960 resultados para Adorno, Theodor Wiesengrund
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Aim. By taking nursing as a human relationships activity, in spite of its strong technical-scientific features, this article reflects on the phenomenological method as one of the ways to develop ail investigation and acquire knowledge of the topic.Rationale. Based on Husserl's phenomenology, which is opposed to the way of doing science based on the laws that regulate the physics and mathematics, the article introduces Merleau Ponty's existential phenomenology as the theoretical foundation for the method it proposes. My existential conceptions-people as historic beings inserted in a world over which they act but which, in its turn, determines them; the human perception as reference for our way of being in the world; the space-time structure of perception-these are the key concepts that have led to the elaboration of ail approach to phenomenological research.Proposal of a methodology. Steps are proposed for such ail approach, namely phenomenological description, reduction and analysis. These lead to the building up of ideographic and nomothetic analyses, thus unveiling and describing general truths about the phenomenon studied. Finally, the possibilities for applying the methodology to nursing research are discussed, illustrated by my research into student nurses' perspectives on working oil an isolation ward.
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The influence of silver additions on the Cu-13 wt. pot. Al alloy hardness was studied for additions in the range 0 to 16 wt. pot Ag. The results indicated a pronounced hardness increase with the silver content and an influence of the quenching temperature. Data obtained from scanning electron microscopy indicated that the formation of silver-rich precipitates, wich change with the quenching temperature, seems to produce the changes on alloys hardness.
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The influence of additions of 2, 4, 6, 8, 10 and 12 mass% Ag on the thermal behavior of the Cu-8 mass% Al alloy was studied using differential scanning calorimetry (DSC), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and X-ray diffractometry (XRD). The results indicate that the presence of silver introduces new thermal events, due to the formation of a silver-rich phase and, for additions of 10 and 12 mass% Ag, it is possible to verify the formation of the gamma (1) phase (Cu9Al4) and the metastable transitions which are only observed in alloys with a minimum of 9 mass% Al.
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The kinetics of eutectoid decomposition beta(1)' --> gamma(2) + (alpha + gamma(2)) in Cu-12.86 wt% Al and Cu-12.84 wt% Al-1.98 wt% Ag alloys was studied by hardness measurements, using the Johnson-Mehl-Avrami equation. The results indicate that the presence of silver seems to influence the nucleation rate and the activation energy of the reaction.
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A new series of high temperature copper based shape memory alloys has recently been patented. These alloys contain 8-20 wt% Al, 1-20 wt% Ag, 0-2 wt% of a minor element (preferably Co), balance copper. The martensitic start transformation temperatures of these alloys are above 200 degrees C and, in some cases, they have good high temperature stability and may be useful in commercial applications where higher operating temperatures than those obtained from Cu-Zn-Al and Cu-Al-Ni shape memory alloys are required.
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The electrochemical behavior of Cu-xAl alloys, with 11 wt%less than or equal to x less than or equal to 15wt%, in 0.5 M H2SO4 was studied by means of open-circuit potential decay measurements, quasi-stationary and fast cyclic voltammetry, and electrochemical impedance spectroscopy. Some of the alloys (x less than or equal to 14%), when quenched formed martensitic structures. Alloys with greater than or equal to 13% showed a little square-shaped phase when quenched from temperatures around 800 degrees C. It was observed that in sulfuric medium, these formations were dealuminized differently than the martensitic phase. The values of the rest potentials are more influenced by the heat treatment rather than by the alloy composition. An anodic Tafel slope of ca. 60 mV/decade was observed for all the alloys, independently of the heat treatment. This is explained in terms of a competition between two processes: copper oxidation and copper(I) deproportionation. In the cyclic voltammetric experiments it was observed an anodic current peak, related with copper oxidation with a possible formation of some interfacial species, and a cathodic current peak during the reverse potential scan, associated with the reduction of soluble species and/or of the film. The AC Impedance data were interpreted in terms of electric equivalent circuits.
MECHANICAL-PROPERTIES AND PRECIPITATION ENERGY OF THE CU-AL-AG (5.4-PERCENT-AL-5.2-PERCENT-AG) ALLOY
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Thermal behavior of alpha-(Cu-Al-Ag) alloys, i.e. alloys with composition less than about 8.5 mass% Al, was studied using differential scanning calorimetry (DSC), differential thermal analysis (DTA), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and X-ray diffractometry (XRD). The results indicated that the presence of silver introduces new thermal events ascribed to the formation of a silver-rich phase and, after addition higher amounts than 8 mass% Ag to the Cu-8 mass% Al alloy it is possible to observe the formation of the gamma(1) phase (Al4Cu9), which is only observed in alloys containing minimum of 9 mass% Al. These results may be attributed to some Ag characteristics and its interaction with Cu and Al.
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In this work the effect of Ag concentration on the thermal behavior of the Cu-10 mass% Al and Cu-11 mass% Al alloys with additions of 4, 6, 8 and 10 mass% Ag was studied using differential scanning calorimetry (DSC), in situ X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The results showed that for the Cu-10 mass% Al alloy Ag addition induce the beta'(1) phase formation and for the Cu-11 mass% Al alloy these additions increase the amount of martensite formed on quenching and decrease the stability range of this phase on heating.
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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The completeness of beta-phase decomposition reaction in the Cu-11wt%Al-xwt%Ag alloys (x = 0, 1, 2, and 3) was studied using differential scanning calorimetry (DSC), X-ray diffractometry (XRD), and optical microscopy (OM). The results indicated that beta-phase transformations are highly dependent on cooling rate and on the presence of Ag. on slow cooling, the silver presence prevents the beta- and beta(1)-phase decomposition; thus, inducing the martensitic phase formation. After rapid cooling, a new thermal event is observed and the reverse martensitic transformation is shifted to lower temperatures.
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In this work the influence of Ag additions on the thermal behavior of the Cu-11 mass% Al alloy was studied using differential scanning calorimetry, in situ X-ray diffractometry and scanning electron microscopy. The results indicated that changes in the heating rate shift the peak attributed to alpha phase formation to higher temperatures, evidencing the diffusive character of this reaction. The activation energy value for the alpha phase formation reaction, obtained from a non-isotherm kinetic model, is close to that corresponding to Cu atoms self diffusion, thus confirming that this reaction is dominated by Cu atoms diffusion through the martensite matrix.
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In this work the (alpha + gamma(1)) complex phase formation reaction in the Cu-10mass% Al-6mass% Ag alloy was studied using Differential Scanning Calorimetry (DSC), Differential Thermodilatometry (DTD), X-ray diffractometry (XRD), Optical (OM) and Scanning Electron Microscopies (SEM). The results indicated the presence of two different processes, related to a change in the Ag diffusion route from the alpha matrix to the (alpha + gamma(1)) complex phase.
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The Ag-rich phase precipitation in the Cu-9 mass% Al was studied using differential scanning calorimetry (DSC), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The results indicated that Ag additions did not interfere on the metastable transitions sequence of the Cu-mass% Al alloy but Ag precipitation disturbs the beta phase formation reaction and the martensitic phase decomposition reaction.