Data on the biogeochemical cycle of methane in the ocean

Geological, mineralogical and microbiological aspects of the methane cycle in water and sediments of different areas in the oceans are under consideration in the monograph. Original and published estimations of formation- and oxidation rates of methane with use of radioisotope and isotopic methods are given. The role of aerobic and anaerobic microbial oxidation of methane in production of organic matter and in formation of authigenic carbonates is considered. Particular attention is paid to processes of methane transformation in areas of its intensive input to the water column from deep-sea hydrothermal sources, mud volcanoes, and cold methane seeps.

(Table 1) Mineral phosphorus contents in bottom sediments and interstitial waters of the Southeast Atlantic

Concentrations of mineral phosphorus in interstitial waters from sediments of the Southeast Atlantic generally increases from the ocean bed to the continental slope and shelf. In diatomaceous oozes of the Southwest Africa shelf, phosphorus concentration in fresh interstitial waters reaches 2.5 mg/l in absence of phosphorite concretions and 0.1-0.7 mg/l in their presence. After prolonged storage of samples concentration of dissolved mineral phosphorus sometimes increases up to 7-8 mg/l. The key factor regulating phosphorus content of solid and liquid phases of unaltered sediments are content and composition of organic matter.

Geochemical and biogeochemical parameters of Black Sea waters and suspended matter

The monograph focuses on the analysis of data addressing the problem of H2S contamination and oxic-anoxic interface in the Black Sea. Regularities of the fine structure of vertical distribution of oxygen, hydrogen sulfide, biogenic elements, organic substances, suspended matter, and metals of the iron-manganese group in the area of contact of aerobic and anaerobic waters have been revealed. Also effects of biochemical, physico-chemical and dynamic processes on their vertical distribution have been examined. Sulfate reduction in seawater and bottom sediments has been studied. Quantitative estimates of H2S fluxes at the water - bottom sediment and O2-H2S interfaces have been done. Features of H2S oxidation have been studied, its budget in the Black Sea has been calculated. Multiyear spatial-temporal variability of the oxic-anoxic interface has been investigated.