Análise e simulação de modelos matemáticos para a estimativa da geração de gases em bioprocessos de decomposição anaeróbia de resíduos sólidos em aterros sanitários

Brazil faces a complex problem in respect to municipal solid waste, having been in recent years an increase of its generation without the country there be adequate for proper disposal thereof. In many states , the percentage of waste destined improperly , ie , in dumps , landfills, send- outs , among others , is greater than that disposed in landfills , which would be the most correct way to be made. It can be argued that this discrepancy is due to the high cost of implementation and operation of the landfill, and the same need large areas with physical characteristics that suit their operations . When there is a provision in properly constructed landfills , municipal solid waste grounded generate gases with high potential energy through biochemical reactions during the anaerobic decomposition of organic material stored . Such gases can be used for power generation within the landfill or other economic means . To estimate the gas generation will be sufficient for such economic compensation , there are mathematical models that make estimating the amount of gas produced . These models calculate the energy capacity and generation , using parameters obtained based on the characteristics of solid waste , climate of the region where they are grounded and grounding time . Such models have been raised and studied so that it was possible to perform simulations that demonstrate the behavior of biogas generation related to the external conditions of the landfill that interfere with biological reactions within. The results show differences between the values obtained , it shows that the preparation of the models found and used in the simulations were allocated amounts for different parameters that determine this difference in the estimate . Therefore, to rule, the models have difficulty understanding this because there is no clarity in the formulation of the equations , and the definition of variables and parameters would require a detailed study to...

Avaliação do ciclo de vida dos tubos de PVC produzidos no Brasil

Naturally characterizes the human being the interference in the environment to ensure their survival and also convenience. After numerous environmental accidents caused by unbridled pursuit of this goal, the concern about providing for current needs without compromising the ability of the future generations to supply their own, gained space. In order to contribute to sustainable development the Life Cycle Assessment (LCA) was implemented. This tool is based on the concept that if the environmental impacts of a product or service are known, it is possible to take better decisions concerning its environmental aspects. The purpose of this research is to conduct the LCA of polyvinyl chloride (PVC), the world’s second most consumed thermoplastic. The methodology described in NBR ISO 14040 and NBR ISO 14044 was followed. As a result, the LCA of polyvinyl chloride produced in Brazil was obtained, and, therefore, the inventory of the product in question adapted to Brazilian reality. The research can be applied to various studies considering that actions were taken to ensure that it represents the Brazilian reality. Moreover, the procedures were described to guarantee the greatest transparency possible

Avaliação estratégica de um plano de gestão de resíduos sólidos com foco nos resíduos orgânicos

One of the greatest problems nowadays is the correct management of solid waste produce in every human activity. On 2010, the “Política Nacional de Resíduos Sólidos” was approved, this law brings directives and instruments to deal with the solid waste issue. The objective of this work is to make a Strategic Assessment on a Solid Waste Management Plan applied to a medium size city. Based on general data about the situation of the solid wastes in Brazil, a first scenario was described. After that, likely scenarios were proposed, taking segregation, treatment and final disposal on account. Finally, those scenarios were compared, mainly in the final volume disposed and costs involved

Avaliação do gerenciamento e disposição final dos resíduos químicos de laboratórios do IGCE, UNESP - Rio Claro/SP

Laboratory of Chemical Waste Management programs are being implemented in various universities of the country and the world, in recognition of the urgent need to change the reality of disregard for the environment, together with objective responsibility of the generator, and especially the awareness of sustainability. Analysis and research laboratories involve a range of waste in developing their studies with intrinsic characteristics related to their form of generation. The amount of waste generated in this segment is negligible compared to industrial activities, but the environmental issue is that these residues do not have a standard technique for treatment due to the potential variation of its composition. This research project, aiming their suitability and continuous improvement, aims to diagnose and analyze the current situation of the management and disposal of chemical waste generated by the laboratories IGCE UNESP, Campus Rio Claro / SP. Universities, through their research, teaching and extension, end up generating potentially hazardous chemicals that may contaminate the environment when they are disposed of improperly, with no concern for the environment and / or public health. Aiming to assist in improvements with respect to this issue, the purpose of this study is to understand the management and disposal of chemical waste from the IGCE, laboratories UNESP - Rio Claro / SP, in order to discuss the situation of such waste, and present proposals to reduce generation of the same and minimizing the environmental impact, thereby increasing the local hygiene through proper disposal. The research instrument used interviews, questionnaires, review of recent literature and observations were made in order to develop proposals for the management and disposal of waste. These proposals based on prevention and corrective control, where the preventive approach aims at lifting techniques and actions to reduce the generating sources and...

Parque Estadual da Serra do Mar, Núcleo Santa Virginia: uma análise paisagística comparativa do período de 1989 até o presente

The Atlantic Forest is considered the fifth most important hotspot of the world, for its high endemism and biodiversity. The Serra do Mar State Park (SMSP) is the biggest area of integral protection in Brazilian coast, having the largest continuous remnant area of Atlantic Forest. Its creation aims to protect the Atlantic Forest remnants and regeneration of degraded areas. The present work develops in the administrative center Núcleo Santa Virgínia, created on May 2, 1989 and aims a comparative analysis and environmental interpretation regarding the evolution of the landscape its creation until the present days, using geoprocessing techniques. For a better understanding of some definitions, a literature review is presented about the current scenario of conservation units, concepts of landscape, landscape ecology, landscape dynamics and the importance of the geoprocessing for landscape analysis. It was elaborated two thematic charts of use and occupation land of Núcleo Santa Virgínia (1989 and 2014) and quantified for each type of use for later comparison

Uso do modelo de simulação 'ABC 6' para avaliação de áreas sujeitas à ocorrência de ondas de cheia e corridas de massa/detritos: estudo de caso na bacia do Ribeirão da Prata (SP)

Pipelines are linear engineering works, designed mostly for transporting oil and its derivatives for long distances, furnishing even the farthermost zones of the country. Due to oil sector needs to ensure for the safety and conservation of its properties, several geotechnical studies are being held at the pipelines field, in order to preserve this important transportation, and also to prevent accidents, which might seriously compromise the environment and the population who lives around it. The OSBRA pipeline, who connects the city of Paulínia to the capital Brasília, is one of these engineering works that deserves to be pointed out. This research, performed at the Ribeirão da Prata Basin, was a pilot study conducted with the main objective of testing the current methodology efficiency, for future applications in the closest watersheds to the OSBRA pipeline. The objective of this research is to analyze flood wave and debris flow processes in a non-fictional watershed, by comparing two different kinds of methods: the first one based on simulation models (software ‘ABC 6’), and the other one by flood wave and debris flow susceptibility mapping. The results from the hydrological modeling were both hydrographs and ietographs that estimated values of outputs and infiltration. To construct the susceptibility maps were necessary three other maps: ground use and occupation maps, divided according to the different protection degrees that were offered to the ground; maps of dam locations in the area and physiographic compartimentation maps, divided according to the local geology. To complete the methodology, the results were collected from both methods for comparison. The obtained product for this methodology was series of data whose different susceptibility degrees to flood wave and debris flow could define the safest route for a pipeline crossing in this watershed...

Elaboração de mapa de susceptibilidade de corridas de massa/detritos e ondas de cheia, aplicado a empreendimentos dutoviários, na bacia hidrográfica do Ribeirão da Prata (SP)

Given the intense expansion of the industries in Brazil and the discovery of hydrocarbons in the pre-salt layer of the Santos and Campos Basin, there is a need to expand the distribution of oil and gas network in the country. The present work aims to present the development of susceptibility map by two distinct methods of two events (debris flows and full wave), applied to the establishment of pipelines on Ribeirão da Prata Basin. The research area covers two municipalities: São João da Boa Vista and Águas da Prata, in total 145 km2. In the paper was used the methodology proposed by Zaine (2011) for the physiographic subdivision method, which uses geological maps, geomorphological maps, digital terrain models and aerial photographs, used to extract the main elements of the physical environment, as rivers, lines, ridges, tops forms and valley forms and historical processes. Thus, the basin was divided into 11 physiographic zones, considering the following elements: thickness of soil, rock type, geomorphology, amplitude, ridges orientation, erosion occurences and mass movements. Were subsequently performed location maps of dams, that had as main purpose to localize major dams in the study area along with their area and perimeter of the reservoir, and land use map that subdivided the area in woody vegetation, permanent culture, temporary culture and urban area. Along with the preparation of the auxiliar maps was conducted a field campaign with three days and approximately 2 points per km2, which aimed to better understand the physical environment and check the main peculiarities of the study area. Criteria have been established for susceptibility maps physiographic subdivision and land use, and a survey of criteria weights used in each map for both processes under study. For the preparation of susceptibility maps were adopted two different methods, which treat the weighted average and the multiplicand. The weighted average method it is...

Diagnóstico geoambiental e avaliação de risco à saúde humana para uma área industrial contaminada por hidrocarbonetos localizada no município de Paulínia (SP)

This paper deals with a case study of assessing risk to human health, with the study area of an industrial site in the city of Paulinia (SP) contaminated by oil, which is disturbing situation that occurs in the state of Sao Paulo, which represents risks for human health, as toxic and carcinogenic potential of petroleum products. As an essential foundation for risk assessment, a Geo-environmental diagnosis of the region was made, posing as historical information of the area and accidents, regional geology and hydrogeology, characterization of contaminants and affected media, contaminant transport and data on potential receptors and pathways. Because of the detection of contaminants above the intervention values CETESB (2005) it was possible to proceeded to quantify risks to human health and the determination of maximum acceptable concentrations for no damage to health, using the methodology and software RBCA Tier 2 (ASTM , 1998) and Spreadsheet Risk Assessment recently published by CETESB. The results showed the risk to the health of industrial workers and regular employees of civil works (both on site) for ingestion of groundwater and inhalation of vapors indoors.

Avaliação da toxicidade sobre Ceriodaphnia dubia das águas dos rios Atibaia, Jaguari e efluente tratado de refinaria de petróleo

Ensuring availability of quality water for human consumption causes becomes an increasing number of studies for the analysis of effluent before and after treatment, so that its release into receiving bodies do not cause significant changes in the river water and on the biological communities related to them. The biomarkers of toxicity have long been used to verify the potential toxic effluent and its correlation with the treatment efficiency of them. In this context, the cladoceran Ceriodaphnia dubia stands out because it is a benthic aquatic organism highly sensitive to environmental changes. In this study, to evaluate the interference of the release of treated wastewater of oil refinery in Rio Atibaia, we sought to determine the toxicity on population dynamics of Ceriodaphnia dubia microcrustacean in water samples upstream and downstream from the launch site, compared with samples from Rio Jaguarí at the point of capture by the company itself and treated effluent. We have studied the number of offspring produced in 10 replicates, each starting with a test individual of up to 24 hours for each sample and correlated the results with physical-chemical and microbiological tests performed by a laboratory technician. For most tests, the results indicate that the treated effluent gives sub-lethal toxicity to the microcrustacean, as delay the onset of the reproductive cycle of the same

Utilização de parâmetros qualitativos dos resíduos aterrados como referência no processo de seleção de valores empregados em modelos matemáticos para a estimativa de geração de metano

The study of mathematical modeling assists in evaluation of the capacity of production and measurement of generation time of biogas in landfills, enabling the implantation of projects of energy generation from methane. Thus, the work aims, by simulating scenarios of potential methane generation in the landfill in Rio Claro, the use of field data from methane flow and waste grounded parameters as references for selecting values of k e L0 used to estimate methane generation model in LandGEM. As a result it was found that compared the characteristics adopted in the four scenarios recommended by the USEPA literature with those found in the landfill of Rio Claro (high amount of organic matter in the waste landed and daily practice of leachate recirculation), the scenario that apparently better represent the rate of methane generation is the scenario 01, with k = 0.7 and L0 = 96. Now, the adjustment of parameters in relation to the data field of methane flow, the value of L0 which best fits the methane generation from the landfill in Rio Claro is 150, while for k the line behavior that best represents the reality are values between 0.7 and 0.3. Regarding the parameters of the waste grounded, between the suggested values of k, 0,3 is most consistent with the intermediate level of biological degradation of the residue grounded, while L0 due to the biodegradability of the waste, a new value between 120 and 150 may be more appropriate for the study

Proposta de traçado de alcoolduto ligando a hidrovia Tietê Paraná à refinaria do planalto paulista com uso de avaliação multicritérios e geotecnologias

From the beginning of the century, with the advent of the flex fuel car, successor fluctuations in oil prices and the rise of awareness of the impending shortage of fossil fuels, the alcohol sector begins to reappear in the panorama of national economy making Brasill reaches the point of becoming a leading exporter of this product. Ethanol assumed the role of such importance in Brazilian exports, which Petrobras through the Growth Acceleration Program (PAC) has made investments in the Brazilian pipeline network to better ensure the production of ethanol to major ports. The means of transport in pipelines are safe and inexpensive, but require careful evaluation in its implementation, they may lead to negative social and environmental impacts. Thus, the purpose of this project is to propose the best route for an ethanol pipeline connectin the Tietê-Paraná, leaving the municipality of Santa Maria da Serra (SP), to the Planalto Paulista Refinery (REPLAN), located in Paulinia (SP), belonging to the passage of ethanol export corridor, currently under revelopment. The technique used for the development of the stroke is the association of multicriteria evaluation, the geographical information system (SIG) and geotechnologies. This study presented three possible layouts for the ethanol pipeline, highlighting the best option, in addition, demonstrated the suitability of the area to receive projects of similar nature to a pipeline

Estudo da tratabilidade de água pluvial utilizando coagulante natural a base de tanino visando fins não potáveis

This paper aimed to study the treatability of rainwater collected in Rio Claro, SP, using natural coagulant tannin based. The tannin was compared with other too primary coagulants, namely ferric chloride and corn starch. Assays were performed in laboratory scale using equipment known as Jarteste and aimed to study the conditions most suitable dosage and coagulation pH. First tests were conducted to compare the coagulating and determination of the conditions to be used in the following tests, taking as a criterion the greatest efficiency for water treatment. Also performed were performed tests to construct the tannin coagulation diagram, using the optimal concentration found in the previous phase, by varying the dosage of coagulant and the pH of clotting in order to determine the isoefficiency regions for apparent color and turbidity. Finally, tests were performed cyclically filtration with filter paper. Preliminary tests indicated that the vegetable tannin concentration 3% (m/m) from the commercial solution was presented the best set of results (84.3% removal of apparent color and 82.51% removal of turbidity) compared to ferric chloride (66.25% removal efficiency and apparent color of turbidity 67.82%) and starch (73.68% removal efficiency apparent color and turbidity to 67.19%). The coagulation diagrams indicate that the best region to work with vegetable tannin 3% is where the coagulant dosage ranges from 15 mg/L to about 37.5 mg/L and coagulation pH ranging from about 6.5 to 7.5. The cyclic filtration showed to be not efficient for the best dosage of coagulant, due to the process of clogging of the filter paper, but proved to be efficient for other dosages. Thus, for the waters studied, the results indicate that the natural coagulant based tannin is an alternative to conventional coagulants, possessing benefits of technical and environmental

Aplicação do método AHP para hierarquização de condicionantes de corrida de massa

Among the flow, the flows have the highest destructive potential, may cause disasters with a very high number of victims, as recorded in the events Caraguatatuba (SP) and the Serra das Araras (RJ) in 1967; Valeu do Rio Figueira, in Timbé do Sul (SC) between 1995 and 1996; Vale do Itajaí in Santa Catarina, in 2008, Teresópolis, Petrópolis and Nova Friburgo (RJ), in December 2010 and January 2011. This project aimed to prioritize the main determinants of inducing processes of debris flows by applying the method of decision making AHP (Analytical Hierarch Process). Therefore, the following stages of work were defined: research of the major factors of debris flows, questionnaire design method for application of AHP expert on the subject, analysis of the results obtained from calculating the ratio of consistency and preparation of proposal for hierarchical of conditions for debris flows. From the surveys it was possible to establish a relationship of conditions according to the scale of work, defining three levels: regional (1:250,000 to 1:100,000), Semi-Detail (1:50,000 to 1:25,000) and Detail (1: 10,000 or higher). The factors found were: concentration time, the flood wave, rain, landslide susceptibility (slope), drainage and development in the deposition. The project analyzed the results obtained from the questionnaires, which allowed the ranking of the constraints, contributing to weight constraints in studies of multicriteria mapping of susceptibility to the occurrence of debris flows. The study showed that the most of the analyzed datas were inconsistent because of the different opinion of the judges

Zoneamento acústico urbano e mapeamento de níveis sonoros na zona central de Rio Claro (SP): diretrizes para o gerenciamento do ruído integrado ao planejamento ambiental urbano

Considering the growing degradation of the urban environmental quality resulting from the progressive sound pollution increase, as well as the consequent harmful effects about the human health, the present study had its central objective the argument and management tools implementation of the urban noise that can be integrated to the environmental planning in the city of Rio Claro (SP). Therefore, normative and bibliographical revisions were developed, that made feasible the directives of control argument and prevention of the urban noise, as well as the technical procedures of sound levels and evaluation’s definition and especially about the criteria applicable for the elaboration of an urban acoustic zoning methodology. Among the main results obtained detach: (1) the applicable legislation to the management of urban noise’s synthesis and argument; (2) the methodology of urban acoustic zoning development and (3) its implementation to determined areas of Rio Claro (SP) with the (4) respective cartography representation; (5) the mapping of sound levels in the central zone of Rio Claro (SP), (6) the obtaining and analysis of noise describers (LAeq, Lmáx, L10, L50, L90, Lmin and TNI) and the subsequent (7) acoustic maps elaboration for the main describers.

Mapeamento do uso da terra como subsídio a um plano de recuperação das áreas de preservação permanente no entorno da represa de Salto Grande - Americana - SP

Currently, the dam of Salto Grande is very degraded. Water quality is seriously amended, and lack of riparian vegetation, as well as the advance of feed crops and land occupation in areas that should be permanently preserved, only complicate this situation. The permanent preservation area is essential for the water sources protection, soil erosion control and consequent watercourse sedimentation. Through aerial photography, using GIS techniques, it was able to identify the outwards bounds of the dam, to demarcate the permanent preservation areas and generate maps for land use. With this data, in addition to studies and ideas of reforestation in different environments, the development of a plan for restoration of degraded areas surrounding the dam is easier to be done. This study confirmed that about 72% of land use in permanent preservation areas is not in accordance with specific laws, making necessary its recovering.