P2(1)/c, a = 7.2356(6), b = 10.5765(9), c = 19.593(2) angstrom, 3 beta=95.101(6)degrees, V = 1493.5(2) angstrom(3), Z = 4, R-1 = 0.0414; (2) C6H2N3O7- center dot C6H8NO+, Mr = 38.24, P2(1)/n, a = 7.8713(5), b = 6.1979(7), c = 28.697(3) angstrom, beta = 90.028(7)degrees, V = 1400.0(2) angstrom(3), Z = 4, R-1 = 0.0416. The packing units in both compounds consist of hydrogen bonded cation-anion pairs. The (hyper)polarizabilities have been calculated for the crystallographic and optimized molecules, by AM1 and at the DFT/B3LYP(6-31G**) level.

HIGH-TEMPERATURE SUPERFLUIDITY WITH ABNORMAL FERMIONIC OCCUPANCY

We examine a Lipkin based two-level pairing model at finite temperature and in the thermodynamic limit. Whereas at T = 0 the model exhibits a superconducting ground state for sufficiently high values of the coupling constant, a partially superconducting phase in which some of the particles are paired, is found to survive at high temperatures in a special treatment. This phase is a mixture of abnormally-occupied eigenstates, which lie at higher energy, of the interactionless model Hamiltonian.

AMBIGUITIES IN CHIRAL-SYMMETRY BREAKING USING THE EFFECTIVE POTENTIAL APPROACH

Using a form of the effective potential for composite operators with a variational approach we show that it is possible to get different directions of the chiral phase transition in QCD. Which one occurs depends on the way the Schwinger-Dyson equation for the fermion self-energy is used in the 2-loop term of the effective potential. We must choose the 2-loop term which agrees with phenomenology in each form of the effective potential.

Seasonal morphology of the domestic quail (Coturnix coturnix japonica) testis

A histological study was conducted on the testes of adult domestic quails (Coturnix coturnix japonica) over a year. The results revealed a clear variation of testicular weight, seminiferous tubule diameter, and the thickness and composition of the germinal epithelium over the year. The highest testicular weights were detected at the end of the autumn and during the winter (short-day period), reaching a maximum, together with spermatogenic activity, in September (long-day period in the southern hemisphere). In contrast, both testicular weight and spermatogenic activity were markedly decreased at the end of spring and during summer (long-day periods in the southern hemisphere).

CHIRAL SCHWINGER MODEL WITH A PODOLSKY TERM AT FINITE-TEMPERATURE

We study an exactly solvable two-dimensional model which mimics the basic features of the standard model. This model combines chiral coupling with an infrared behavior which resembles low energy QCD. This is done by adding a Podolsky higher-order derivative term in the gauge field to the Lagrangian of the usual chiral Schwinger model. We adopt a finite temperature regularization procedure in order to calculate the non-trivial fermionic Jacobian and obtain the photon and fermion propagators, first at zero temperature and then at finite temperature in the imaginary and real time formalisms. Both singular and non-singular cases, corresponding to the choice of the regularization parameter, are treated. In the nonsingular case there is a tachyonic mode as usual in a higher order derivative theory, however in the singular case there is no tachyonic excitation in the spectrum.

Population dynamics of Lucilia eximia (Dipt., Calliphoridae)

The theoretical dynamics of experimental populations of Lucilia eximia was investigated as an attempt to understand its population biology. Specifically the population dynamics of L. eximia was analysed by means of a mathematical model that incorporates fecundity and survival as density-dependent demographic parameters in discrete time. The sensitivity of these parameters to changes in the magnitude was also investigated. The mathematical model applied to experimental populations of L. eximia predicts a theoretical one-point equilibrium for immatures. The population dynamics of L. eximia is compared to the dynamics of Chrysomya species and Cochliomyia macellaria.

Diamondiferous deposits in the Jequitai area (Minas Gerais, Brazil): a consequence of neotectonic processes

Diamonds obtained from small scale mining near Jequitai and surrounding villages are extracted from Tertiary conglomerates and Quaternary gravels of the Rio Jequitai. Eocretaceous conglomerates, which are locally poorly diamondiferous, cover parts of the Serra da Agua Fria and Serra do Cabral. They are of no economic importance. Analyses of neotectonic, post-Miocene features support a transpressive regime that gave rise to N-S to N25° E transcurrent faults, and WNW normal faults. The main evidence for neotectonic processes are inclined Tertiary sediments, drainage captures, striated laterites of Miocene age, and tilting of blocks that form the Rio Jequitai graben. Diamonds in the Tertiary terraces derived from the Eocretaceous conglomerates, which were affected by neotectonic processes, followed by erosion and concentration during redeposition of sediments.

Crystal structure of di-mu(N,S)-thiocyanato-bis[(N-benzylideneaniline-C-2,N)palladium(II)], [Pd(C6H4CH=NC6H5)(mu-SCN)](2)

C28H20N4Pd2S2, monoclinic, P12(1)/c1 (No. 14), a = 11.325(1) Angstrom, b = 13.530(1) Angstrom, c = 17.925(1) Angstrom, beta = 106.23(1)degrees, V = 2637.1 Angstrom(3), Z = 4, R-gt(F) = 0.052, wR(ref)(F-2) = 0.129, T = 293 K.

Genetic parameters by Bayesian inference for dual purpose Jaffarabadi buffaloes

Knowledge of genetic parameters is essential for improved reproductive management and increased yield. Quantitative analysis of genetic parameters is lacking for many breeds of buffaloes. This article provides the first estimate of genetic parameters for dual purpose (meat and milk) Brazilian Jaffarabadi buffaloes, using Bayesian inference. Data on milk yield (MY), lactation length (LL), weight at 205 days (W205) and 365 (W365) days of age, and average daily gain (ADG) from 205 to 365 days of age were collected in two herds. Bivariate analyses (using the program MTGSAM) were performed with the Gibbs sampler to obtain estimates of variance and covariance. Average lactation milk yield and lactation length were 1 620.2 +/- 450.9 kg and 257.6 +/- 46.8 days, respectively, and the mean values for weight traits (kg) were 181.6 +/- 63.3 (W205), 298.04 +/- 116.1 (W365), and 0.73 +/- 0.35 (ADG). Heritability estimates (modes) were 0.16 for MY, 0.10 for LL, 0.43 for W205, 0.48 for W365 and 0.32 for ADG. There was a high genetic correlation (0.96) between milk yield and lactation length and very high genetic correlations (0.99) between the three growth traits. Our data suggest that both milk production and growth traits have clear potential for yield improvement through direct selection in this dual purpose breed. The selection for weight at an early age would be successful and selection for MY can be performed in the first lactation.

Áreas ecologicamente estáveis como instrumento de planejamento ambiental

The population growth phenomenon, coupled with recent urbanization, is seen in all continents and generates huge pressures on the physical and biotic environment, resulting in floods in several areas, desertification in others, and also various forms of pollution that cause serious problems to human health. It is appropriate to ask, what actions can be implemented in consolidated urban areas to improve the quality of life in this environment? What growth alternatives present themselves to today's society in order to keep an acceptable level of environmental quality in urban centers? A possibility is presented herein, stemming from the application of the Biotope Area Factor (BAF; www.stadtentwicklung.berlin.de) to an area of a Brazilian municipality. Current growing waterproofing requirements fur lots of the area were assesed, comparing them with those that would be desirable by the implementation of the BAF. The associated costs of this deployment are also discussed.

Glueballs as intermediate states in hadronic transitions

Hadronic transitions rates in the heavy quarkonium systems are calculated within the framework of the QCD multipole expansion. The spectrum of glueballs consisting of two massive gluons, obtained by the use of the potential model, is adopted as a suitable description of the intermediate states. Comparisons with the quark confining string model (QCS) and the bag model are made. © 1990 Springer-Verlag.

A diquark model for baryon spectroscopy

A quark-diquark approximation is used to investigate the mass spectroscopy of the spin-1/2 baryons belonging to the SU(3)-flavor group in a nonrelativistic potential approach. The baryon spectra obtained are confronted with relativistic results and experimental data. Root-mean-square radii are also calculated. © 1993 Springer-Verlag.

Hamiltonian quantization of the non-anomalous generalized Schwinger model

We quantize a generalized version of the Schwinger model, where the two chiral sectors couples with different strengths to the U(1) gauge field. Starting from a theory which includes a generalized Wess-Zumino term, we obtain the equal time commutation relation for physical fields, both the singular and non-singular cases are considered. The photon propagators are also computed in their gauge dependent and invariant versions. © 1995 Springer-Verlag.