(Figure 2, page 940) K-T boundary enrichment for cerium and iridium chemical composition of layers inside the ZETES-3D manganese nodule in the Pacific Ocean

Hydrogenous manganese nodules form on the ocean floor by slow authigenic precipitation (1-6 mm/Ma) of the oxyhydroxides of manganese and iron that continuously scavenge trace elements from the marine environment. Consequently, these nodules represent independent marine deposits useful for the study of the chemical signatures of the paleomarine environments. The results presented are a continuation of a study of the Zetes-3D nodule from the Pacific Ocean. It is a large (24x17x10 cm) hydrogenous nodule whose slow growth rate of 1.3 mm/Ma was detremined using 10Be techniques. A positive cerium anomaly is observed throughout the nodule and its Ir content indicates a sharp spike at 54-62 Ma in fair agreement with the K-T event.

(Appendix A) Oxygen and carbon isotope results of detrital carbonate grains of Heinrich layers from HU90-013-028 and IODP Sites 303-U1302/U1303/U1308 in the North Atlantic Ocean

We report oxygen and carbon isotope results of detrital carbonate grains from Heinrich layers at three sites in the North Atlantic located along a transect from the Labrador Sea to the eastern North Atlantic. Oxygen isotopic values of individual detrital carbonate grains from six Heinrich layers at all sites average - 5.6 ppm ± 1.5 ppm (1sigma; n = 166), reflecting values of dolomitic limestone derived from source areas in northeastern Canada. The d18O of bulk carbonate at Integrated Ocean Drilling Program (IODP) Site U1308 (re-occupation of Deep Sea Drilling Project (DSDP) Site 609) in the eastern North Atlantic records the proportion of detrital to biogenic carbonate and d18O decreases to - 5 ppm during Heinrich (H) events 1, 2, 4 and 5 relative to a background value of ~ 1 to 2 ppm for biogenic carbonate. Bulk d18O also decreases during H3 and H6 but only attains values of - 1ppm, indicating either a greater proportion of biogenic-to-detrital carbonate or a different source. Because the d18O of detrital carbonate is ~ 9 ppm lower than foraminifer carbonate, any fine-grained detrital carbonate not removed from the inner test chambers will lower foraminifer d18O. We conclude bulk carbonate d18O is a sensitive proxy for detrital carbonate and may be useful for identifying Heinrich layers in cores within and near the margins of the North Atlantic ice-rafted detritus (IRD) belt.

Sea surface temperatures, alkenones and sedimentation rates at the Alboran basin

Sea surface temperatures (SSTs) recorded by alkenones and oxygen isotopes in the Alboran basin are used here to describe, at an unprecedented fine temporal resolution, the present interglaciation (PIG, initiated at 11.7 ka BP), the last interglaciation (LIG, onset approximately at 129 ka) and respective deglaciations. Similarities and dissimilarities in the progression of these periods are reviewed in comparison with ice cores and stalagmites. Cold spells coeval with the Heinrich events (H) described in the North Atlantic include multi-decadal scale oscillations not previously obvious (up to 4 °C in less than eight centuries within the stadials associated with H1 and H11, ca 133 ka and 17 ka respectively). These abrupt oscillations precede the accumulation of organic rich layers deposited when perihelion moves from alignment with NH spring equinox to the summer solstice, a reference for deglaciations. Events observed during the last deglaciation at 17 ka, 14.8 ka and 11.7 ka are reminiscent of events occurred during the penultimate deglaciation at ca 136 ka, 132 ka and 129 ka, respectively. The SST trend during the PIG is no more than 2 °C (from 20 °C to 18 °C; up to ?0.2 °C/ka). The trend is steeper during the LIG, i.e. up to a 5 °C change from the early interglaciation to immediately before the glacial inception (from 23 °C to 18 °C; up to -0.4 °C/ka). Events are superimposed upon a long term trend towards colder SSTs, beginning with SST maxima followed by temperate periods until perihelion aligned with the NH autumn equinox (before ca 5.3 ka for the PIG and 121 ka for the LIG). A cold spell of around eight centuries at 2.8 ka during the PIG was possibly mimicked during the LIG at ca 118 ka by a SST fall of around 1 °C in a millennium. These events led interglacial SST to stabilise at around 18 °C. The glacial inception, barely evident at the beginning ca 115 ka (North Atlantic event C25, after perihelion passage in the NH winter solstice), culminated with a SST drop of at least 2 °C in two millennia (event C24, ca 111 ka). The Little Ice Age (0.7 ka) also occurred after the latest perihelion passage in the NH winter solstice and could be an example of how a glacial pre-inception event following an interglaciation might be.

Potassium and Argon data for dating the core, and radiochemical data of a series of measurements made on layers inside various manganese nodules from the Pacific Ocean

Although various models have been proposed to explain the origin of manganese nodules (see Goldberg and Arrhenius), two major hypotheses have received extensive attention. One concept suggests that manganese nodules form as the result of interaction between submarine volcanic products and sea water. The common association of manganese nodules with volcanic materials constitutes the main evidence for this theory. The second theory involves a direct inorganic precipitation of manganese from sea water. Goldberg and Arrhenius view this process as the oxidation of divalent manganese to tetravalent manganese by oxygen under the catalytic action of particulate iron hydroxides. Manganese accumulation by the Goldberg and Arrhenius theory would be a relatively slow and comparatively steady process, whereas Bonatti and Nayudu believe manganese nodule formation takes place subsequent to the eruption of submarine volcanoes by the acidic leaching of lava.

Miocene to Pleistocene gluconite-rich layers of the US Mid-Atlantic margin

Glauconite is generally agreed to be a reliable indicator of low sedimentation rate, but little systematic work has been done to specify the role of glauconite in a sequence-stratigraphic framework. Ocean Drilling Program Leg 174A recovered a good record of late Tertiary sediments along the shelf edge of the New Jersey US Atlantic margin, and glauconite was present in many intervals of the cores, sometimes in vertical proximity to sequence boundaries. Leg 174A glauconite was analyzed with binocular microscope, XRD and SEM to determine the percent of potassium and degree of maturity in order to relate occurrence to depositional environment. Seismic data were used to locate sequence boundaries, and percent glauconite was visually estimated. Glauconite samples from Site 1073 were found to have formed within a lowstand systems tract (LST), and as part of a distal condensed section (CS) within a transgressive systems tract (TST). These results are comparable to those from nearby Site 903 of Leg 150, which indicate a similar depositional setting for glauconite. Glauconites at shelf Sites 1071 and 1072 likely formed in the TST as well. Onshore, glauconite occurs mainly in transgressive systems tracts. The Miocene appears to be the upper limit of glauconite formation onshore. As the magnitude of sea-level change decreased, present onshore locations became too nearshore to maintain sediment-free environments, and the zone of glauconite deposition moved seaward. The same process did not occur offshore until the Plio-Pleistocene. Low subsidence-rate margins such as the US Atlantic are subject more to the variations of sea-level than to changes in sediment supply, tectonics, or other factors influencing their depositional patterns. Although glauconite occurrence is widespread in the stratigraphic record, this study demonstrates that for low subsidence-rate margins, primary deposition of glauconite is largely restricted to the TST.

Warmer, deeper and greener mixed layers in the north Atlantic subpolar gyre over the last 50 years.

Shifts in global climate resonate in plankton dynamics, biogeochemical cycles, and marine food webs. We studied these linkages in the North Atlantic subpolar gyre (NASG), which hosts extensive phytoplankton blooms. We show that phytoplankton abundance increased since the 1960s in parallel to a deepening of the mixed layer and a strengthening of winds and heat losses from the ocean, as driven by the low frequency of the North Atlantic Oscillation (NAO). In parallel to these bottom-up processes, the top-down control of phytoplankton by copepods decreased over the same time period in the western NASG, following sea surface temperature changes typical of the Atlantic Multi-decadal Oscillation (AMO). While previous studies have hypothesized that climate-driven warming would facilitate seasonal stratification of surface waters and long-term phytoplankton increase in subpolar regions, here we show that deeper mixed layers in the NASG can be warmer and host a higher phytoplankton biomass. These results emphasize that different modes of climate variability regulate bottom-up (NAO control) and top-down (AMO control) forcing on phytoplankton at decadal timescales. As a consequence, different relationships between phytoplankton, zooplankton, and their physical environment appear subject to the disparate temporal scale of the observations (seasonal, interannual, or decadal). The prediction of phytoplankton response to climate change should be built upon what is learnt from observations at the longest timescales.

Warmer, deeper and greener mixed layers in the north Atlantic subpolar gyre over the last 50 years.

Shifts in global climate resonate in plankton dynamics, biogeochemical cycles, and marine food webs. We studied these linkages in the North Atlantic subpolar gyre (NASG), which hosts extensive phytoplankton blooms. We show that phytoplankton abundance increased since the 1960s in parallel to a deepening of the mixed layer and a strengthening of winds and heat losses from the ocean, as driven by the low frequency of the North Atlantic Oscillation (NAO). In parallel to these bottom-up processes, the top-down control of phytoplankton by copepods decreased over the same time period in the western NASG, following sea surface temperature changes typical of the Atlantic Multi-decadal Oscillation (AMO). While previous studies have hypothesized that climate-driven warming would facilitate seasonal stratification of surface waters and long-term phytoplankton increase in subpolar regions, here we show that deeper mixed layers in the NASG can be warmer and host a higher phytoplankton biomass. These results emphasize that different modes of climate variability regulate bottom-up (NAO control) and top-down (AMO control) forcing on phytoplankton at decadal timescales. As a consequence, different relationships between phytoplankton, zooplankton, and their physical environment appear subject to the disparate temporal scale of the observations (seasonal, interannual, or decadal). The prediction of phytoplankton response to climate change should be built upon what is learnt from observations at the longest timescales.

Item and task difficulty in a B2 reading examination: perceptions of test-takers and CEFR alignment experts compared with psychometric measurements

The article presents a study of a CEFR B2-level reading subtest that is part of the Slovenian national secondary school leaving examination in English as a foreign language, and compares the test-taker actual performance (objective difficulty) with the test-taker and expert perceptions of item difficulty (subjective difficulty). The study also analyses the test-takers’ comments on item difficulty obtained from a while-reading questionnaire. The results are discussed in the framework of the existing research in the fields of (the assessment of) reading comprehension, and are addressed with regard to their implications for item-writing, FL teaching and curriculum development.

Towards a Contingency Theory perspective of Quality Management in Enabling Strategic Alignment

The aim of this paper is to explore the role of Quality Management (QM) theory and practice using a contingency theory perspective. The study is grounded in the role of QM in improving strategic alignment within Small and Medium Sized Enterprises (SMEs) using Contingency Theory rather than adopting best practice approaches. An inductive theory building research methodology was used involving multiple case analyses of five SMEs, involving repeat interviews (n=45), focus groups (n=5) and document analysis. From the findings, it was found that Contingency Variables (strategy, culture, lifecycle and customer focus) and their respective typologies were found to interact with QM practices in helping to shape strategic alignment between the SMEs and their environments. This shaping process based on contingency approaches occurred in a manner unique to each SME and their respective environments rather than in an overarching best practice manner.