846 resultados para Gibbs isotherm


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Optical instabilities in the output light from a bistable optical device (BOD) with a delayed feedback was predicted by Ikeda [1]. Gibbs et al. [2] gave the first experimental verification of this type of instabilities. From that time several groups have studied the instabilities of the BOD for different relations between the delay time tR and the time constant ح of the system. In a previous paper [3] an empirical and analytical study of instabilities in hybrid BOD was reported by us. The employed set up is shown in Fig. 1.

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As it is well known from the work by Gibbs et al., optical turbulence and periodic oscillations are easily seen in hybrid optical bistable devices when a delay is added to the feedback. Such effects, as it was pointed out by Gibbs, may be used to convert cw laser power into a train of light pulses.

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Since the observation of optical bistability by Gibbs et al., optical bistability has been the field where researchers from many fields have found a common place to work. More recently, when Ikeda and co-workers discussed the effect of a delayed feedback on instability of a ring cavity containing a non linear dielectric medium, and pointed out that the transmitted light from the ring cavity can be periodic or chaotic in time under a certain condition, optical bistable devices have shown new possibilities to be applied in many different fields. The novel phenomenon has been predicted to be observed in the hybrid optical device and has been confirmed by Gibbs et al. Moreover, as we have shown, a similar effect can be obtained when liquid crystal cells are employed as non linear element.

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Moment invariants have been thoroughly studied and repeatedly proposed as one of the most powerful tools for 2D shape identification. In this paper a set of such descriptors is proposed, being the basis functions discontinuous in a finite number of points. The goal of using discontinuous functions is to avoid the Gibbs phenomenon, and therefore to yield a better approximation capability for discontinuous signals, as images. Moreover, the proposed set of moments allows the definition of rotation invariants, being this the other main design concern. Translation and scale invariance are achieved by means of standard image normalization. Tests are conducted to evaluate the behavior of these descriptors in noisy environments, where images are corrupted with Gaussian noise up to different SNR values. Results are compared to those obtained using Zernike moments, showing that the proposed descriptor has the same performance in image retrieval tasks in noisy environments, but demanding much less computational power for every stage in the query chain.

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This paper provides an overview of an ongoing research project work: “A Polytechnical Bilingual Dictionary of Metaphors: Spanish-English/English-Spanish” done by the UPM consolidated research group “DISCYT” (Estudios Cognitivos del Discurso Científico-Técnico). A detailed explanation of the method adopted to identify key metaphors collected from the different subject areas is included. Drawing from recognized empirical methods (Pragglejaz 2007, Cameron 2007, Steen 2007), the examples have been examined according to the main tenets of conceptual metaphor and conceptual integration theory (Deignan 2005, Gibbs 2008, Lakoff 1993, Lakoff & Johnson 1999, Steen 2007, Fauconnier & Turner 2008). This forthcoming dictionary comprises metaphors of over 10 scientific and technical areas such as Aeronautical engineering, Agronomy, Architecture, Biotechnology, Civil engineering, Geology and Mining, Mechanical engineering, Nanotechnology, Naval and Maritime engineering, Sports and Telecommunications. In this paper, we focus on the study of examples taken from civil engineering, materials engineering and naval engineering. Representative cases are analyzed from several points of view (multimodal metaphor, linguistic information strategies and translation into target language) highlighting cross linguistic variations between Spanish and English.

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DELLA proteins are the master negative regulators in gibberellin (GA) signaling acting in the nucleus as transcriptional regulators. The current view of DELLA action indicates that their activity relies on the physical interaction with transcription factors (TFs). Therefore, the identification of TFs through which DELLAs regulate GA responses is key to understanding these responses from a mechanistic point of view. Here, we have determined the TF interactome of the Arabidopsis (Arabidopsis thaliana) DELLA protein GIBBERELLIN INSENSITIVE and screened a collection of conditional TF overexpressors in search of those that alter GA sensitivity. As a result, we have found RELATED TO APETALA2.3, an ethylene-induced TF belonging to the group VII ETHYLENE RESPONSE FACTOR of the APETALA2/ethylene responsive element binding protein superfamily, as a DELLA interactor with physiological relevance in the context of apical hook development. The combination of transactivation assays and chromatin immunoprecipitation indicates that the interaction with GIBBERELLIN INSENSITIVE impairs the activity of RELATED TO APETALA2.3 on the target promoters. This mechanism represents a unique node in the cross regulation between the GA and ethylene signaling pathways controlling differential growth during apical hook development.

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Adaptive Rejection Metropolis Sampling (ARMS) is a wellknown MCMC scheme for generating samples from onedimensional target distributions. ARMS is widely used within Gibbs sampling, where automatic and fast samplers are often needed to draw from univariate full-conditional densities. In this work, we propose an alternative adaptive algorithm (IA2RMS) that overcomes the main drawback of ARMS (an uncomplete adaptation of the proposal in some cases), speeding up the convergence of the chain to the target. Numerical results show that IA2RMS outperforms the standard ARMS, providing a correlation among samples close to zero.

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La gasificación de lodos de depuración consiste en la conversión termoquímica del lodo por oxidación parcial a alta temperatura mediante un agente gasificante, que generalmente es aire, oxígeno o vapor de agua. Se trata de una tecnología de gran interés, ya que consigue reducir la masa de estos residuos y permite el aprovechamiento de los gases formados, tanto en la generación de energía térmica y/o eléctrica como en la síntesis de productos químicos orgánicos y combustibles líquidos. Debido a la complejidad de este proceso, es útil el uso de modelos que faciliten su estudio de forma fiable y a bajo coste. El presente Proyecto Fin de Carrera se centra en el diseño de un modelo adimensional de equilibrio en estado estacionario basado en la minimización de la energía libre de Gibbs. Para ello, se ha empleado el software de simulación de procesos Aspen Plus, que posee una amplia base de datos de propiedades físicas y permite gran flexibilidad en el manejo de sólidos. Para la elaboración del modelo se han asumido las hipótesis de mezcla perfecta dentro del reactor y operación isoterma. El gasificador se ha considerado de lecho fluidizado burbujeante, al permitir un buen control de la temperatura y una alta transferencia de materia y energía entre el sólido y el agente gasificante. El modelo desarrollado consta de cuatro etapas. La primera reproduce el proceso de pirólisis o descomposición térmica de los componentes del lodo en ausencia de agente gasificante. En la segunda etapa se simula que todo el nitrógeno y el azufre contenidos en el lodo se transforman en amoniaco y ácido sulfhídrico, respectivamente. En la tercera etapa se produce la gasificación en dos reactores. El primer gasificador alcanza el equilibrio químico mediante la minimización de la energía libre de Gibbs del sistema. En el segundo reactor se establece un equilibrio restringido por medio de la especificación de una aproximación de temperatura para cada reacción. Este método permite validar los resultados del modelo con datos reales. En la última etapa se separa el residuo carbonoso o char (compuesto por carbono y cenizas) del gas de salida, formado por N2, H2, CO, CO2, CH4 (supuesto como único hidrocarburo presente), NH3, H2S y H2O. Este gas debe ser depurado mediante equipos de limpieza aguas abajo. Los resultados de la simulación del modelo han sido validados frente a los valores obtenidos en ensayos previos llevados a cabo en la planta de gasificación a escala de laboratorio ubicada en el Departamento de Ingeniería Química Industrial y del Medio Ambiente de la Escuela Técnica Superior de Ingenieros Industriales de la Universidad Politécnica de Madrid. Estos resultados han mostrado muy buena concordancia con los obtenidos experimentalmente, con un error inferior al 7% en todos los parámetros analizados en el caso de gasificación con aire y menor al 13% cuando se utiliza una mezcla aire/vapor de agua como agente gasificante. Se ha realizado un análisis de sensibilidad con el fin de estudiar la influencia de las condiciones de operación (temperatura, ratio equivalente y ratio vapor/biomasa) sobre los resultados del proceso modelado (composición, producción y poder calorífico inferior de los gases, conversión de carbono y eficiencia de la gasificación). Para ello, se han llevado a cabo diferentes simulaciones modificando la temperatura de gasificación entre 750ºC y 850ºC, el ratio equivalente (ER) entre 0,2 y 0,4 y el ratio vapor/biomasa (S/B) entre 0 y 1. Como ya ocurriera con la validación del modelo, los resultados de las simulaciones bajo las distintas condiciones de gasificación se ajustan de forma satisfactoria a los valores experimentales. Se ha encontrado que un aumento en la temperatura mejora la cantidad y la calidad del gas producido y, por tanto, la eficiencia del proceso. Un incremento del ratio equivalente reduce la concentración de CO y H2 en el gas y, en consecuencia, también su poder calorífico. Sin embargo, valores bajos del ratio equivalente disminuyen la producción de gases y la conversión de carbono. La alimentación de vapor de agua en el sistema mejora todos los parámetros analizados. Por tanto, dentro del rango estudiado, las condiciones de operación que optimizan el proceso de gasificación de lodos consisten en el empleo de mezclas aire/vapor de agua como agente gasificante, una temperatura de 850ºC y un ER de 0,3.

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El objetivo principal de este Proyecto Fin de Grado es el estudio experimental de la atenuación, producida por las precipitaciones, en los enlaces Tierra – satélite en banda Ka. En particular, se ha realizado el estudio para una frecuencia de 19,701 GHz, que corresponde con la frecuencia de una de las balizas del satélite Hot Bird 13 de Eutelsat. Para la realización del estudio se dispone de datos experimentales recogidos por sondeos realizados en la estación meteorológica de Madrid - Barajas y de datos sinópticos. La primera parte del proyecto comienza con una descripción de los fundamentos teóricos de los distintos fenómenos que afectan a la propagación en un enlace por satélite, y se enumeran los distintos modelos de predicción más importantes. Posteriormente se describen en más detalle algunos modelos de predicción propuestos por la Unión Internacional de Telecomunicaciones (UIT). En la segunda parte del mismo se explica en detalle el proceso necesario para el procesado de los datos experimentales, con el fin de poder manejarlos de forma más sencilla a la hora de presentar los resultados pertinentes. En una tercera parte se recogen los resultados experimentales obtenidos para el caso de la altura de la isoterma a 0˚C y de la atenuación por lluvia. El capítulo dedicado al estudio de la altura de la isoterma a 0˚C se centra en obtener dicho dato a partir de los datos experimentales de los sondeos, que fueron procesados con anterioridad. Así mismo, se realizará una comparativa de estos datos experimentales con los proporcionados por la UIT en la Recomendación 839. En el capítulo dedicado al estudio de la atenuación producida por la lluvia se compararán los resultados obtenidos de forma experimental con los datos proporcionados por la UIT en la Recomendación 618. Por último se recoge en un capítulo las conclusiones obtenidas con la realización de este PFG y las líneas futuras de investigación. ABSTRACT. The main aim of this Final Degree Project is the experimental study of attenuation by precipitation, in links Earth – Ka band satellite. In particular, the study was performed at a frequency of 19.701 GHz, which corresponds to the frequency of one of the beacons of the satellite Hot Bird 13 (Eutelsat). There is experimental data and synoptic data provided, which was collected from surveys in the Madrid- Barajas weather station. The first part of the project outlines some theoretical foundations regarding different phenomena which affect propagation in a satellite link and includes the most important prediction models. Additionally, some prediction models proposed by the International Telecommunication Union (ITU) are outlined in detail. In the second part, the process for the processing of the experimental data is explained in detail. This process is necessary in order to be able to utilize the data more easily when presenting the results of this project. In the third part, the experimental results obtained in the study are presented for both cases: isotherm height at 0°C and rain attenuation. The chapter dedicated to the study of the isotherm height at 0°C focuses on obtaining the real isotherm height at 0°C from the experimental data processed previously. Furthermore, a comparison will be made between the experimental results and data proposed by ITU in Recommendation 839. The chapter dedicated to the study of rain attenuation focuses on making a comparison between the results from the experimental data and data proposed by ITU in Recommendation 618. Finally, there is a chapter which revises all the conclusions obtained throughout this project and provides recommendations for future research.

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To get a better understanding of mutagenic mechanisms in humans, we have cloned and sequenced the human homolog of the Saccharomyces cerevisiae REV3 gene. The yeast gene encodes the catalytic subunit of DNA polymerase ζ, a nonessential enzyme that is thought to carry out translesion replication and is responsible for virtually all DNA damage-induced mutagenesis and the majority of spontaneous mutagenesis. The human gene encodes an expected protein of 3,130 residues, about twice the size of the yeast protein (1,504 aa). The two proteins are 29% identical in an amino-terminal region of ≈340 residues, 39% identical in a carboxyl-terminal region of ≈850 residues, and 29% identical in a 55-residue region in the middle of the two genes. The sequence of the expected protein strongly predicts that it is the catalytic subunit of a DNA polymerase of the pol ζ type; the carboxyl-terminal domain possesses, in the right order, the six motifs characteristic of eukaryotic DNA polymerases, most closely resembles yeast pol ζ among all polymerases in the GenBank database, and is different from the human α, δ, and ɛ enzymes. Human cells expressing high levels of an hsREV3 antisense RNA fragment grow normally, but show little or no UV-induced mutagenesis and are slightly more sensitive to killing by UV. The human gene therefore appears to carry out a function similar to that of its yeast counterpart.

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DNA polymerase δ (pol δ) plays an essential role in DNA replication, repair, and recombination. We have purified pol δ from Schizosaccharomyces pombe more than 103-fold and demonstrated that the polymerase activity of purified S. pombe pol δ is completely dependent on proliferating cell nuclear antigen and replication factor C. SDS/PAGE analysis of the purified fraction indicated that the pol δ complex consists of five subunits that migrate with apparent molecular masses of 125, 55, 54, 42, and 22 kDa. Western blot analysis indicated that the 125, 55, and 54 kDa proteins are the large catalytic subunit (Pol3), Cdc1, and Cdc27, respectively. The identity of the other two subunits, p42 and p22, was determined following proteolytic digestion and sequence analysis of the resulting peptides. The peptide sequences derived from the p22 subunit indicated that this subunit is identical to Cdm1, previously identified as a multicopy suppressor of the temperature-sensitive cdc1-P13 mutant, whereas peptide sequences derived from the p42 subunit were identical to a previously uncharacterized ORF located on S. pombe chromosome 1.